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Guidelines for care & Use of Dry Solvent Stills [Example]

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4. INTERPRETING CHEMICAL HAZARD HMIS RATINGS<br />

The HMIS (Hazardous Material In<strong>for</strong>mation System) rating consists <strong>of</strong> a set <strong>of</strong> three numbers<br />

representing Acute (or immediate) Toxicity, Fire, and Reactivity, in that order, followed by a letter code <strong>for</strong><br />

Personal Protection Equipment and ending with a letter(s) <strong>for</strong> Chronic (or long-term) Toxicity, if necessary.<br />

The numerical hazard ratings are as follows:<br />

4 - severe hazard Chemical Inventory Safety Data Column Key<br />

3 - serious hazard ct = Chronic toxicity hazard, if indicated by an asterisk<br />

2 - moderate hazard at = Acute Toxicity fl = Flammability<br />

1 - slight hazard re = Reactivity pe = personal protective equipment<br />

0 - minimal hazard ct2 = actual description <strong>of</strong> Chronic toxicity hazard<br />

The Personal Protection Equipment code (PPE) begins with letter A <strong>for</strong> least equipment needed<br />

(safety glasses), through H (the most common – standing <strong>for</strong> use <strong>of</strong> safety glasses, lab coat, gloves, and a<br />

hood) and ends with K <strong>for</strong> something extremely dangerous and requiring elaborate protection, such as selfcontained<br />

breathing apparatus. Note that a good fume hood may normally be used in place <strong>of</strong> respirators.<br />

An asterisk next to the Acute Toxicity rating in the first column on the left indicates that a special<br />

“Chronic”, or long-term, hazard exists <strong>for</strong> the chemical, and will be identified by an additional letter(s)<br />

immediately following the capitol letter designation <strong>for</strong> PPE in the last column on the right. In some cases,<br />

a chemical could have more than one chronic health hazard letter designation. These special hazards are:<br />

M –mutagen <strong>Example</strong>: <strong>for</strong> Benzene, *330Hcm<br />

m - suspected mutagen Acute toxicity is 3, with an associated Chronic hazard<br />

T – teratogen Flammability rating is 3<br />

t - suspected teratogen Reactivity rating is 0<br />

C – carcinogen PPE rating is H<br />

c - suspected carcinogen Chronic toxicity rating is cm<br />

A – allergen (<strong>for</strong> suspected carcinogen and<br />

S - can cause silicosis suspected mutagen)<br />

Note that chronic health hazards may also be indicated in plain English on the container<br />

label and/or the MSDS sheet. Chemicals bought from a company and sent without MSDS sheets must be<br />

assumed to have ratings in each category <strong>of</strong> 4 until proven otherwise. Missing hazard data in any category<br />

<strong>of</strong> an MSDS sheet will likewise result in a rating <strong>of</strong> 4 unless the faculty or the laboratory manager judges<br />

the chemical deserving <strong>of</strong> a lower rating based on knowledge <strong>of</strong> chemical properties.<br />

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