Self-assembled Transition Metal Coordination Frameworks of ...

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_ g A __ Ni(lI) complexes The reddish brown color on adding NiCl2 was found to change into orange on adding NH4PF6, which changed to brown on refluxion. The brown powder precipitated after 2 days were filtered, washed with methanol and ether, recrystallized in acetonitrile: ethanol mixture and dried in vacuo over P4010. Yield: 0.430 g (78%). Elemental Anal. Found (Calc.): C, 46.57 (46.22); H, 3.15 (3.33); N, 15.09 (15.40); S, 6.00 (5.88)%. [N»'(HL‘)14(PF.).- 12H20 (3) To a hot solution of HZL4 (0.424 g, 1 mmol) in 50 ml methanol was added an equimolar amount of nicl
Chapter 3 i _ g_ H if 7 7 _, g methanol and ether and dried in vacuo over P40“). Yield: 0.100 g (57%). Elemental analysis: Found (calc.): C, 51.46 (51.60); 1-1, 5.01 (4.62); N, 16.17 (16.05); S, 9.09 (9.18)%. Crystals suitable for X-ray analysis were obtained by slow evaporation of a methanol solution of 5 in air. The complex 5 crystallized as [Ni(HL7)2]C12' 2‘/zH2O (5' 2‘/1H2O). [Ni(HL”)L"‘] (:10. 71120 (6) To a hot solution of HL8 (0.186 g, 0.6 mmol) in 10 ml chloroform was added an equimolar amount of nicke1(11) perchlorate hexahydrate (0.220 g) dissolved in 20 ml hot methanol. The mixture was refluxed for an hour and allowed to stand at room temperature. The reddish brown crystals precipitated were filtered, washed with methanol and ether. It was then dried in vacuo over P.,O|0. Yield: 210 g (78%). Elemental analysis: Found (calc.): C, 44.65 (45.17); H, 5.32 (5.46); N, 12.28 (12.39); S, 6.83 (7.09)%. XRD quality single crystals were obtained by slow evaporation of a solution of the compound in DMSO. The complex 6 got crystallized with deprotonation, of HL8 in 6, to form a new complex [Ni(L8)2] (6a). [NiL”Cl]- 1/21120 (7) To a hot solution of HL8 (0.186 g, 0.6 mmol) in 10 ml chloroform was added an equimolar amount of nicke1(1I) chloride hexahydrate (0.143 g) dissolved in 20 ml hot methanol. The mixture was refluxed for an hour and allowed to stand at room temperature. The reddish brown compound precipitated was filtered, washed with methanol and ether and then dried in vac:-:0 over P4010. Yield: 0.138 g (56%). Elemental analysis: Found (calc.): C, 49.94 (49.49); H, 4.15 (4.40); N, 13.75 (13.58); S, 7.72 (7.77)%. 80
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
Page 39 and 40: Chapter I W _ _ Traditional magnets
Page 41 and 42: Chapter I L.K. Thompson, O. Waldman
Page 43 and 44: Chapter I i __ _ Org. Chem. 31 (200
Page 45 and 46: Chapter In _g , g H g 85. S. Padhye
Page 47 and 48: Chapter 2 1 g anticipation of Cu(H)
Page 49 and 50: Chapter 2 _. M_ _ up 1. Quinoline-2
Page 51 and 52: Chapter 2 chloroform solution and d
Page 53 and 54: Chapter2 V _ _ _ _, 7 _ with aceton
Page 55: Chapter 2 _ 7 f __ i 2.3. Results a
Page 58 and 59: 100s0- I > J 20
Page 60 and 61: — — 1 Ligands 1
Page 62 and 63: Ligands The ‘H and "C NMR spectra
Page 64 and 65: Ligands The ‘H NMR spectrum of HZ
Page 66 and 67: M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
Page 68 and 69: ' | Ligands uo no 1&0 150 no no no
Page 70 and 71: Ligands Table 2. 3. Crystal data an
Page 72 and 73: Ligands The C-S bond distances of 1
Page 74 and 75: ligands between the planes of Cg(2)
Page 76 and 77: " F Ligands A indicates a typical d
Page 78 and 79: ' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
Page 80 and 81: 2.4.2. M TT Cell Proliferation Assa
Page 82 and 83: Table 2.9. Cell proliferation effec
Page 84 and 85: 7 y _ i _ W Ligands B. Moubaraki, K
Page 86 and 87: CHAPTER Ni(II) complexes of carbohy
Page 88 and 89: _ _ __ g_ g W g H__ Ni(ll) complexe
Page 92 and 93: 3.3. Results and discussion g_g _ N
Page 94 and 95: 3.3.1. MALDI MS spectral studies of
Page 96 and 97: Ni(Il) complexes In the case of com
Page 98 and 99: 100 U-
Page 100: 3.3.2. IR and electronic spectral s
Page 103 and 104: Chapter 3 The electronic spectra of
Page 105 and 106: t§hqphw*3 v(Ni—S), further suppo
Page 107 and 108: Chapter 3 charge transfer bands. Fo
Page 109 and 110: Chapter 3 were refined anisotropica
Page 111 and 112: Chapter 3 3.3.3.1. Crystal structur
Page 113 and 114: Chapter 3 Table 3.7. Selected bond
Page 115 and 116: Chapter 3 N(l3)—C(35), N(2l)-C(58
Page 118 and 119: 3.3.3.2. Crystal structures 0f[Ni(H
Page 120 and 121: Table 3.10. Selected bond lengths (
Page 122 and 123: Ni(lI) complexes significant 1t---1
Page 124 and 125: 3.3.4. Magnetochemistry of the mole
Page 126 and 127: Ni(Il) complexes The allowed values
Page 128 and 129: in xn In
Page 130 and 131: g 7 Ni(Il) complexes 3.4. Concludin
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Page 134 and 135: 41 42 43 44 45 46 47 48 49 50 51 52
Page 136 and 137: _ g “FOUR CHAPTER Cu(II) complexe
Page 138 and 139: _g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
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i ____ 3+ i --—- C 0pper(H) 2+ co
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C0pper(Il) complexes 499 100i ~04 7
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.04Copper(II) complexes 385 50.1I 1
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100-I 4 -1 U ” Q 7°-J 59-: "1
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C0pper(lI) complexes confirm the po
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C0pper(ll) complexes 100 80" I
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C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
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Copper(lI) complexes F1 = g",3B:S:
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Chapter 4 for both species consider
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Chapter 4 The spectrum of compound
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Chapter 4 stability alone could not
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Chapter 4 zénzénzénzénénaloeé
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Chapter 4 164 | | | 252 272 2Q 31 B
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Chapter 4 The shifting of g values
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Chapter 4 _|“. / "| 1' '| |' | 1'
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Chapter 4 The solid state and some
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Chapter 4 U 1 .I - O i I . I II I
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_ I Chapter 4 — I I I — I '
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. , Chapter 4 2.5 I I ' I ' I ' I '
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Chapter 4 The field dependence of m
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Chapter 4 Where ,1’ M is the magn
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Chapter 4 g e The powder and frozen
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Chapter 4 various aspects like bond
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C0pper(ll) complexes Table 4.6. Sel
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,____ p _p C0pper(H) complexes from
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Ed. Engl. 31 (1992) 733. 7___7 7 7
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__ ,_ f W C 0pper(l1) complexes Che
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-_ FIVE CHAPTER Spectral and magnet
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__ g_ _g g H g __ Manganese(II) com
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q H _ Manganesefll) complexes [Mn2(
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Manganese(Il) complexes lcmzmoll in
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1W3 "l U 70 60 40 30 10 490 740 979
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Manganese(II) complexes MALDI MS sp
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5.3.2. EPR spectral studies Mangane
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Manganese(II) complexes D and E , e
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the pattern is uncertain and it is
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__ I . l r Manganese(II) complexes
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" |\ Man ganese(II) complexes 80" 6
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Chapter 5 thiocarbohydrazone comple
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Chapter 5 To fit and interpret the
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Chapter 5 #1 IT 0.00 1 — ‘ I '
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Chapter 5 The temperature dependenc
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Chapter 5 ___ M _ 357 (2004) 2694.
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Chapter5 p _ _ S. Sivakumar, Struct
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Chapter 6 _ _ __ 7 the latter have
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Chapter6A, 0 0 _, 0 0 _* 4, W 0 0 0
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Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
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Chapter 6 / ‘~ ' if‘ . l \ N N/
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1 | Chapter 6 100m__ ‘ 76$ mi, 16
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3 - i El Q I Chapter 6 - '3“ 1999
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Chapter 6 The compound 27 exhibits
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(T71aq7tew'¢5 centered at 1711.9 c
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1 . 1 Chapter 6 1244 100--1-; 1245
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Chapter 6 6.3.2. Electronic and IR
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Chapter 6 band at 19160 and 23920 c
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Zinc(II) & Cadmium(II) complexes Th
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.- 60- I ‘J TZinc(Il) & Cadmium(l
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Zinc(Il) & Cadmium(Il) complexes re
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Zinc(II) & C admium(ll) complexes T
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Fig. 6.25. The molecular structure
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Zinc(lI) & Cadmium(ll) complexes Al
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Zi!lC(II) & Cadmlum(II) C0mlexes Ta
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V _ i Zinc(1I) & Cadmium(lI) comple
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_ g _ g g V Zinc(lI) & Cadmiumfll)
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_, _ g pg L Summary and conclusion
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W g _ g mm Summary and conclusion a
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__ ,_ _ W A _ _ Summary and conclus
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Curriculum Vitae PERSONAL PROFILE N
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2-Hydroxyacetophenone 4-phenylthios
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Self-assembled Transition Metal Coordination Frameworks of ...

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