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Self-assembled Transition Metal Coordination Frameworks of ...

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CONTENTS<br />

CHAPTER 1<br />

Introduction to carbohydrazones, thiocarbohydrazones and self<strong>assembled</strong><br />

transition metal coordination frameworks<br />

1 .1 . General introduction<br />

1.2. <strong>Coordination</strong> frameworks - A brief introduction<br />

1.2.1. The method <strong>of</strong> self-assembly<br />

1.2.2. <strong>Metal</strong>losupramolecular squares<br />

1.2.2.1 Characterization <strong>of</strong> molecular squares<br />

1.3. A preface on carbohydrazones and thiocarbohydrazones<br />

1.3.1. Applications <strong>of</strong> carbohydrazones and thiocarbohydrazones<br />

1.3.1.1. Anticancer drugs - A brief report<br />

1.4. Importance <strong>of</strong> carbohydrazones and thiocarbohydrazones<br />

1.5. Objectives <strong>of</strong> the present work<br />

1.6. Physico-chemical techniques<br />

1.6.1. Elemental analyses and conductivity measurements<br />

1.6.2. NMR spectra<br />

1.6.3. Electronic spectra<br />

1.6.4. IR spectra<br />

1.6.5. Single crystal X-ray crystallography<br />

1.6.6. MALDI MS spectrometry<br />

1.6.7. EPR spectroscopy<br />

1 .6.8. Magnetochemistry<br />

References<br />

CHAPTER 2<br />

Carbohydrazone, thiocarbohydrazone and thiosemicarbazone<br />

ligands: Structural, spectral and anticancer properties<br />

2.1 . Introduction<br />

2.2. Experimental<br />

2.3. Results and discussion<br />

2.3.1. IR spectral studies<br />

2.3.2. Electronic spectral studies<br />

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