Self-assembled Transition Metal Coordination Frameworks of ...

More documents

Recommendations

Info

2.5 2.0 1.5 0.5 — I O _ . . .. .‘......I..OOQOl(UQQl.OlI 0.002047 0.002046 0.002045 0.002044 . — 0.002043 IIQ..O....O'.I."...I..‘O I I0 0 0.0-1 | I | I | I | I | I | I | I | I 0.002042 0 50 1 00 1 50 200 250 300 350 T (K) O -. Fig. 4.42. Effective magnetic moment pd; (I) and molar magnetic susceptibility Xm (0) data as a function of temperature for 10. I ' I ' I ' I ' I ' I ' I ' I 2.0 — 1.5- - 0 O I‘ -I ' ‘ . — 0.0024 I-. _ I — 0.0021 I.I O. §_{ I - 0.001 1.0 O I - O . OQ _ OOOO o@°°°°o - 0.0015 0.5 1 OOQ an I | I | I | I | I | I | I | I | I 0 50 100 1 50 200 250 300 350 T (K) C0pper(II) complexes 0.0012 Fig. 4.43. Temperature dependence of effective magnetic moment pdf (n) and of molar magnetic susceptibility X,“ (0) of complex ll .II/\ \-/
_ I Chapter 4 — I I I — I ' I 0.0030 ' I ' I ' I 3.0 I I‘.-I -00028 2.5 2.0 I- _ I. . 0.0 0 1.5 _ I O — 0.0026 '/O0I 0 1.0 I .0000 I ¢°°‘ - 0.0024 o 0°’ 0.5 /‘O0’ \_O. 90° P °~o 00 00' 0.0022 0.0-I | I | I | I | I | I | I | I | -I 0 50 1 0'0 150 200 250 300 350 T (K) Fig. 4.44. Effective magnetic moment um (I) and molar magnetic susceptibility 70,, " (0) data as a function of temperature for complex 12. I ' — I I ' I ' I 0.0028 ' I ' I ' I ' I 2.5 I 9 2.0 — 0.0026 I I‘ I I‘-I I P 1.5 | I \ . l 1.0 Q I 1| I I I - 0.0024 — 0.0022 |‘ 0.5 0.0 O 0 02° - 0.0020 _O\ /O -O Q O-Q O,0 O 00 Q 50 100 1 50 200 250 300 350 -I | I | I | I | I | I | I | I | I T (K) Fig. 4.45. Temperature dependence of effective magnetic moment pdf (I) and of molar magnetic susceptibility Xm (0) of complex 13. 174
Page 1 and 2:
7,2/H5 Self-assembled Transition Me
Page 3 and 4:
, Phone orr. 0484-2575804 ; Phone R
Page 5 and 6:
‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
Page 7 and 8:
PREFACE In its method, chemistry is
Page 9 and 10:
CONTENTS CHAPTER 1 Introduction to
Page 11 and 12:
4.3.5. Magnetochemistry 4.3.6. Char
Page 13 and 14:
Chapter I__ _ _ irreducible, is a n
Page 15 and 16:
Chapter I W 7 _ W _ 7 pg _ jg to pr
Page 17 and 18:
Chapter I H_ g g 7 g 7 7 __ harvest
Page 19 and 20:
Chapter I _ _ ______g__H _ g involv
Page 21 and 22:
Chapter I _ g plays a pivotal role
Page 23 and 24:
Chapter I g g _ exhibit considerabl
Page 25 and 26:
Chapter I _, assemblies to generate
Page 27 and 28:
Chapter I _ ,_ of mono or dinuclear
Page 29 and 30:
Chapter I M W 7 7 _ __ 1.3.1.1. Ant
Page 31 and 32:
Chapter I _ _ _ _ \_ 4- Jm _. _.
Page 33 and 34:
Chapter In g_ g _ E __ _ E __( > es
Page 35 and 36:
Chapter I W__‘ _ 1.6.6. MALDI MS
Page 37 and 38:
Chapter I ,,_ g electron spin (the
Page 39 and 40:
Chapter I W _ _ Traditional magnets
Page 41 and 42:
Chapter I L.K. Thompson, O. Waldman
Page 43 and 44:
Chapter I i __ _ Org. Chem. 31 (200
Page 45 and 46:
Chapter In _g , g H g 85. S. Padhye
Page 47 and 48:
Chapter 2 1 g anticipation of Cu(H)
Page 49 and 50:
Chapter 2 _. M_ _ up 1. Quinoline-2
Page 51 and 52:
Chapter 2 chloroform solution and d
Page 53 and 54:
Chapter2 V _ _ _ _, 7 _ with aceton
Page 55:
Chapter 2 _ 7 f __ i 2.3. Results a
Page 58 and 59:
100s0- I > J 20
Page 60 and 61:
— — 1 Ligands 1
Page 62 and 63:
Ligands The ‘H and "C NMR spectra
Page 64 and 65:
Ligands The ‘H NMR spectrum of HZ
Page 66 and 67:
M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
Page 68 and 69:
' | Ligands uo no 1&0 150 no no no
Page 70 and 71:
Ligands Table 2. 3. Crystal data an
Page 72 and 73:
Ligands The C-S bond distances of 1
Page 74 and 75:
ligands between the planes of Cg(2)
Page 76 and 77:
" F Ligands A indicates a typical d
Page 78 and 79:
' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
Page 80 and 81:
2.4.2. M TT Cell Proliferation Assa
Page 82 and 83:
Table 2.9. Cell proliferation effec
Page 84 and 85:
7 y _ i _ W Ligands B. Moubaraki, K
Page 86 and 87:
CHAPTER Ni(II) complexes of carbohy
Page 88 and 89:
_ _ __ g_ g W g H__ Ni(ll) complexe
Page 90 and 91:
_ g A __ Ni(lI) complexes The reddi
Page 92 and 93:
3.3. Results and discussion g_g _ N
Page 94 and 95:
3.3.1. MALDI MS spectral studies of
Page 96 and 97:
Ni(Il) complexes In the case of com
Page 98 and 99:
100 U-
Page 100:
3.3.2. IR and electronic spectral s
Page 103 and 104:
Chapter 3 The electronic spectra of
Page 105 and 106:
t§hqphw*3 v(Ni—S), further suppo
Page 107 and 108:
Chapter 3 charge transfer bands. Fo
Page 109 and 110:
Chapter 3 were refined anisotropica
Page 111 and 112:
Chapter 3 3.3.3.1. Crystal structur
Page 113 and 114:
Chapter 3 Table 3.7. Selected bond
Page 115 and 116:
Chapter 3 N(l3)—C(35), N(2l)-C(58
Page 118 and 119:
3.3.3.2. Crystal structures 0f[Ni(H
Page 120 and 121:
Table 3.10. Selected bond lengths (
Page 122 and 123:
Ni(lI) complexes significant 1t---1
Page 124 and 125:
3.3.4. Magnetochemistry of the mole
Page 126 and 127:
Ni(Il) complexes The allowed values
Page 128 and 129:
in xn In
Page 130 and 131:
g 7 Ni(Il) complexes 3.4. Concludin
Page 132 and 133:
11 12 13 14 15 16 17 18 19 20 21 22
Page 134 and 135: 41 42 43 44 45 46 47 48 49 50 51 52
Page 136 and 137: _ g “FOUR CHAPTER Cu(II) complexe
Page 138 and 139: _g C0pper(II) complexes complex of
Page 140 and 141: _ _ , p f 7, Copper-(II) complexes
Page 142 and 143: pp g _g _4_,_ C0pper(II) complexes
Page 144 and 145: g _,_,_ g g Copperfll) complexes in
Page 146 and 147: i ____ 3+ i --—- C 0pper(H) 2+ co
Page 148 and 149: C0pper(Il) complexes 499 100i ~04 7
Page 150 and 151: .04Copper(II) complexes 385 50.1I 1
Page 152 and 153: 100-I 4 -1 U ” Q 7°-J 59-: "1
Page 154: C0pper(lI) complexes confirm the po
Page 158 and 159: C0pper(ll) complexes 100 80" I
Page 160 and 161: C0pper(1l) complexes state, similar
Page 162 and 163: 2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
Page 164: Copper(lI) complexes F1 = g",3B:S:
Page 167 and 168: Chapter 4 for both species consider
Page 169 and 170: Chapter 4 The spectrum of compound
Page 171 and 172: Chapter 4 stability alone could not
Page 173 and 174: Chapter 4 zénzénzénzénénaloeé
Page 175 and 176: Chapter 4 164 | | | 252 272 2Q 31 B
Page 177 and 178: Chapter 4 The shifting of g values
Page 179 and 180: Chapter 4 _|“. / "| 1' '| |' | 1'
Page 181 and 182: Chapter 4 The solid state and some
Page 183: Chapter 4 U 1 .I - O i I . I II I
Page 187 and 188: . , Chapter 4 2.5 I I ' I ' I ' I '
Page 189 and 190: Chapter 4 The field dependence of m
Page 191 and 192: Chapter 4 Where ,1’ M is the magn
Page 193 and 194: Chapter 4 g e The powder and frozen
Page 195: Chapter 4 various aspects like bond
Page 198 and 199: C0pper(ll) complexes Table 4.6. Sel
Page 200 and 201: ,____ p _p C0pper(H) complexes from
Page 202 and 203: Ed. Engl. 31 (1992) 733. 7___7 7 7
Page 204 and 205: __ ,_ f W C 0pper(l1) complexes Che
Page 206 and 207: -_ FIVE CHAPTER Spectral and magnet
Page 208 and 209: __ g_ _g g H g __ Manganese(II) com
Page 210 and 211: q H _ Manganesefll) complexes [Mn2(
Page 212 and 213: Manganese(Il) complexes lcmzmoll in
Page 214 and 215: 1W3 "l U 70 60 40 30 10 490 740 979
Page 216 and 217: Manganese(II) complexes MALDI MS sp
Page 218 and 219: 5.3.2. EPR spectral studies Mangane
Page 220 and 221: Manganese(II) complexes D and E , e
Page 222 and 223: the pattern is uncertain and it is
Page 224 and 225: __ I . l r Manganese(II) complexes
Page 226: " |\ Man ganese(II) complexes 80" 6
Page 229 and 230: Chapter 5 thiocarbohydrazone comple
Page 231 and 232: Chapter 5 To fit and interpret the
Page 233 and 234: Chapter 5 #1 IT 0.00 1 — ‘ I '
Page 235 and 236:
Chapter 5 The temperature dependenc
Page 237 and 238:
Chapter 5 ___ M _ 357 (2004) 2694.
Page 239 and 240:
Chapter5 p _ _ S. Sivakumar, Struct
Page 241 and 242:
Chapter 6 _ _ __ 7 the latter have
Page 243 and 244:
Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
Page 245 and 246:
Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
Page 247 and 248:
Chapter 6 / ‘~ ' if‘ . l \ N N/
Page 249 and 250:
1 | Chapter 6 100m__ ‘ 76$ mi, 16
Page 251 and 252:
3 - i El Q I Chapter 6 - '3“ 1999
Page 253 and 254:
Chapter 6 The compound 27 exhibits
Page 255 and 256:
(T71aq7tew'¢5 centered at 1711.9 c
Page 257 and 258:
1 . 1 Chapter 6 1244 100--1-; 1245
Page 259 and 260:
Chapter 6 6.3.2. Electronic and IR
Page 261 and 262:
Chapter 6 band at 19160 and 23920 c
Page 264 and 265:
Zinc(II) & Cadmium(II) complexes Th
Page 266 and 267:
.- 60- I ‘J TZinc(Il) & Cadmium(l
Page 268 and 269:
Zinc(Il) & Cadmium(Il) complexes re
Page 270 and 271:
Zinc(II) & C admium(ll) complexes T
Page 272 and 273:
Fig. 6.25. The molecular structure
Page 274 and 275:
Zinc(lI) & Cadmium(ll) complexes Al
Page 276 and 277:
Zi!lC(II) & Cadmlum(II) C0mlexes Ta
Page 278 and 279:
V _ i Zinc(1I) & Cadmium(lI) comple
Page 280 and 281:
_ g _ g g V Zinc(lI) & Cadmiumfll)
Page 282 and 283:
_, _ g pg L Summary and conclusion
Page 284 and 285:
W g _ g mm Summary and conclusion a
Page 286 and 287:
__ ,_ _ W A _ _ Summary and conclus
Page 288 and 289:
Curriculum Vitae PERSONAL PROFILE N
Page 290:
2-Hydroxyacetophenone 4-phenylthios
show all

Self-assembled Transition Metal Coordination Frameworks of ...

Create successful ePaper yourself

Delete template?

Save as template?