Self-assembled Transition Metal Coordination Frameworks of ...

Chapter 3
Table 3.7. Selected bond lengths (A) and angles (°) of [Ni(HL')]4(PF6)4
Ni(l)-N(3) 2.014(10)
Ni(1)-N(27) 2.018(10)
Ni(l)-N(l) 2.055(10)
Ni(l)-N(25) 2.066(10)
Ni(l)-S(2) 2.356(4)
1~11(1)-s(1) 2.405(4)
Ni(2)-N(l9) 2.022(10)
Ni(2)-N(6) 2.018(11)
Ni(2)-N(8) 2.064(10)
Ni(2)-N(l7) 2.073(11)
Ni(2)-(S2) 2.356(4)
Ni(2)-S(3) 2.422(4)
Ni(3)-N(22) 2.011(10)
Ni(3)-N(l4) 2.008(10)
Ni(3)-N(l6) 2.048(10)
Ni(3)-N(24) 2.073(11)
Ni(3)-S(3) 2.398(4)
191(3)-s(4) 2.403(4)
Ni(4)-N(3O) 2.023(10)
Ni(4)-N(l 1) 2.033(10)
Ni(4)-N(32) 2.061(11)
Ni(4)-N(9) 2.079(11)
Ni(4)-S(l) 2.382(4)
Ni(4)-S(4) 2.411(4)
s(1)-c(81) 1.748(13)
s(2)-c(12) 1.735(14)
8(3)-c(58)
s(4)c(35)
1.696(13)
"1.732(13)
N(3)-N(4) 1.374(14)
N(4)-C(12) 1.347(16)
N(5)-N(6) 1.343(14)
N(5)-C(12) 1.349(17)
N(l 1)-N(l2) 1.340(14)
N(12)-C(35) 1.368(16)
N(l3)-C(35) 1.338(16)
N(l3)-N(l4) 1.355(14)
102
N(l9)-N(20)
N(20)-C(58)
N(21)-C(58)
N(2l)-N(22)
N(27)-N(28)
1~1(28)-c(81)
N(29)-C(81)
1.338(14)
1.379(15)
1.349(15)
1.373(14)
1.355(14)
1.384(16)
1.324(16)
N(29)-N(30) 1.380(14)
N(3)-Ni(l)-N(27) 175.0(4)
N(3)-Ni(l)-N(l) 79.5(5)
N(27)-Ni(l)-N(l) 104.7(4)
N(3)-Ni(1)-N(25) 98.2(4)
N(27)-Ni(l)-N(25) 79.o(4)
N(l)-Ni(1)-N(25) 95.3(4)
N(3)-Ni(l)-S(2) 82.4(3)
N(27)-Ni(l)-S(2) 93.4(3)
N(l)-Ni(l)-S(2) 161.9(3)
N(25)-Ni(l)-S(2) 87.9(3)
N(3)-Ni(l)-S(l) 100.5(3)
N(27)-Ni(l)-S(1) 82.3(3)
N(l)-Ni(l)-S(l) 89.3(3)
N(25)-Ni(l)-S(l) 161.3(3)
S(2)-Ni(l)-S(l) 93.30(14)
N(l9)-Ni(2)-N(6) 178.5(4)
N(l9)-Ni(2)-N(8) 98.8(4)
N(6)-Ni(2)-N(8) 79.6(5)
N(19)-Ni(2)-N(17) 78.6(5)
N(6)-Ni(2)-N(17) 101.4(5)
N(8)-Ni(2)-N(l7) 93.1(4)
N(19)-Ni(2)-S(2) 100.3(3)
N(6)-Ni(2)-S(2) 81.2(3)
N(8)-Ni(2)-S(2) 160.8(3)
N(l7)-Ni(2)-S(2) 91.4(3)
N(l9)-Ni(2)-S(3) 81.6(3)
N(6)-Ni(2)-S(3) 98.3(3)
N(8)-Ni(2)-S(3) 89.5(3)
N(17)-Ni(2)-S(3) 160.2(4)
S(2)-Ni(2)-S(3) 92.53(13)
N(22)-Ni(3)-N(l4) 177.5(4)
N(22)-Ni(3)-N(16)
N(l4)-Ni(3)-N(l6)
N(22)-Ni(3)-N(24)
N(l4)-Ni(3)-N(24)
N(l6)-Ni(3)-N(24)
N(22)-Ni(3)-S(3)
N(l4)-Ni(3)-S(3)
N(l6)-Ni(3)-S(3)
N(24)-Ni(3)-S(3)
N(22)-Ni(3)-S(4)
N(l4)-Ni(3)-S(4)
N(l6)-Ni(3)-S(4)
N(24)-Ni(3)-S(4)
S(3)-Ni(3)-S(4)
989(4)
799(4)
79.6(4)
98.2(4)
91.9(4)
82.1(3)
100.1(3)
89.5(3)
161.6(3)
99.9(3)
81.4(3)
161.3(3)
91.1(3)
93.51(13)
N(30)-Ni(4)-N(l 1) 179.3(4)
N(30)-Ni(4)-N(32) 78.7(5)
N ( 11 ) -Ni4-N () ( 32 ) 101.3 (4)
N(30)-Ni(4)-N(9) 100.5(4)
N(l 1)-Ni(4)-N(9) 78.8(5)
N(32)-Ni(4)-N(9) 91.8(4)
N(30)-Ni(4)-S(l) 82.4(3)
1~1(1 1)-141(4)-8(1) 97.6(3)
N(32)-Ni(4)-S(l) 160.7(3)
N(9)-Ni(4)-S(l) 88.1(3)
N(30)-Ni(4)-S(4) 98.6(3)
N(l 1)-191(4)-8(4) 82.1(3)
N(32)-Ni(4)-S(4) 90.3(3)
N(9)-Ni(4)-S(4) 160.8(3)
S(l)-Ni(4)-S(4) 96.17(13)
Ni(l)-S(2)-Ni(2) 166.30(18)
Ni(3)-S(3)-Ni(2) 168.68(16)
Ni(3)-S(4)-Ni(4) 165.30(17)
Ni(4)-S(l)-Ni(1) 168_71(17)