Self-assembled Transition Metal Coordination Frameworks of ...

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Manganese(lI) complexes The best-fit results obtained for 19, 21, 22 and 23 are given in Figs. 5.18 to 5.21. Reasonably good fitting are obtained for all Mn(II) squares. The fitting parameters of Mn(II) thiocarbohydrazone square grid 19 are g = 2.000:l: 0.017, J = — 98.872 2.22 cm", 6) = -0.08 K, p = 0.0403 and R = 1.93>< 10'2. Similarly, for complex 22 the magnetic data were fitted to the van Vleck equation using the Hamiltonian (1) to get the parameters g = 2.0042 0.064, J= -98.751 5.27 cm", o = -1.5 K, p = 0.0072 and R = 3.13>
Chapter 5 #1 IT 0.00 1 — ‘ I ' I ' I ' I ' I ' I ' I ' I 2.5 1 -n 1 2.0 -' 1.5 1 — 1.0 0.5 0.0 Fig. 5.18. Temperature dependence of molar magnetic susceptibility Xm (0) and effective magnetic moment turf (n) of 19. The solid lines represent the best fit got 222 u—n Ii 0.14 0.12 0.10 1 0.08 0.06 -| 0.04 0.02 _ 'I| I I I ' I ' I ' I ' I ' I ' I L i —u — — ‘I | I | I | I | I | I | I | I | I 0 50 1 00 1 50 200 250 300 350 T(K 0 so 100 150 200 250 soo 350 T(K ) Fig. 5.19. X,,,T data (n) as a function of temperature for complex 21. The solid line represents the best fit obtained. -1 in 1 up 1 up
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
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Ligands The ‘H and "C NMR spectra
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Ligands The ‘H NMR spectrum of HZ
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M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
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' | Ligands uo no 1&0 150 no no no
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Ligands Table 2. 3. Crystal data an
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Ligands The C-S bond distances of 1
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ligands between the planes of Cg(2)
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" F Ligands A indicates a typical d
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' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
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2.4.2. M TT Cell Proliferation Assa
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Table 2.9. Cell proliferation effec
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7 y _ i _ W Ligands B. Moubaraki, K
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CHAPTER Ni(II) complexes of carbohy
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_ _ __ g_ g W g H__ Ni(ll) complexe
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_ g A __ Ni(lI) complexes The reddi
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3.3. Results and discussion g_g _ N
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
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t§hqphw*3 v(Ni—S), further suppo
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Chapter 3 charge transfer bands. Fo
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Chapter 3 were refined anisotropica
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Chapter 3 3.3.3.1. Crystal structur
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Chapter 3 Table 3.7. Selected bond
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Chapter 3 N(l3)—C(35), N(2l)-C(58
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3.3.3.2. Crystal structures 0f[Ni(H
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Table 3.10. Selected bond lengths (
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Ni(lI) complexes significant 1t---1
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3.3.4. Magnetochemistry of the mole
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Ni(Il) complexes The allowed values
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in xn In
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g 7 Ni(Il) complexes 3.4. Concludin
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11 12 13 14 15 16 17 18 19 20 21 22
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41 42 43 44 45 46 47 48 49 50 51 52
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_ g “FOUR CHAPTER Cu(II) complexe
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_g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
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i ____ 3+ i --—- C 0pper(H) 2+ co
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C0pper(Il) complexes 499 100i ~04 7
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.04Copper(II) complexes 385 50.1I 1
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100-I 4 -1 U ” Q 7°-J 59-: "1
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C0pper(lI) complexes confirm the po
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C0pper(ll) complexes 100 80" I
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C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
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Copper(lI) complexes F1 = g",3B:S:
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Chapter 4 for both species consider
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Chapter 4 The spectrum of compound
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Chapter 4 stability alone could not
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Chapter 4 zénzénzénzénénaloeé
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Chapter 4 164 | | | 252 272 2Q 31 B
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Chapter 4 The shifting of g values
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Chapter 4 _|“. / "| 1' '| |' | 1'
Page 181 and 182: Chapter 4 The solid state and some
Page 183 and 184: Chapter 4 U 1 .I - O i I . I II I
Page 185 and 186: _ I Chapter 4 — I I I — I '
Page 187 and 188: . , Chapter 4 2.5 I I ' I ' I ' I '
Page 189 and 190: Chapter 4 The field dependence of m
Page 191 and 192: Chapter 4 Where ,1’ M is the magn
Page 193 and 194: Chapter 4 g e The powder and frozen
Page 195: Chapter 4 various aspects like bond
Page 198 and 199: C0pper(ll) complexes Table 4.6. Sel
Page 200 and 201: ,____ p _p C0pper(H) complexes from
Page 202 and 203: Ed. Engl. 31 (1992) 733. 7___7 7 7
Page 204 and 205: __ ,_ f W C 0pper(l1) complexes Che
Page 206 and 207: -_ FIVE CHAPTER Spectral and magnet
Page 208 and 209: __ g_ _g g H g __ Manganese(II) com
Page 210 and 211: q H _ Manganesefll) complexes [Mn2(
Page 212 and 213: Manganese(Il) complexes lcmzmoll in
Page 214 and 215: 1W3 "l U 70 60 40 30 10 490 740 979
Page 216 and 217: Manganese(II) complexes MALDI MS sp
Page 218 and 219: 5.3.2. EPR spectral studies Mangane
Page 220 and 221: Manganese(II) complexes D and E , e
Page 222 and 223: the pattern is uncertain and it is
Page 224 and 225: __ I . l r Manganese(II) complexes
Page 226: " |\ Man ganese(II) complexes 80" 6
Page 229 and 230: Chapter 5 thiocarbohydrazone comple
Page 231: Chapter 5 To fit and interpret the
Page 235 and 236: Chapter 5 The temperature dependenc
Page 237 and 238: Chapter 5 ___ M _ 357 (2004) 2694.
Page 239 and 240: Chapter5 p _ _ S. Sivakumar, Struct
Page 241 and 242: Chapter 6 _ _ __ 7 the latter have
Page 243 and 244: Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
Page 245 and 246: Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
Page 247 and 248: Chapter 6 / ‘~ ' if‘ . l \ N N/
Page 249 and 250: 1 | Chapter 6 100m__ ‘ 76$ mi, 16
Page 251 and 252: 3 - i El Q I Chapter 6 - '3“ 1999
Page 253 and 254: Chapter 6 The compound 27 exhibits
Page 255 and 256: (T71aq7tew'¢5 centered at 1711.9 c
Page 257 and 258: 1 . 1 Chapter 6 1244 100--1-; 1245
Page 259 and 260: Chapter 6 6.3.2. Electronic and IR
Page 261 and 262: Chapter 6 band at 19160 and 23920 c
Page 264 and 265: Zinc(II) & Cadmium(II) complexes Th
Page 266 and 267: .- 60- I ‘J TZinc(Il) & Cadmium(l
Page 268 and 269: Zinc(Il) & Cadmium(Il) complexes re
Page 270 and 271: Zinc(II) & C admium(ll) complexes T
Page 272 and 273: Fig. 6.25. The molecular structure
Page 274 and 275: Zinc(lI) & Cadmium(ll) complexes Al
Page 276 and 277: Zi!lC(II) & Cadmlum(II) C0mlexes Ta
Page 278 and 279: V _ i Zinc(1I) & Cadmium(lI) comple
Page 280 and 281: _ g _ g g V Zinc(lI) & Cadmiumfll)
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_, _ g pg L Summary and conclusion
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W g _ g mm Summary and conclusion a
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__ ,_ _ W A _ _ Summary and conclus
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Curriculum Vitae PERSONAL PROFILE N
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2-Hydroxyacetophenone 4-phenylthios
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