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Self-assembled Transition Metal Coordination Frameworks of ...

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4.3.5. Magnetochemistry<br />

4.3.6. Characterization <strong>of</strong> an unusual complex<br />

4.3.6.1. Crystal structure <strong>of</strong> [Cu(L4“);Cl;]- Cll3OH- H2O~ H_;OTCl‘ (l3a)<br />

4.4. Anticancer properties<br />

4.5. Concluding remarks<br />

References<br />

CHAPTER 5<br />

Spectral and magnetic studies <strong>of</strong> Mn(II) molecular frameworks <strong>of</strong><br />

carbohydrazone and thiocarbohydrazone ligands<br />

5.1 . introduction<br />

5 .2. Experimental<br />

5.3. Results and discussion<br />

5.3.1. MALDI MS spectral studies<br />

5.3.2. EPR spectral studies<br />

5.3.3. IR and electronic spectral studies<br />

5.3.4. M agnetochemistry<br />

5.4. Concluding remarks<br />

References<br />

CHAPTER 6<br />

<strong>Self</strong>-<strong>assembled</strong> Zn(II) and Cd(II) molecular frameworks: Structural<br />

and spectral properties<br />

6.1 . Introduction<br />

6.2. Experimental<br />

6.3. Results and discussion<br />

6.3.1. MALDI MS spectral studies<br />

6.3.2. Electronic and IR spectral characteristics<br />

6.3.3. Single crystal X-ray diffraction study<br />

6.3.3.1. Crystal structure <strong>of</strong> [Zn(HL5)]4(BF4)4- 10}-I20 (29)<br />

6.4. Concluding remarks<br />

References<br />

Summary and conclusion

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