FIBEROPTIC SENSOR TECHNOLOGY HANDBOOK
FIBEROPTIC SENSOR TECHNOLOGY HANDBOOK
FIBEROPTIC SENSOR TECHNOLOGY HANDBOOK
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MAXIMUM TENSILE STRENGTH (GN/m2 = lo g N/m2)<br />
INSULATOR<br />
CONDUCTOR<br />
NO FIRE POLISH<br />
N = 40<br />
FURNACE FIRE POLISH ~<br />
N = 46 ;<br />
:<br />
10<br />
5<br />
; ~z”NDucT’oN’’NE~<br />
K<br />
Lu<br />
BAND-GAP EG<br />
—<br />
61~<br />
VALENCE BAND<br />
— —<br />
b<br />
m<br />
LASER FIRE POLISH :<br />
N = 42 ~<br />
z<br />
:L_.—dJu<br />
o 200 400 600 800 1,000<br />
P-TYPE SEMICONDUCTOR<br />
N-TYPE SEMICONDUCTOR<br />
I 1 I 1<br />
I 1<br />
DONOR LEVEL I a. a. * a. I<br />
ACCEPTOR LEVEL<br />
MAXIMUM TENSILE STRESS (KPSI)<br />
Fig. 2.37 The variation of maximum tension stress of<br />
a number of optical fibers for unpolished,<br />
furnace polished, and laser polished fibers<br />
showing the number of fibers that failed at<br />
the various stress levels in total tested<br />
for each polishing condition.<br />
These results clearly indicate how important it ia to<br />
carefully prepare the preforms and to accurately control<br />
the drawing process in order to maintain the strength<br />
of the final drawn fibers and thus get as cloae as possible<br />
to the ideal strength of silica glass.<br />
2.3 SOLID STATE <strong>FIBEROPTIC</strong> LIGHT SOURCES<br />
Solid state optical sources and detectors<br />
utilized in compact fiberoptic sensors will be discussed<br />
in this section. This information will serve as a<br />
background for understanding later discusaiona of sensor<br />
noise and packaging. In order to understand the<br />
trade-offs required, a knowledge of light production<br />
mechanisms and fabrication processes is helpful.<br />
Finally, such information is important for estimating<br />
what is likely to be available in the future.<br />
2.3.1 Energy Levels In Semiconductors<br />
Electrons in free atoms are normally tightly<br />
bound in discrete energy levels. When the atoms are<br />
located in a crystalline structure these discrete<br />
energy levels are replaced by energy bands. Some of<br />
the electrons remain tightly bound to the atom while<br />
other, more energetic electrons, have energies corresponding<br />
to the valence or conduction bands. Those in<br />
the valence band are atill localized at individual atoms<br />
but have the highest energy of such bound electrons,<br />
while electrons in the conduction band are free to move<br />
throughout the crystal. Materials can be divided into<br />
a number of classes depending on the energy gap (separation<br />
between the top energy level of the valence and<br />
the bottom energy level of the conduction band) and<br />
upon the number of electrons, if any, in the conduction<br />
band and lack of electrons in the valence band as shown<br />
in Fig. 2.38. Electrons cannot possess energies that<br />
lie in the gap.<br />
In an insulator the valence and conduction<br />
energy bands are separated by a wide energy gap. If<br />
the gaps in Fig. 2.38 were drawn to scale, the gap<br />
between the valence and conduction bands of the insulator<br />
would be much wider than that of the other materials.<br />
The conduction band in insulators is normally<br />
devoid of electrons while the valence band is filled.<br />
Therefore, when an electric field is applied across<br />
Fig . 2.38 Energy band diagrams in which the crosshatching<br />
symbolizes that there are many<br />
electrons in the various energy bands for<br />
various types of materials.<br />
the insulator, no current flows. If sufficiently high<br />
temperatures are applied (thousands of degrees) it is<br />
possible to excite some of the electrons with valence<br />
band energies up to the energy level of the conduction<br />
band. At such an elevated temperature, insulators become<br />
conductors with conduct ivities that increase with<br />
temperature. Electrical conductors, such as metals,<br />
consist of materials in which electrons fill the valence<br />
band and about half the conduction band. In this<br />
case when an electric field is applied the electrona<br />
move through the crystal easily and the material is<br />
referred to as a conductor. In metals an increaae in<br />
temperature increases lattice vibrations and electron<br />
scattering, therefore the conductivity decreases with<br />
increasing temperature. Materials with properties between<br />
insulators and conductors are known as semiconductors.<br />
Semiconductors are similar to insulators in<br />
that the valence band is filled and the conduction band<br />
is empty. However, the energy gap separating the conduction<br />
and valence bands is much smaller than that of<br />
insulators. For such semiconductors, thermal energy<br />
can excite a few electrons from the valence to the conduction<br />
band. Such materials are known as intrinaic<br />
semiconductors. Their conductivity increases with increasing<br />
temperature. By doping these materials with<br />
certain impurities, it is possible to greatly increase<br />
the number of carriers and increase the conductivity.<br />
If the dopant has carriers with an energy level that<br />
lies in the band gap just slightly below the conduction<br />
band, then thermal motions can readily excite electrona<br />
from these impurities (or dopants) into the conduction<br />
band where they are free to move through the crystal<br />
causing the material to become more conductive. Such<br />
dopants are known as donors and the resultant materials<br />
are known as negative or n-type semiconductors due to<br />
the fact that the carriers are electrons. Galium arsenide<br />
(GaAs) crystalline materials are important as roomtemperature<br />
light-emitting diodes (LED’s) and diode (or<br />
injection) lasers. In these materials, tin and tellurium<br />
serve as dopants that contribute (or donate) electrons<br />
to the conduction band while germanium (an acceptor<br />
impurity) introduces trapping sites with energy<br />
levels slightly above the valence band in the band gap<br />
itself. In the case of an acceptor, thermal motions<br />
will provide sufficient energy to permit electrons from<br />
the valence band to be trapped by an acceptor impurity<br />
atom. The holes left behind in the valence band act<br />
as positive conductors.<br />
p-type semiconductors.<br />
An important<br />
These materials are known as<br />
semiconductor energy state is<br />
2-17