Landfills and waste water treatment plants as sources of ... - GKSS

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SUPPORTING INFORMATION Table S2: Mass-to-charge-ratio (m/z) of semi-volatile PFCs determined with GC-MS. MW: molecular weight, TI: Target Ion, Q: Qualifier. PCI: positive chemical ionisation; NCI: negative chemical ionisation. IS: internal standard used for correction Analyte MW TI Q1 (PCI) Q2 (Carballa Omil Lema) IS 4:2 FTOH 264 265.0 227.0 - 13 C 6:2 FTOH 6:2 FTOH 364 365.0 327.0 - 13 C 6:2 FTOH 8:2 FTOH 464 465.0 493.1 - 13 C 8:2 FTOH 10:2 FTOH 564 565.0 527.0 - 13 C 10:2 FTOH 12:2 FTOH 664 665.1 627.0 - 13 C 10:2 FTOH 6:2 FTA 418 419.0 447.1 - 13 C 6:2 FTOH 8:2 FTA 518 519.1 547.1 - 13 C 8:2 FTOH 10:2 FTA 618 619.1 647.1 - 13 C 10:2 FTOH EtFOSA 527 528.0 508.0 507.0 EtFOSA D5 EtFOSE MeFOSA 571 513 554.0 514.0 572.1 494.0 508.0 493.0 EtFOSE D9 MeFOSA D3 MeFOSE MeFBSA MeFBSE Me2FOSA 557 313 357 527 540.0 314.0 340.0 528.0 558.0 294.0 358.0 444.0 494.0 292.9 293.2 483.0 MeFOSE D7 MeFOSA D3 MeFOSE D7 13 C 8:2 FTOH PFOSA 499 500.0 381.0 478.9 EtFOSE D9 Table S3: Mass-to-charge-ratio (m/z) and product ion of ionic PFCs determined at HPLC- MS/MS analyte m/z product ion PFBS 298.877 80 PFHxS 398.894 80 PFOS 498.971 80 PFBA 112.9 169 PFPA 262.825 219 PFHxA 312.934 269 PFHpA 362.95 319 PFOA 412.987 369 PFNA 462.908 419 PFDA 512.876 469 PFUnDA 562.865 519 PFDoDA 612.991 569 PFOSA 497.896 78 MeFBSA 311.914 219 MeFBSE 416.047 59 18 O2-PFHxS 402.981 84 13 C PFOS 502.899 80 13 C PFBA 216.823 172 13 C PFHxA 314.891 270 13 C PFOA 416.978 372 13 C PFNA 467.907 423 13 C PFDA 514.944 470 13 C PFUnDA 564.959 520 13 C PFDoDA 614.913 570 EtFOSAA D5 589.015 419 116
SUPPORTING INFORMATION Table S4: Instrumental detection limits (LOD), instrumental quantification limits (LOQ), method quantification limits (MQL), and method detection limits (MDL) of semi-volatile and ionic PFCs from the gas phase (g) and particle phase (p). MQL(g) MDL(g) MQL(p) MDL(p) LOQ LOD LOQ LOD pg m -3 pg m -3 pg m -3 pg m -3 pg μL -1 pg μL -1 pg abs. pg abs. 4:2 FTOH
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ISSN 0344-9629 Landfills and waste
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Die Berichte der GKSS werden kosten
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Deponien und Kläranlagen als Quell
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TABLE OF CONTENTS VI 4.2.5 Extracti
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LIST OF FIGURES Figure 20: Proporti
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LIST OF TABLES Table S6: Table of r
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ABBREVIATIONS BDE47 2,2',4,4'-Tetra
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ABBREVIATIONS MW molecular weight M
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2 INTRODUCTION
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INTRODUCTION 175 chemicals classifi
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INTRODUCTION Table 1 cont. Analytes
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INTRODUCTION Table 3: Polycyclic mu
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INTRODUCTION Mabury 2006). This inc
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INTRODUCTION 1.3 Physico-chemical p
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INTRODUCTION 1.4 Environmental conc
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INTRODUCTION Chen et al. 2007a; Har
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INTRODUCTION prevent xenobiotica fr
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INTRODUCTION al. 2009c) and being d
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INTRODUCTION Table 6: Selection of
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INTRODUCTION 1.5 Sources Sources of
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OBJECTIVES 2. Objectives In recent
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METHOD OPTIMISATION Simonich et al.
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METHOD OPTIMISATION used as carrier
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METHOD OPTIMISATION 3.3 Extraction
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METHOD OPTIMISATION 3.3 Results 3.3
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METHOD OPTIMISATION AHMI). For less
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METHOD OPTIMISATION 3.3.5 Extractio
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METHOD OPTIMISATION 3.4 Discussion
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METHOD OPTIMISATION partly due to h
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METHOD OPTIMISATION Figure 7: Final
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STUDY 1: LANDFILLS AS SOURCES volat
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STUDY 1: LANDFILLS AS SOURCES On ea
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STUDY 1: LANDFILLS AS SOURCES (Supe
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STUDY 1: LANDFILLS AS SOURCES Table
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STUDY 1: LANDFILLS AS SOURCES 52 c
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STUDY 1: LANDFILLS AS SOURCES 4.3.2
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STUDY 1: LANDFILLS AS SOURCES 4.5 D
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STUDY 1: LANDFILLS AS SOURCES conce
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STUDY 1: LANDFILLS AS SOURCES influ
Page 84 and 85: STUDY 2: WASTE WATER TREATMENT PLAN
Page 106 and 107: CONCLUSIONS AND OUTLOOK BDE183 were
Page 108 and 109: REFERENCES wastewater treatment/pol
Page 110 and 111: REFERENCES Capuano, F. Cavalchi, B.
Page 112 and 113: REFERENCES Dreyer, A. Temme, C. Stu
Page 114 and 115: REFERENCES Harada, K. Nakanishi, S.
Page 116 and 117: REFERENCES Kallenborn, R. Gatermann
Page 118 and 119: REFERENCES sexual development, and
Page 120 and 121: REFERENCES Oros, D. R. Hoover, D. R
Page 122 and 123: REFERENCES Rimkus, G. (1995): Nitro
Page 124 and 125: REFERENCES Smithwick, M. Mabury, S.
Page 126 and 127: REFERENCES USEPA (2006): 2010/2015
Page 128 and 129: REFERENCES Zhao, Y.-X. Qin, X.-F. L
Page 130 and 131: SUPPORTING INFORMATION Figure S3: H
Page 132 and 133: SUPPORTING INFORMATION Table S1: Ta
Page 136 and 137: SUPPORTING INFORMATION Table S5: Ta
Page 138 and 139: SUPPORTING INFORMATION Table S7: Bl
Page 140 and 141: SUPPORTING INFORMATION Table S11: P
Page 142 and 143: SUPPORTING INFORMATION Figure S7: S
Page 144 and 145: SUPPORTING INFORMATION Figure S7 co
Page 146 and 147: SUPPORTING INFORMATION Table S16: T
Page 148 and 149: SUPPORTING INFORMATION Table S19: M
Page 154: ERKLÄRUNG DER SELBSTSTÄNDIGEN VER
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