74 75 76 77 78 79 80 81 82 83 84 ,___ m_ H _ Introduction de Clercq, Pharmazie 52 (1997) 182. Z.H. Chohan, H. Pervez, K.M. Khan, C.T. Supuran, J. Enz. Inhib. Med Chem. 20 (2005) 81. T. Spector, J.A. Harrington, R.W. Jr Morrison, C.U. Lambe, D.J. Nelson, D.R. Averett, K. Biron, P.A. Furman, Proc. Natl. Acad. Sci. USA. 86 (1989) 1051. T.A. Blumenkopf, J .A. Harrington, C.S. Kolbe, D.D. Bankston, R.W. Morrison, E.C. Bigham, V.L. Styles, T. Spector, J. Med. Chem. 35 (1992) 2306. G. Domagk, R. Behnisch, F. Mietzsch, H. Schmidt, Naturewissenschaften 33 (1946) 315. W.-x. Hu, W. Zhou, C.-n. Xia, X. Wen, Bioorg. Med. Chem. Lett. 16 (2006) 2213. M. Whitnall, J. Howard, P. Ponka, D.R. Richardson, Proc. Nat. Acad. Sci. 103 (2006) 14901. D.S. Kalinowski, Y. Yu, P.C. Sharpe, M. Islam, Y.-T, Liao, D.B. Lovejoy, N. Kumar, P.V. Bernhardt, D.R. Richardson, J. Med. Chem. 50 (2007) 3716. C. Junnan, Y.-W. Huang, L. Guanshu, Z. Afrasiabi, E. Sinn, S. Padhye, M. Yinfa, Toxicol. Appl. Phannacol. 197 (2004) 40. A. Kraker, S. Krezoski, J. Schneider, D. Mingel, D.H. Petering, J . Biol. Chem. 260 (1985) 13710. Z. Iakovidou, A. Papageorgiou, M.A. Demertzis, E. Mioglou, D. Mourelatos, A. Kotsis, P.N. Yadav, D. Kovala-Demertzi, Anti-Cancer Drugs 12 (2001) 65. J.L. Buss, B.T. Greene, J. Tumer, F.M. Torti, S.V. Torti, Curr. Topic. Med. Chem. 4 (2004) 1623. 33
Chapter In _g , g H g 85. S. Padhye, Z. Afrasiabi, E. Sinn, J. Fok, K. Mehta, N. Rath, Inorg. Chem. 44 (2005) 1154. 86. I.S. Snyder, J .L. Stringer, drug. Encyclopmdia Britannica from Encyclopaedia Britannica 2007 Ultimate Reference Suite (2007). 87. Z. Lin, H. Chen, J. Zhuang, Y. Wu, Y. Lin, J. Incl. Phen. Mol. Recog. Chem. 30 (1998) 13. 88. W.L. Bragg, Proc. Roy. Soc. London A89 (1913) 248. 89. http://www.ccdc.cam.ac.uk/products/csd/statistics/ 90. Sigma-Alcliich, Analytix, 6 (2001). 91. B.J. Hathaway, Coord. Chem. Rev. 53 (1983) 87. 92. C. Calle, A. Sreekanth, M.V. Fedin, J. Forrer, I. Garcia-Rubio, I.A. Gromov, D. Hinderberger, B. Kasumaj, P. Leger, B. Mancosu, G. Mitrikas, M.G. Santangelo, S. Stoll, A. Schweiger, R. Tschaggelar, J. Hanner, Helv. Chim. Acta 89 (206) 2495. 93. R. Boca, Coord. Chem. Rev. 248 (2004) 757. 94. A. Bencini, D. Gatteschi, EPR <strong>of</strong> exchange Coupled Systems, Springer Verlag, Berlin (1990). 95. B.J. Hathaway, D.E. Billing, Coord. Chem. Rev. 5 (1970) 143. 96. G.V.R. Chandramouli, T.K. Kundu, P.T. Manoharan, Aust. J Chem. 56 (2003) 1239. 97. G.A. Seisenbaeva, M. Kritikos, V.G. Kessler, Polyhedron 22 (2003) 2581. 98. W. Linert, M. Verdaguer (eds.), Molecular Magnets: Recent Highlights, Springer (2003). 99. J .-P. Sauvage, C. Dietrich-Buchecker (eds.) Molecular Catenanes, Rotaxanes and Knots, Wiley-VCH (1999). 100. R.L. Dutta, A. Syamal, Elements <strong>of</strong> Magnetochemistry, EWP (1993). 34 **********
- Page 1 and 2: 7,2/H5 Self-assembled Transition Me
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- Page 41 and 42: Chapter I L.K. Thompson, O. Waldman
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
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t§hqphw*3 v(Ni—S), further suppo
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Chapter 3 charge transfer bands. Fo
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Chapter 3 were refined anisotropica
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Chapter 3 3.3.3.1. Crystal structur
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Chapter 3 Table 3.7. Selected bond
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Chapter 3 N(l3)—C(35), N(2l)-C(58
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3.3.3.2. Crystal structures 0f[Ni(H
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Table 3.10. Selected bond lengths (
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Ni(lI) complexes significant 1t---1
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3.3.4. Magnetochemistry of the mole
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Ni(Il) complexes The allowed values
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in xn In
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g 7 Ni(Il) complexes 3.4. Concludin
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11 12 13 14 15 16 17 18 19 20 21 22
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41 42 43 44 45 46 47 48 49 50 51 52
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_ g “FOUR CHAPTER Cu(II) complexe
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_g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
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i ____ 3+ i --—- C 0pper(H) 2+ co
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C0pper(Il) complexes 499 100i ~04 7
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.04Copper(II) complexes 385 50.1I 1
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100-I 4 -1 U ” Q 7°-J 59-: "1
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C0pper(lI) complexes confirm the po
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C0pper(ll) complexes 100 80" I
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C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
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Copper(lI) complexes F1 = g",3B:S:
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Chapter 4 for both species consider
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Chapter 4 The spectrum of compound
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Chapter 4 stability alone could not
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Chapter 4 zénzénzénzénénaloeé
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Chapter 4 164 | | | 252 272 2Q 31 B
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Chapter 4 The shifting of g values
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Chapter 4 _|“. / "| 1' '| |' | 1'
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Chapter 4 The solid state and some
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Chapter 4 U 1 .I - O i I . I II I
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_ I Chapter 4 — I I I — I '
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. , Chapter 4 2.5 I I ' I ' I ' I '
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Chapter 4 The field dependence of m
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Chapter 4 Where ,1’ M is the magn
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Chapter 4 g e The powder and frozen
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Chapter 4 various aspects like bond
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C0pper(ll) complexes Table 4.6. Sel
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,____ p _p C0pper(H) complexes from
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Ed. Engl. 31 (1992) 733. 7___7 7 7
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__ ,_ f W C 0pper(l1) complexes Che
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-_ FIVE CHAPTER Spectral and magnet
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__ g_ _g g H g __ Manganese(II) com
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q H _ Manganesefll) complexes [Mn2(
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Manganese(Il) complexes lcmzmoll in
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1W3 "l U 70 60 40 30 10 490 740 979
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Manganese(II) complexes MALDI MS sp
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5.3.2. EPR spectral studies Mangane
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Manganese(II) complexes D and E , e
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the pattern is uncertain and it is
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__ I . l r Manganese(II) complexes
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" |\ Man ganese(II) complexes 80" 6
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Chapter 5 thiocarbohydrazone comple
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Chapter 5 To fit and interpret the
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Chapter 5 #1 IT 0.00 1 — ‘ I '
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Chapter 5 The temperature dependenc
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Chapter 5 ___ M _ 357 (2004) 2694.
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Chapter5 p _ _ S. Sivakumar, Struct
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Chapter 6 _ _ __ 7 the latter have
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Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
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Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
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Chapter 6 / ‘~ ' if‘ . l \ N N/
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1 | Chapter 6 100m__ ‘ 76$ mi, 16
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3 - i El Q I Chapter 6 - '3“ 1999
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Chapter 6 The compound 27 exhibits
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(T71aq7tew'¢5 centered at 1711.9 c
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1 . 1 Chapter 6 1244 100--1-; 1245
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Chapter 6 6.3.2. Electronic and IR
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Chapter 6 band at 19160 and 23920 c
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Zinc(II) & Cadmium(II) complexes Th
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.- 60- I ‘J TZinc(Il) & Cadmium(l
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Zinc(Il) & Cadmium(Il) complexes re
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Zinc(II) & C admium(ll) complexes T
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Fig. 6.25. The molecular structure
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Zinc(lI) & Cadmium(ll) complexes Al
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Zi!lC(II) & Cadmlum(II) C0mlexes Ta
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V _ i Zinc(1I) & Cadmium(lI) comple
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_ g _ g g V Zinc(lI) & Cadmiumfll)
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_, _ g pg L Summary and conclusion
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W g _ g mm Summary and conclusion a
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__ ,_ _ W A _ _ Summary and conclus
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Curriculum Vitae PERSONAL PROFILE N
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2-Hydroxyacetophenone 4-phenylthios