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DOE/ORO/2327 Oak Ridge Reservation Annual Site Environmental ...

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<strong>Annual</strong> <strong>Site</strong> <strong>Environmental</strong> Report<br />

• 2026 Radioactive Materials Analytical Laboratory;<br />

• 3020 Radiochemical Development Facility;<br />

• 3039 central off-gas and scrubber system, which includes the 3500 and 4500 areas’ cell ventilation<br />

system, isotope solid-state ventilation system, 3025 and 3026 areas’ cell ventilation system, 3042<br />

ventilation system, and 3092 central off-gas system;<br />

• 7503 Molten Salt Reactor Experiment Facility;<br />

• 7880 TWPC;<br />

• 7911 Melton Valley complex, which includes HFIR and the Radiochemical Engineering<br />

Development Center; and<br />

• 8915 SNS Central Exhaust Facility stack.<br />

In 2009, there were 17 minor point/group sources, and emission calculations/estimates were made for<br />

each of them.<br />

5.4.3.1 Sample Collection and Analytical Procedure<br />

Five of the major point sources (2026, 3020, 3039, 7503, and 7911) are equipped with in-stack<br />

source-sampling systems that comply with criteria in the American National Standards Institute (ANSI)<br />

standard ANSI N 13.1-1969 (ANSI 1969). The sampling systems generally consist of a multipoint instack<br />

sampling probe, a sample transport line, a particulate filter, activated charcoal cartridges, a silica-gel<br />

cartridge (if required), flow-measurement and totalizing instruments, a sampling pump, and a return line<br />

to the stack. In addition to that instrumentation, the system at Stack 7911 includes a high-purity<br />

germanium detector with a NOMAD analyzer, which allows continuous isotopic identification and<br />

quantification of radioactive noble gases (e.g., 41 Ar) in the effluent stream. The sample probes are<br />

annually removed, inspected, and cleaned. The 7880 stack is equipped with an in-stack source-sampling<br />

system that complies with criteria in the ANSI Health Physics Society standard ANSI/HPS N13.1-1999<br />

(ANSI 1999). The system consists of a stainless-steel, shrouded probe; an in-line filter-cartridge holder<br />

placed at the probe to minimize line losses; a particulate filter; a sample transport line; a rotary vane<br />

vacuum pump; and a return line to the stack. The sample probe is annually removed, inspected, and<br />

cleaned. The 8915 stack is equipped with an in-stack radiation detector that complies with criteria in<br />

ANSI/HPS N13.1-1999. The detector monitors radioactive gases flowing through the exhaust stack and<br />

provides a continual readout of detected activity using a scintillator probe. The detector is calibrated to<br />

correlate with isotopic emissions.<br />

Velocity profiles are performed quarterly following the criteria in EPA Method 2 at major and some<br />

minor sources. The profiles provide accurate stack flow data for subsequent emission-rate calculations.<br />

An annual leak-check program is carried out to verify the integrity of the sample transport system. For the<br />

7880 stack, an annual comparison between the effluent flow rate totalizer and EPA Method 2 is<br />

performed. The stack effluent flow rate monitoring system response is checked quarterly against the<br />

manufacturer’s instrument test procedures. The stack sampler rotameter is calibrated at least quarterly in<br />

comparison with a secondary (transfer) standard. Only a certified secondary standard is used for all<br />

rotameter tests.<br />

In addition to the major sources, ORNL has a number of minor sources that have the potential to emit<br />

radionuclides to the atmosphere. A minor source is defined as any ventilation system or component such<br />

as a vent, laboratory hood, room exhaust, or stack that does not meet the approved regulatory criteria for a<br />

major source but that is located in or vents from a radiological control area as defined by Radiological<br />

Support Services of the UT-Battelle Nuclear and Radiological Protection Division. A variety of methods<br />

are used to determine the emissions from the various minor sources. Methods used for minor sourceemission<br />

calculations comply with EPA criteria. The minor sources are evaluated on a 1- to 5-year basis.<br />

Emissions, major and minor, are compiled annually to determine the overall ORNL source term and<br />

associated dose.<br />

<strong>Oak</strong> <strong>Ridge</strong> National Laboratory 5-31

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