Self-assembled Transition Metal Coordination Frameworks of ...

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Chapter 4 Table 4.5. Crystal data and structural refinement parameters <strong>of</strong> compound 13a Parameters '7 Empirical Formula Formula weight (M) Color, shape Temperature (T) K Wavelength (Mo K11) (A) Crystal system Space group Lattice constants a (A ) b (A) c (A) ..... (p) (Mg m"’> Absorption coefficient, ,u (mm") F (000) 6 Range for data collection Limiting Indices 186 Reflections collected Independent Reflections Refinement method Data / restraints / parameters Goodness-<strong>of</strong>-fit on F2 Final R indices [I > 20(1)] R indices (all data) Largest difference peak and hole (e 13(3) [Cu(L4’)2Cl_] CH3OH H 0 11,0 Cl C33H35Cl3CUNgO3 626.36 green, plate 293(2) 0.71073 T riclinic Pi 7.132(3) 10.542(4) 1s.477(7) 97.397(6) 1o1.14s(6) 109.751(6) 1254.1(s) 2 1.659 1.235 636 1.15 to 27.44 -95 hS8, -13 SkSl3 051323 5735 5735 [R(int) = 0 0000] Full-matrix least squares on F 5735/1/348 1.161 R1 =0.0404, WR'> = 0 1547 R, = 0.0405, wR2 =0 1548 0.317 and -0 880
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
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Ligands The ‘H and "C NMR spectra
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Ligands The ‘H NMR spectrum of HZ
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M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
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' | Ligands uo no 1&0 150 no no no
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Ligands Table 2. 3. Crystal data an
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Ligands The C-S bond distances of 1
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ligands between the planes of Cg(2)
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" F Ligands A indicates a typical d
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' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
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2.4.2. M TT Cell Proliferation Assa
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Table 2.9. Cell proliferation effec
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7 y _ i _ W Ligands B. Moubaraki, K
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CHAPTER Ni(II) complexes of carbohy
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_ _ __ g_ g W g H__ Ni(ll) complexe
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_ g A __ Ni(lI) complexes The reddi
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3.3. Results and discussion g_g _ N
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
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t§hqphw*3 v(Ni—S), further suppo
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Chapter 3 charge transfer bands. Fo
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Chapter 3 were refined anisotropica
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Chapter 3 3.3.3.1. Crystal structur
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Chapter 3 Table 3.7. Selected bond
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Chapter 3 N(l3)—C(35), N(2l)-C(58
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3.3.3.2. Crystal structures 0f[Ni(H
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Table 3.10. Selected bond lengths (
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Ni(lI) complexes significant 1t---1
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3.3.4. Magnetochemistry of the mole
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Ni(Il) complexes The allowed values
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in xn In
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g 7 Ni(Il) complexes 3.4. Concludin
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11 12 13 14 15 16 17 18 19 20 21 22
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41 42 43 44 45 46 47 48 49 50 51 52
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_ g “FOUR CHAPTER Cu(II) complexe
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_g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
Page 146 and 147: i ____ 3+ i --—- C 0pper(H) 2+ co
Page 148 and 149: C0pper(Il) complexes 499 100i ~04 7
Page 150 and 151: .04Copper(II) complexes 385 50.1I 1
Page 152 and 153: 100-I 4 -1 U ” Q 7°-J 59-: "1
Page 154: C0pper(lI) complexes confirm the po
Page 158 and 159: C0pper(ll) complexes 100 80" I
Page 160 and 161: C0pper(1l) complexes state, similar
Page 162 and 163: 2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
Page 164: Copper(lI) complexes F1 = g",3B:S:
Page 167 and 168: Chapter 4 for both species consider
Page 169 and 170: Chapter 4 The spectrum of compound
Page 171 and 172: Chapter 4 stability alone could not
Page 173 and 174: Chapter 4 zénzénzénzénénaloeé
Page 175 and 176: Chapter 4 164 | | | 252 272 2Q 31 B
Page 177 and 178: Chapter 4 The shifting of g values
Page 179 and 180: Chapter 4 _|“. / "| 1' '| |' | 1'
Page 181 and 182: Chapter 4 The solid state and some
Page 183 and 184: Chapter 4 U 1 .I - O i I . I II I
Page 185 and 186: _ I Chapter 4 — I I I — I '
Page 187 and 188: . , Chapter 4 2.5 I I ' I ' I ' I '
Page 189 and 190: Chapter 4 The field dependence of m
Page 191 and 192: Chapter 4 Where ,1’ M is the magn
Page 193 and 194: Chapter 4 g e The powder and frozen
Page 195: Chapter 4 various aspects like bond
Page 199 and 200: Chapter 4 Table 4.7. Cell survival
Page 201 and 202: Chapter 4 _ g g ,4 pp if magnetic s
Page 203 and 204: Chapter 4 g _, 17 18 19 20 21 22 23
Page 205 and 206: Chapter 4 7 W *_ ?_ _ _ 53. Y.D. La
Page 207 and 208: Chapter 5 _ g _ g g _g_ g _g magnet
Page 209 and 210: Chapter5 __ ,4 4 4 4 __ _, after th
Page 211 and 212: Chapter 5 _ H _ g g A temperature,
Page 213 and 214: Chapter 5 5.3.1. AIALDI MS spectral
Page 215 and 216: Chapter 5 The spectrum of 20 shows
Page 217 and 218: Chapter 5 The peaks of complex 22 a
Page 219 and 220: Chapter 5 lower than cubic. However
Page 221 and 222: Chapter 5 value of 265 MI-lz (94.9
Page 223 and 224: Chapter 5 Broad signals above g=2,
Page 225 and 226: Chapter 5 5.3.3. IR and electronic
Page 228 and 229: Manganese(ll) complexes .l 70 60
Page 230 and 231: 5.3.4. Magnetochemistry Manganese(l
Page 232 and 233: Manganese(lI) complexes The best-fi
Page 234 and 235: ml lManganese(Il) complexes 4-5 "I
Page 236 and 237: W 7 N A _ gm g_ g Manganesefll) com
Page 238 and 239: _, f _ ,_ Manganesefll) complexes L
Page 240 and 241: _ {{{{ o SIX CHAPTER Self-assembled
Page 242 and 243: pg p_ g g _ Zinc(lI) & Cadmiumfll)
Page 244 and 245: g pg __ V g A Zinc(II) & Cadmium(II
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__ A A A __AA_*_Ag Zinc(Il) & Cadmi
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6.3.1 . MALDI MS spectral studies Z
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Zinc(Il) & Cadmium(lI) complexes 24
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Zinc(lI) & Cadmium(lI) complexes -
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Zinc(ll) & Cadmium(II) complexes di
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Zinc(II) & Cadmium(Il) complexes m
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ml ~81 70 ‘O . 30. 1. I00. 50 108
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08 ‘ 00 0.0 07 06 05 Zinc(lI) &
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Zinc(II) & Cadmium(Il) complexes Th
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Chapter 6 with v |(B—F) at ~777 c
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Chapter 6 strong v(C=S) bands of fr
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Chapter 6 6.3.3.1. Crystal structur
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Chapter 6 comparatively greater tha
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Chapter 6 Zn(4)=9O.78(l)°}. The Zn
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Chapter 6 In the crystal packing (F
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Chapter 6 H 6.4. Concluding remarks
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Chapter6 H f f _ j i W f W ‘ ,_ A
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Chapter 6 j ,_ , 40. A.L. Spek,Acta
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4. 1,5-Bis(di-2-pyridyl ketone) car
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g g 7 g Self-Assembled Transition M
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A Self-Assembled Transition Metal C
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RESEARCH PUBLICATIONS Structural an
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