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DOE/ORO/2327 Oak Ridge Reservation Annual Site Environmental ...

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<strong>Annual</strong> <strong>Site</strong> <strong>Environmental</strong> Report<br />

The highest gross beta activity in groundwater was observed during CY 2009 from well GW-108<br />

(16,200 pCi/L), east of the S-3 site.<br />

4.6.4.1.6 Exit Pathway and Perimeter Monitoring<br />

Data collected to date indicate that volatile organic compounds are the primary class of contaminants<br />

that are migrating through the exit pathways in the Upper East Fork regime. Historically, the compounds<br />

have been observed at depths of almost 500 ft in the Maynardville Limestone, the primary exit pathway<br />

on the east end of the Y-12 Complex. The deep fractures and solution channels that constitute flow paths<br />

within the Maynardville Limestone appear to be well connected, resulting in contaminant migration for<br />

substantial distances off the ORR into Union Valley to the east of the complex.<br />

In addition to the intermediate to deep pathways within the Maynardville Limestone, shallow<br />

groundwater within the water table interval of that geologic unit near New Hope Pond, Lake Reality, and<br />

Upper East Fork Poplar Creek is also monitored. Historically, volatile organic compounds have been<br />

observed near Lake Reality from wells, a dewatering sump, and the New Hope Pond distribution channel<br />

underdrain. In that area, shallow groundwater flows north-northeast through the water table interval east<br />

of New Hope Pond and Lake Reality, following the path of the distribution channel for Upper East Fork<br />

Poplar Creek.<br />

During CY 2009, the observed concentrations of volatile organic compounds at the New Hope Pond<br />

distribution channel underdrain continue to remain low. This may be because the continued operation of<br />

the groundwater plume–capture system in Well GW-845 southeast of New Hope Pond is effectively<br />

reducing the levels of volatile organic compounds in the area. The installation of the plume capture<br />

system was completed in June 2000. This system pumps groundwater from the intermediate bedrock<br />

depth to mitigate off-site migration of volatile organic compounds. Groundwater is continuously pumped<br />

from the Maynardville Limestone at about 95 L/min (25 gal/min), passes through a treatment system to<br />

remove the volatile organic compounds, and then discharges to Upper East Fork Poplar Creek.<br />

Monitoring wells near Well GW-845 continue to show an encouraging response to the pumping<br />

activities. The multiport system installed in Well GW-722, approximately 153 m (500 ft) east and<br />

downgradient of Well GW-845, permits sampling of vertically discrete zones within the Maynardville<br />

Limestone between 27 and 130 m (87 and 425 ft) below ground surface. This well has been instrumental<br />

in characterizing the vertical extent of the east-end plume of volatile organic compounds and is critical in<br />

the evaluation of the effectiveness of the plume capture system. Monitoring results from the sampled<br />

zones in Well GW-722 indicate reductions in volatile organic compounds due to groundwater pumping<br />

upgradient at Well GW-845 (Fig. 4.43). Other wells also show decreases that may be attributable to the<br />

plume capture system operation. These indicators show that operation of the plume capture system is<br />

decreasing volatile organic compounds upgradient and downgradient of Well GW-845.<br />

Fig. 4.43. Decreasing summed volatile organic compounds observed in exit pathway Well<br />

GW-722-17 near the New Hope Pond, 2009.<br />

The Y-12 National Security Complex 4-73

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