Self-assembled Transition Metal Coordination Frameworks of ...

More documents

Recommendations

Info

Ni(II) complexes -40- 100 1 , 80so-3 20 9 1 ' | - | * | * | ' | ' I ' l 4000 3500 3000 2500 2000 1500 1000 500 Wavenumber (cm"l Fig. 3.11. IR spectrum of Ni(II) thiocarbohydrazone complex 2. 100'nn 60- _ -120- ‘ i All" "‘' ‘l_| I , \ . _.. 1' 1'.i v l 40 0 '1 ' | ' I ' | ' | ' | ' I ' | 4000 3500 3000 2500 2000 1500 1000 500 Wavenumber (cm"l 1 .> 50 .1 .2 Fig. 3.12. IR spectrum of Ni(II) carbohydrazone complex 3. ' I --'—Pl- --7 . .7. _ . _ , . , _: ....._...._,__....... ,_ _.. ,2 500 400 300 200 100 Wavenumber (cIn") Fig. 3.13. Far IR spectrum of Ni(II) thiocarbohydrazone complex 2. 91
Chapter 3 The electronic spectra of Ni(H) species are of especial interest existing in all coordination numbers from seven through two [31]. Also, there may be exist more electronic data for Ni(H) than for any other metal ion [31]. The electronic spectral data of Ni(H) complexes in 10-5 M DMF solutions are listed in Table 3.2 and the spectra are given in Figs. 3.14 and 3.15. The intraligand n —> fr * transitions of free ligands have suffered considerable shift in complexes. The ground state of Ni(H) in an octahedral coordination is 3A2g and expects three spin allowed transitions 3T2g(F)
Page 1 and 2:
7,2/H5 Self-assembled Transition Me
Page 3 and 4:
, Phone orr. 0484-2575804 ; Phone R
Page 5 and 6:
‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
Page 7 and 8:
PREFACE In its method, chemistry is
Page 9 and 10:
CONTENTS CHAPTER 1 Introduction to
Page 11 and 12:
4.3.5. Magnetochemistry 4.3.6. Char
Page 13 and 14:
Chapter I__ _ _ irreducible, is a n
Page 15 and 16:
Chapter I W 7 _ W _ 7 pg _ jg to pr
Page 17 and 18:
Chapter I H_ g g 7 g 7 7 __ harvest
Page 19 and 20:
Chapter I _ _ ______g__H _ g involv
Page 21 and 22:
Chapter I _ g plays a pivotal role
Page 23 and 24:
Chapter I g g _ exhibit considerabl
Page 25 and 26:
Chapter I _, assemblies to generate
Page 27 and 28:
Chapter I _ ,_ of mono or dinuclear
Page 29 and 30:
Chapter I M W 7 7 _ __ 1.3.1.1. Ant
Page 31 and 32:
Chapter I _ _ _ _ \_ 4- Jm _. _.
Page 33 and 34:
Chapter In g_ g _ E __ _ E __( > es
Page 35 and 36:
Chapter I W__‘ _ 1.6.6. MALDI MS
Page 37 and 38:
Chapter I ,,_ g electron spin (the
Page 39 and 40:
Chapter I W _ _ Traditional magnets
Page 41 and 42:
Chapter I L.K. Thompson, O. Waldman
Page 43 and 44:
Chapter I i __ _ Org. Chem. 31 (200
Page 45 and 46:
Chapter In _g , g H g 85. S. Padhye
Page 47 and 48:
Chapter 2 1 g anticipation of Cu(H)
Page 49 and 50:
Chapter 2 _. M_ _ up 1. Quinoline-2
Page 51 and 52: Chapter 2 chloroform solution and d
Page 53 and 54: Chapter2 V _ _ _ _, 7 _ with aceton
Page 55: Chapter 2 _ 7 f __ i 2.3. Results a
Page 58 and 59: 100s0- I > J 20
Page 60 and 61: — — 1 Ligands 1
Page 62 and 63: Ligands The ‘H and "C NMR spectra
Page 64 and 65: Ligands The ‘H NMR spectrum of HZ
Page 66 and 67: M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
Page 68 and 69: ' | Ligands uo no 1&0 150 no no no
Page 70 and 71: Ligands Table 2. 3. Crystal data an
Page 72 and 73: Ligands The C-S bond distances of 1
Page 74 and 75: ligands between the planes of Cg(2)
Page 76 and 77: " F Ligands A indicates a typical d
Page 78 and 79: ' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
Page 80 and 81: 2.4.2. M TT Cell Proliferation Assa
Page 82 and 83: Table 2.9. Cell proliferation effec
Page 84 and 85: 7 y _ i _ W Ligands B. Moubaraki, K
Page 86 and 87: CHAPTER Ni(II) complexes of carbohy
Page 88 and 89: _ _ __ g_ g W g H__ Ni(ll) complexe
Page 90 and 91: _ g A __ Ni(lI) complexes The reddi
Page 92 and 93: 3.3. Results and discussion g_g _ N
Page 94 and 95: 3.3.1. MALDI MS spectral studies of
Page 96 and 97: Ni(Il) complexes In the case of com
Page 98 and 99: 100 U-
Page 100: 3.3.2. IR and electronic spectral s
Page 105 and 106: t§hqphw*3 v(Ni—S), further suppo
Page 107 and 108: Chapter 3 charge transfer bands. Fo
Page 109 and 110: Chapter 3 were refined anisotropica
Page 111 and 112: Chapter 3 3.3.3.1. Crystal structur
Page 113 and 114: Chapter 3 Table 3.7. Selected bond
Page 115 and 116: Chapter 3 N(l3)—C(35), N(2l)-C(58
Page 118 and 119: 3.3.3.2. Crystal structures 0f[Ni(H
Page 120 and 121: Table 3.10. Selected bond lengths (
Page 122 and 123: Ni(lI) complexes significant 1t---1
Page 124 and 125: 3.3.4. Magnetochemistry of the mole
Page 126 and 127: Ni(Il) complexes The allowed values
Page 128 and 129: in xn In
Page 130 and 131: g 7 Ni(Il) complexes 3.4. Concludin
Page 132 and 133: 11 12 13 14 15 16 17 18 19 20 21 22
Page 134 and 135: 41 42 43 44 45 46 47 48 49 50 51 52
Page 136 and 137: _ g “FOUR CHAPTER Cu(II) complexe
Page 138 and 139: _g C0pper(II) complexes complex of
Page 140 and 141: _ _ , p f 7, Copper-(II) complexes
Page 142 and 143: pp g _g _4_,_ C0pper(II) complexes
Page 144 and 145: g _,_,_ g g Copperfll) complexes in
Page 146 and 147: i ____ 3+ i --—- C 0pper(H) 2+ co
Page 148 and 149: C0pper(Il) complexes 499 100i ~04 7
Page 150 and 151: .04Copper(II) complexes 385 50.1I 1
Page 152 and 153:
100-I 4 -1 U ” Q 7°-J 59-: "1
Page 154:
C0pper(lI) complexes confirm the po
Page 158 and 159:
C0pper(ll) complexes 100 80" I
Page 160 and 161:
C0pper(1l) complexes state, similar
Page 162 and 163:
2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
Page 164:
Copper(lI) complexes F1 = g",3B:S:
Page 167 and 168:
Chapter 4 for both species consider
Page 169 and 170:
Chapter 4 The spectrum of compound
Page 171 and 172:
Chapter 4 stability alone could not
Page 173 and 174:
Chapter 4 zénzénzénzénénaloeé
Page 175 and 176:
Chapter 4 164 | | | 252 272 2Q 31 B
Page 177 and 178:
Chapter 4 The shifting of g values
Page 179 and 180:
Chapter 4 _|“. / "| 1' '| |' | 1'
Page 181 and 182:
Chapter 4 The solid state and some
Page 183 and 184:
Chapter 4 U 1 .I - O i I . I II I
Page 185 and 186:
_ I Chapter 4 — I I I — I '
Page 187 and 188:
. , Chapter 4 2.5 I I ' I ' I ' I '
Page 189 and 190:
Chapter 4 The field dependence of m
Page 191 and 192:
Chapter 4 Where ,1’ M is the magn
Page 193 and 194:
Chapter 4 g e The powder and frozen
Page 195:
Chapter 4 various aspects like bond
Page 198 and 199:
C0pper(ll) complexes Table 4.6. Sel
Page 200 and 201:
,____ p _p C0pper(H) complexes from
Page 202 and 203:
Ed. Engl. 31 (1992) 733. 7___7 7 7
Page 204 and 205:
__ ,_ f W C 0pper(l1) complexes Che
Page 206 and 207:
-_ FIVE CHAPTER Spectral and magnet
Page 208 and 209:
__ g_ _g g H g __ Manganese(II) com
Page 210 and 211:
q H _ Manganesefll) complexes [Mn2(
Page 212 and 213:
Manganese(Il) complexes lcmzmoll in
Page 214 and 215:
1W3 "l U 70 60 40 30 10 490 740 979
Page 216 and 217:
Manganese(II) complexes MALDI MS sp
Page 218 and 219:
5.3.2. EPR spectral studies Mangane
Page 220 and 221:
Manganese(II) complexes D and E , e
Page 222 and 223:
the pattern is uncertain and it is
Page 224 and 225:
__ I . l r Manganese(II) complexes
Page 226:
" |\ Man ganese(II) complexes 80" 6
Page 229 and 230:
Chapter 5 thiocarbohydrazone comple
Page 231 and 232:
Chapter 5 To fit and interpret the
Page 233 and 234:
Chapter 5 #1 IT 0.00 1 — ‘ I '
Page 235 and 236:
Chapter 5 The temperature dependenc
Page 237 and 238:
Chapter 5 ___ M _ 357 (2004) 2694.
Page 239 and 240:
Chapter5 p _ _ S. Sivakumar, Struct
Page 241 and 242:
Chapter 6 _ _ __ 7 the latter have
Page 243 and 244:
Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
Page 245 and 246:
Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
Page 247 and 248:
Chapter 6 / ‘~ ' if‘ . l \ N N/
Page 249 and 250:
1 | Chapter 6 100m__ ‘ 76$ mi, 16
Page 251 and 252:
3 - i El Q I Chapter 6 - '3“ 1999
Page 253 and 254:
Chapter 6 The compound 27 exhibits
Page 255 and 256:
(T71aq7tew'¢5 centered at 1711.9 c
Page 257 and 258:
1 . 1 Chapter 6 1244 100--1-; 1245
Page 259 and 260:
Chapter 6 6.3.2. Electronic and IR
Page 261 and 262:
Chapter 6 band at 19160 and 23920 c
Page 264 and 265:
Zinc(II) & Cadmium(II) complexes Th
Page 266 and 267:
.- 60- I ‘J TZinc(Il) & Cadmium(l
Page 268 and 269:
Zinc(Il) & Cadmium(Il) complexes re
Page 270 and 271:
Zinc(II) & C admium(ll) complexes T
Page 272 and 273:
Fig. 6.25. The molecular structure
Page 274 and 275:
Zinc(lI) & Cadmium(ll) complexes Al
Page 276 and 277:
Zi!lC(II) & Cadmlum(II) C0mlexes Ta
Page 278 and 279:
V _ i Zinc(1I) & Cadmium(lI) comple
Page 280 and 281:
_ g _ g g V Zinc(lI) & Cadmiumfll)
Page 282 and 283:
_, _ g pg L Summary and conclusion
Page 284 and 285:
W g _ g mm Summary and conclusion a
Page 286 and 287:
__ ,_ _ W A _ _ Summary and conclus
Page 288 and 289:
Curriculum Vitae PERSONAL PROFILE N
Page 290:
2-Hydroxyacetophenone 4-phenylthios
show all

Self-assembled Transition Metal Coordination Frameworks of ...

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?