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FIBEROPTIC SENSOR TECHNOLOGY HANDBOOK

FIBEROPTIC SENSOR TECHNOLOGY HANDBOOK

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mately a 0.5 electron-volt increase. For fractional<br />

parts of Al greater than 0.37, i.e., x > 0.37, mechanisms<br />

in addition to simple photon production occur during<br />

recombination with the result that not all of the<br />

energy goes into producing photons, part of it goes into<br />

thermal energy with the possibility of crystal damage<br />

and a reduced tendency for lasing. The wavelength<br />

can be obtained from the photon energy relation E t<br />

= hf<br />

and from the wavelength-frequency-velocity relation ~f=<br />

= c/n, from which the relation 1 = hc/nEt is obtained,<br />

where h is Planck’s constant, c is the velocity of light<br />

in a vacuum, n is the refractive index taken as unity,<br />

and E t<br />

is the energy lost by a particle. For a particle<br />

with a charge of one electron that loses energy<br />

equal to the gap energy, A = 1.24/Eg, where h is the<br />

wavelength in microns and Eg is the gap energy in electron-volts.<br />

Thus for GaAs, 1 = 0.90 micron and for 37%<br />

Al, 1 = 0.64 micron. Longer wavelength lasers (1.1<br />

micron to 1.6 micron) can be produced by using the<br />

quarternary alloy iridium-gallium-arsenic-phosphorous<br />

(InGaAsP).<br />

1 P,<br />

A —P —~ qi - N—<br />

I<br />

I<br />

I<br />

I<br />

1<br />

1<br />

++++++++++++++++++++++++++<br />

I<br />

1<br />

Gal.xA~As:Ge ,~Ga l-y A’yAs ~ Gal_xAlxAs:Sn/Te<br />

I<br />

Ge ‘<br />

S;;Te<br />

Fig. 2.43 The energy levels of a semiconductor forward-biased<br />

double heterostructure laser in<br />

a junction of lower concentration alumlnum<br />

surrounded by higher concentration aluminum.<br />

‘“’~ “’:;’v:;:N:;GAp0.37COMPETING<br />

9 /.<br />

~ ,- PROCESSES OCCUR MAKING<br />

/-<br />

m2.O<br />

u ...” ONSET OF LASING LESS<br />

..0” PROBABLE<br />

n-<br />

a<br />

><br />

0 AIXGal.XAs ● FOR X INCREASING FROM<br />

OT00.37 THE REFRACTIVE<br />

%<br />

300”K<br />

z<br />

INDEX DECREASES BY 5%<br />

u.1 15<br />

[1111111111<br />

o 0.5 1.0<br />

GaAs x AIAs<br />

Fig. 2.42<br />

The band-gap energy level versus aluminum<br />

galium arsenide composition (AIXGA(l-X)AS).<br />

Another important effect is that as the fractional<br />

part of Al, x, increases from zero to 0.37 the<br />

refractive index decreases by 5%. Thus, as x increases,<br />

the energy gap increases and the refractive<br />

index decreases. The energy gap increases by almost<br />

30% and the refractive index by about 5%.<br />

The energy band structure for a crystal in<br />

which a higher concentration of aluminum in two regions<br />

sandwich a third region of lower aluminum content between<br />

them is shown in Fig. 2.43. The corresponding<br />

crystal structure can be formed by a number of processes<br />

one of which is the liquid-phase epitaxial growth<br />

process. Epitaxial growth is the growth of a crystal<br />

from the surface. For the case of interest the following<br />

is a highly simplified description. The process<br />

begins with a crystal of gallium arsenide (GaAs), one<br />

surface of which is put in contact with a high temperature<br />

solution of gallium aluminum arsenide (GaAIAs).<br />

The crystal is maintained at a slightly lower temperature<br />

than the liquid and crystal growth occurs from the<br />

surface. Once the proper thickness of this particular<br />

composition has been achieved, the crystal is removed<br />

from the bath and put in contact with another liquid<br />

having the composition corresponding to that of the<br />

next layer. A crystal results with a p-type and an n-<br />

type layer, each of which have a higher aluminum content,<br />

larger energy gap, and lower refractive index,<br />

2-19<br />

and between which is a recombination layer with lower<br />

aluminum content, smaller energy gap, and higher refractive<br />

index. The amount of aluminum in the recombination<br />

layer determines the wavelength of the light<br />

emitted. In this manner the structure corresponding to<br />

the energy diagram shown in Fig. 2.43 can be formed. By<br />

this process the recombination layer can be made thin,<br />

often as small as a few tenths of a micron. The longer-wavelength<br />

quarternary InGaAsP alloys are produced<br />

by liquid-phase epitaxial growth on an iridium phosphorus<br />

(InP) substrate.<br />

The recombination layer has lower aluminum<br />

content and therefore, a smaller energy gap, while the<br />

layers on each side have greater aluminum content and<br />

a resulting larger energy gap. In this case, when an<br />

electrical bias is applied, electrons are introduced<br />

from the n-type layer into the recombination layer.<br />

Recombination occur overwhelmingly more often in the<br />

layer with the lowest energy gap.<br />

2.3.2 Light Emitting Diodes (LEDs) and Diode<br />

Lasers<br />

The use of crystal structures to fabricate<br />

either an LED or a diode laser is shown in Fig. 2.44.<br />

Electrons are introduced into the bottom of the crystal<br />

and holes are introduced into the top. In the recombination<br />

layer, holes and electrons recombine to form<br />

photons that tend to move outward in all directions as<br />

shown on the left of Fig. 2.44. In this case, the device<br />

behaves as an LED. The light, emitted in all directions,<br />

results from spontaneous emission.<br />

In order to produce a laser it is necessary<br />

to confine and guide the emitted light. This increases<br />

the light intensity to the level where stimulated emission<br />

occurs. This is accomplished in the following<br />

way. The recombination layer has less aluminum therefore<br />

it has the lower energy gap and recombination occurs<br />

here. The use of some aluminum in the recombination<br />

layer allows the wavelength to be adjusted but in<br />

addition it reduces the probability of crystal damage.<br />

Furthermore, the layer with the smallest energy gap<br />

also has the highest refractive index. Thus, a higher<br />

refractive index layer is sandwiched between two layers<br />

of lower refractive index. This is exactly the situation<br />

that leads to lightwave trapping in optical fibers.<br />

Similarly for the structure shown on the right in Fig.<br />

2.44, photons tend to be reflected from the lower refractive<br />

index surface back into the higher-refractiveindex<br />

recombination layer. Photons are retained in the

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