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1W3 "l U 70 60 40 30 10 490 740 979 430 N0 I | Man ganese(ll) complexes m 1U! I E 1 T41 431 l 1111 ‘$2 M "2 - | l ‘E3- M I us Mass!Charg: 0 it it ,3, I "7 no on 1124 1220 “ea Ll 000 800 1000 1200 1400 1000 1000 440 53‘-57° no ml 59 can 1- 1:111:00 _ __ __ _ __ _ ___ _____ 1ss11eo:216441¢1¢1rsa __ __ _____________7____i_ ______ _ ____ _ ________ ma _____ ____- ma .i 1280 "5 5'" l | 1452 Mnalchnrp Fig. 5.1. MALDI MS spectrum of complex 19. The insets are calculated isotropic distribution patterns. 9‘/9.1 1068.0 mo °'° I 880 so ‘z 050 1 33' 382 Q9-0 1- I I 68 1068 mo 1451 1452 1653
Chapter 5 The spectrum of 20 shows many peaks (Fig. 5.3). The peak at 438 is assigned as [Mn(HL3)]+ (calc. 438) with matching isotropic distribution pattern. The small peak at 913 may be of [Mn2(HL3)L3- 21i,o]* (calc. 912), which lacks isotropic pattern due to very low intensity. The peak at 875 is assigned as [Mn2(HL3)L3]+ (calc. 875), 822 as [Mn(HL3)H2L3]+ (calc. 822), 651 as [Mn(H2L3)N3+quinoline-2-aldehyde hydrazone]+ (calc. 651) and 609 as [Mn(HL3)+quinoline-2-aldehyde hydrazone]+ (calc. 609) with agreeing calculated isotropic pattems (Fig. 5.4). .03 ‘°° 214 1N—~ 704 fin? we =4_ - 651 sea ‘°'J sas 3°-_i eos mi I 112 " - "7 23° 521 353 eao an ‘ 1;; 101 400 as 561 32‘ 1°67 us ' ‘ no no 251 T52 rs: ea: 91:4 1200 1336 0 '—\ I zoo I |—‘l I I I |'I 400 I I I F_I I I coo ll I | I I I I | I 000 I I I I I I I-'F'r 1000 I I I I I | I I 1200 I I I I I I l"_T"I I I I I || Ihalfilp Fig. 5.3. MALDI MS spectrum of dimanganese(II) complex 20. as-2 an W :22 Isa I 612 511 825,2‘ 5 are "53 ‘ 024 lg.5 on 204 440 A 654 ”*~~——-~~~ 0 ; _ _ | Mu 441 ___mm IC Ma.uICl'n.I'ge 8 i iiii W 62$ 8 M._“;Chu.a. i"”“ H an an ' hat‘. Mu:ICha1'ge Muslcrntgg Fig. 5.4. Calculated agreeing isotropic distribution pattems of main peaks of 20.
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
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Ligands The ‘H and "C NMR spectra
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Ligands The ‘H NMR spectrum of HZ
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M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
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' | Ligands uo no 1&0 150 no no no
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Ligands Table 2. 3. Crystal data an
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Ligands The C-S bond distances of 1
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ligands between the planes of Cg(2)
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" F Ligands A indicates a typical d
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' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
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2.4.2. M TT Cell Proliferation Assa
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Table 2.9. Cell proliferation effec
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7 y _ i _ W Ligands B. Moubaraki, K
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CHAPTER Ni(II) complexes of carbohy
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_ _ __ g_ g W g H__ Ni(ll) complexe
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_ g A __ Ni(lI) complexes The reddi
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3.3. Results and discussion g_g _ N
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
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t§hqphw*3 v(Ni—S), further suppo
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Chapter 3 charge transfer bands. Fo
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Chapter 3 were refined anisotropica
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Chapter 3 3.3.3.1. Crystal structur
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Chapter 3 Table 3.7. Selected bond
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Chapter 3 N(l3)—C(35), N(2l)-C(58
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3.3.3.2. Crystal structures 0f[Ni(H
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Table 3.10. Selected bond lengths (
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Ni(lI) complexes significant 1t---1
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3.3.4. Magnetochemistry of the mole
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Ni(Il) complexes The allowed values
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in xn In
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g 7 Ni(Il) complexes 3.4. Concludin
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11 12 13 14 15 16 17 18 19 20 21 22
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41 42 43 44 45 46 47 48 49 50 51 52
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_ g “FOUR CHAPTER Cu(II) complexe
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_g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
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i ____ 3+ i --—- C 0pper(H) 2+ co
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C0pper(Il) complexes 499 100i ~04 7
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.04Copper(II) complexes 385 50.1I 1
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100-I 4 -1 U ” Q 7°-J 59-: "1
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C0pper(lI) complexes confirm the po
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C0pper(ll) complexes 100 80" I
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C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
Page 164: Copper(lI) complexes F1 = g",3B:S:
Page 167 and 168: Chapter 4 for both species consider
Page 169 and 170: Chapter 4 The spectrum of compound
Page 171 and 172: Chapter 4 stability alone could not
Page 173 and 174: Chapter 4 zénzénzénzénénaloeé
Page 175 and 176: Chapter 4 164 | | | 252 272 2Q 31 B
Page 177 and 178: Chapter 4 The shifting of g values
Page 179 and 180: Chapter 4 _|“. / "| 1' '| |' | 1'
Page 181 and 182: Chapter 4 The solid state and some
Page 183 and 184: Chapter 4 U 1 .I - O i I . I II I
Page 185 and 186: _ I Chapter 4 — I I I — I '
Page 187 and 188: . , Chapter 4 2.5 I I ' I ' I ' I '
Page 189 and 190: Chapter 4 The field dependence of m
Page 191 and 192: Chapter 4 Where ,1’ M is the magn
Page 193 and 194: Chapter 4 g e The powder and frozen
Page 195: Chapter 4 various aspects like bond
Page 198 and 199: C0pper(ll) complexes Table 4.6. Sel
Page 200 and 201: ,____ p _p C0pper(H) complexes from
Page 202 and 203: Ed. Engl. 31 (1992) 733. 7___7 7 7
Page 204 and 205: __ ,_ f W C 0pper(l1) complexes Che
Page 206 and 207: -_ FIVE CHAPTER Spectral and magnet
Page 208 and 209: __ g_ _g g H g __ Manganese(II) com
Page 210 and 211: q H _ Manganesefll) complexes [Mn2(
Page 212 and 213: Manganese(Il) complexes lcmzmoll in
Page 216 and 217: Manganese(II) complexes MALDI MS sp
Page 218 and 219: 5.3.2. EPR spectral studies Mangane
Page 220 and 221: Manganese(II) complexes D and E , e
Page 222 and 223: the pattern is uncertain and it is
Page 224 and 225: __ I . l r Manganese(II) complexes
Page 226: " |\ Man ganese(II) complexes 80" 6
Page 229 and 230: Chapter 5 thiocarbohydrazone comple
Page 231 and 232: Chapter 5 To fit and interpret the
Page 233 and 234: Chapter 5 #1 IT 0.00 1 — ‘ I '
Page 235 and 236: Chapter 5 The temperature dependenc
Page 237 and 238: Chapter 5 ___ M _ 357 (2004) 2694.
Page 239 and 240: Chapter5 p _ _ S. Sivakumar, Struct
Page 241 and 242: Chapter 6 _ _ __ 7 the latter have
Page 243 and 244: Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
Page 245 and 246: Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
Page 247 and 248: Chapter 6 / ‘~ ' if‘ . l \ N N/
Page 249 and 250: 1 | Chapter 6 100m__ ‘ 76$ mi, 16
Page 251 and 252: 3 - i El Q I Chapter 6 - '3“ 1999
Page 253 and 254: Chapter 6 The compound 27 exhibits
Page 255 and 256: (T71aq7tew'¢5 centered at 1711.9 c
Page 257 and 258: 1 . 1 Chapter 6 1244 100--1-; 1245
Page 259 and 260: Chapter 6 6.3.2. Electronic and IR
Page 261 and 262: Chapter 6 band at 19160 and 23920 c
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Zinc(II) & Cadmium(II) complexes Th
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.- 60- I ‘J TZinc(Il) & Cadmium(l
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Zinc(Il) & Cadmium(Il) complexes re
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Zinc(II) & C admium(ll) complexes T
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Fig. 6.25. The molecular structure
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Zinc(lI) & Cadmium(ll) complexes Al
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Zi!lC(II) & Cadmlum(II) C0mlexes Ta
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V _ i Zinc(1I) & Cadmium(lI) comple
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_ g _ g g V Zinc(lI) & Cadmiumfll)
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_, _ g pg L Summary and conclusion
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W g _ g mm Summary and conclusion a
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__ ,_ _ W A _ _ Summary and conclus
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Curriculum Vitae PERSONAL PROFILE N
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2-Hydroxyacetophenone 4-phenylthios
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