Self-assembled Transition Metal Coordination Frameworks of ...

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’ Ni(II) complexes Fig. 3.20. ORTEP diagram for the compound la with 50% probability ellipsoids. Hydrogen atoms, ethanol and lattice water molecules are omitted for clarity. N14 u I N16 Q \ A N24 N8 , / _.Ni4 Nu $31 N9 Ni3 . N32 KN11 $4 ‘ N6 J‘ N19 S2 . S1 y eN30 _ N17 101 N" 7- / V P N1 N25 N27 Fig. 3.21. The coordination core about Ni(II) centers of la with the numbering scheme showing the octahedral centers of Ni(II) connected by sulfur bridges.
Chapter 3 Table 3.7. Selected bond lengths (A) and angles (°) of [Ni(HL')]4(PF6)4 Ni(l)-N(3) 2.014(10) Ni(1)-N(27) 2.018(10) Ni(l)-N(l) 2.055(10) Ni(l)-N(25) 2.066(10) Ni(l)-S(2) 2.356(4) 1~11(1)-s(1) 2.405(4) Ni(2)-N(l9) 2.022(10) Ni(2)-N(6) 2.018(11) Ni(2)-N(8) 2.064(10) Ni(2)-N(l7) 2.073(11) Ni(2)-(S2) 2.356(4) Ni(2)-S(3) 2.422(4) Ni(3)-N(22) 2.011(10) Ni(3)-N(l4) 2.008(10) Ni(3)-N(l6) 2.048(10) Ni(3)-N(24) 2.073(11) Ni(3)-S(3) 2.398(4) 191(3)-s(4) 2.403(4) Ni(4)-N(3O) 2.023(10) Ni(4)-N(l 1) 2.033(10) Ni(4)-N(32) 2.061(11) Ni(4)-N(9) 2.079(11) Ni(4)-S(l) 2.382(4) Ni(4)-S(4) 2.411(4) s(1)-c(81) 1.748(13) s(2)-c(12) 1.735(14) 8(3)-c(58) s(4)c(35) 1.696(13) "1.732(13) N(3)-N(4) 1.374(14) N(4)-C(12) 1.347(16) N(5)-N(6) 1.343(14) N(5)-C(12) 1.349(17) N(l 1)-N(l2) 1.340(14) N(12)-C(35) 1.368(16) N(l3)-C(35) 1.338(16) N(l3)-N(l4) 1.355(14) 102 N(l9)-N(20) N(20)-C(58) N(21)-C(58) N(2l)-N(22) N(27)-N(28) 1~1(28)-c(81) N(29)-C(81) 1.338(14) 1.379(15) 1.349(15) 1.373(14) 1.355(14) 1.384(16) 1.324(16) N(29)-N(30) 1.380(14) N(3)-Ni(l)-N(27) 175.0(4) N(3)-Ni(l)-N(l) 79.5(5) N(27)-Ni(l)-N(l) 104.7(4) N(3)-Ni(1)-N(25) 98.2(4) N(27)-Ni(l)-N(25) 79.o(4) N(l)-Ni(1)-N(25) 95.3(4) N(3)-Ni(l)-S(2) 82.4(3) N(27)-Ni(l)-S(2) 93.4(3) N(l)-Ni(l)-S(2) 161.9(3) N(25)-Ni(l)-S(2) 87.9(3) N(3)-Ni(l)-S(l) 100.5(3) N(27)-Ni(l)-S(1) 82.3(3) N(l)-Ni(l)-S(l) 89.3(3) N(25)-Ni(l)-S(l) 161.3(3) S(2)-Ni(l)-S(l) 93.30(14) N(l9)-Ni(2)-N(6) 178.5(4) N(l9)-Ni(2)-N(8) 98.8(4) N(6)-Ni(2)-N(8) 79.6(5) N(19)-Ni(2)-N(17) 78.6(5) N(6)-Ni(2)-N(17) 101.4(5) N(8)-Ni(2)-N(l7) 93.1(4) N(19)-Ni(2)-S(2) 100.3(3) N(6)-Ni(2)-S(2) 81.2(3) N(8)-Ni(2)-S(2) 160.8(3) N(l7)-Ni(2)-S(2) 91.4(3) N(l9)-Ni(2)-S(3) 81.6(3) N(6)-Ni(2)-S(3) 98.3(3) N(8)-Ni(2)-S(3) 89.5(3) N(17)-Ni(2)-S(3) 160.2(4) S(2)-Ni(2)-S(3) 92.53(13) N(22)-Ni(3)-N(l4) 177.5(4) N(22)-Ni(3)-N(16) N(l4)-Ni(3)-N(l6) N(22)-Ni(3)-N(24) N(l4)-Ni(3)-N(24) N(l6)-Ni(3)-N(24) N(22)-Ni(3)-S(3) N(l4)-Ni(3)-S(3) N(l6)-Ni(3)-S(3) N(24)-Ni(3)-S(3) N(22)-Ni(3)-S(4) N(l4)-Ni(3)-S(4) N(l6)-Ni(3)-S(4) N(24)-Ni(3)-S(4) S(3)-Ni(3)-S(4) 989(4) 799(4) 79.6(4) 98.2(4) 91.9(4) 82.1(3) 100.1(3) 89.5(3) 161.6(3) 99.9(3) 81.4(3) 161.3(3) 91.1(3) 93.51(13) N(30)-Ni(4)-N(l 1) 179.3(4) N(30)-Ni(4)-N(32) 78.7(5) N ( 11 ) -Ni4-N () ( 32 ) 101.3 (4) N(30)-Ni(4)-N(9) 100.5(4) N(l 1)-Ni(4)-N(9) 78.8(5) N(32)-Ni(4)-N(9) 91.8(4) N(30)-Ni(4)-S(l) 82.4(3) 1~1(1 1)-141(4)-8(1) 97.6(3) N(32)-Ni(4)-S(l) 160.7(3) N(9)-Ni(4)-S(l) 88.1(3) N(30)-Ni(4)-S(4) 98.6(3) N(l 1)-191(4)-8(4) 82.1(3) N(32)-Ni(4)-S(4) 90.3(3) N(9)-Ni(4)-S(4) 160.8(3) S(l)-Ni(4)-S(4) 96.17(13) Ni(l)-S(2)-Ni(2) 166.30(18) Ni(3)-S(3)-Ni(2) 168.68(16) Ni(3)-S(4)-Ni(4) 165.30(17) Ni(4)-S(l)-Ni(1) 168_71(17)
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
Page 62 and 63: Ligands The ‘H and "C NMR spectra
Page 64 and 65: Ligands The ‘H NMR spectrum of HZ
Page 66 and 67: M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
Page 68 and 69: ' | Ligands uo no 1&0 150 no no no
Page 70 and 71: Ligands Table 2. 3. Crystal data an
Page 72 and 73: Ligands The C-S bond distances of 1
Page 74 and 75: ligands between the planes of Cg(2)
Page 76 and 77: " F Ligands A indicates a typical d
Page 78 and 79: ' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
Page 80 and 81: 2.4.2. M TT Cell Proliferation Assa
Page 82 and 83: Table 2.9. Cell proliferation effec
Page 84 and 85: 7 y _ i _ W Ligands B. Moubaraki, K
Page 86 and 87: CHAPTER Ni(II) complexes of carbohy
Page 88 and 89: _ _ __ g_ g W g H__ Ni(ll) complexe
Page 90 and 91: _ g A __ Ni(lI) complexes The reddi
Page 92 and 93: 3.3. Results and discussion g_g _ N
Page 94 and 95: 3.3.1. MALDI MS spectral studies of
Page 96 and 97: Ni(Il) complexes In the case of com
Page 98 and 99: 100 U-
Page 100: 3.3.2. IR and electronic spectral s
Page 103 and 104: Chapter 3 The electronic spectra of
Page 105 and 106: t§hqphw*3 v(Ni—S), further suppo
Page 107 and 108: Chapter 3 charge transfer bands. Fo
Page 109 and 110: Chapter 3 were refined anisotropica
Page 111: Chapter 3 3.3.3.1. Crystal structur
Page 115 and 116: Chapter 3 N(l3)—C(35), N(2l)-C(58
Page 118 and 119: 3.3.3.2. Crystal structures 0f[Ni(H
Page 120 and 121: Table 3.10. Selected bond lengths (
Page 122 and 123: Ni(lI) complexes significant 1t---1
Page 124 and 125: 3.3.4. Magnetochemistry of the mole
Page 126 and 127: Ni(Il) complexes The allowed values
Page 128 and 129: in xn In
Page 130 and 131: g 7 Ni(Il) complexes 3.4. Concludin
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Page 136 and 137: _ g “FOUR CHAPTER Cu(II) complexe
Page 138 and 139: _g C0pper(II) complexes complex of
Page 140 and 141: _ _ , p f 7, Copper-(II) complexes
Page 142 and 143: pp g _g _4_,_ C0pper(II) complexes
Page 144 and 145: g _,_,_ g g Copperfll) complexes in
Page 146 and 147: i ____ 3+ i --—- C 0pper(H) 2+ co
Page 148 and 149: C0pper(Il) complexes 499 100i ~04 7
Page 150 and 151: .04Copper(II) complexes 385 50.1I 1
Page 152 and 153: 100-I 4 -1 U ” Q 7°-J 59-: "1
Page 154: C0pper(lI) complexes confirm the po
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Page 160 and 161: C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
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Copper(lI) complexes F1 = g",3B:S:
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Chapter 4 for both species consider
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Chapter 4 The spectrum of compound
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Chapter 4 stability alone could not
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Chapter 4 zénzénzénzénénaloeé
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Chapter 4 164 | | | 252 272 2Q 31 B
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Chapter 4 The shifting of g values
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Chapter 4 _|“. / "| 1' '| |' | 1'
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Chapter 4 The solid state and some
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Chapter 4 U 1 .I - O i I . I II I
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_ I Chapter 4 — I I I — I '
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. , Chapter 4 2.5 I I ' I ' I ' I '
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Chapter 4 The field dependence of m
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Chapter 4 Where ,1’ M is the magn
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Chapter 4 g e The powder and frozen
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Chapter 4 various aspects like bond
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C0pper(ll) complexes Table 4.6. Sel
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,____ p _p C0pper(H) complexes from
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Ed. Engl. 31 (1992) 733. 7___7 7 7
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__ ,_ f W C 0pper(l1) complexes Che
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-_ FIVE CHAPTER Spectral and magnet
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__ g_ _g g H g __ Manganese(II) com
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q H _ Manganesefll) complexes [Mn2(
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Manganese(Il) complexes lcmzmoll in
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1W3 "l U 70 60 40 30 10 490 740 979
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Manganese(II) complexes MALDI MS sp
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5.3.2. EPR spectral studies Mangane
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Manganese(II) complexes D and E , e
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the pattern is uncertain and it is
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__ I . l r Manganese(II) complexes
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" |\ Man ganese(II) complexes 80" 6
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Chapter 5 thiocarbohydrazone comple
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Chapter 5 To fit and interpret the
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Chapter 5 #1 IT 0.00 1 — ‘ I '
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Chapter 5 The temperature dependenc
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Chapter 5 ___ M _ 357 (2004) 2694.
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Chapter5 p _ _ S. Sivakumar, Struct
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Chapter 6 _ _ __ 7 the latter have
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Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
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Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
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Chapter 6 / ‘~ ' if‘ . l \ N N/
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1 | Chapter 6 100m__ ‘ 76$ mi, 16
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3 - i El Q I Chapter 6 - '3“ 1999
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Chapter 6 The compound 27 exhibits
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(T71aq7tew'¢5 centered at 1711.9 c
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1 . 1 Chapter 6 1244 100--1-; 1245
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Chapter 6 6.3.2. Electronic and IR
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Chapter 6 band at 19160 and 23920 c
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Zinc(II) & Cadmium(II) complexes Th
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.- 60- I ‘J TZinc(Il) & Cadmium(l
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Zinc(Il) & Cadmium(Il) complexes re
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Zinc(II) & C admium(ll) complexes T
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Fig. 6.25. The molecular structure
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Zinc(lI) & Cadmium(ll) complexes Al
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Zi!lC(II) & Cadmlum(II) C0mlexes Ta
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V _ i Zinc(1I) & Cadmium(lI) comple
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_ g _ g g V Zinc(lI) & Cadmiumfll)
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_, _ g pg L Summary and conclusion
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W g _ g mm Summary and conclusion a
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__ ,_ _ W A _ _ Summary and conclus
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Curriculum Vitae PERSONAL PROFILE N
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2-Hydroxyacetophenone 4-phenylthios
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