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Self-assembled Transition Metal Coordination Frameworks of ...

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2.5<br />

2.0<br />

1.5­<br />

0.5 —<br />

I O<br />

_ . . .. .‘......I..OOQOl(UQQl.OlI ­<br />

0.002047<br />

0.002046<br />

0.002045<br />

0.002044<br />

. — 0.002043<br />

IIQ..O....O'.I."...I..‘O I I0 0<br />

0.0-1<br />

| I | I | I | I | I | I | I | I 0.002042<br />

0 50 1 00 1 50 200 250 300 350<br />

T (K)<br />

O -. ­<br />

Fig. 4.42. Effective magnetic moment pd; (I) and molar magnetic susceptibility Xm<br />

(0) data as a function <strong>of</strong> temperature for 10.<br />

I ' I ' I ' I ' I ' I ' I ' I<br />

2.0 —<br />

1.5- - 0 O I‘ -I ' ‘<br />

. — 0.0024<br />

I-.­<br />

_<br />

I<br />

— 0.0021<br />

I.I<br />

O. §_{<br />

I<br />

- 0.001<br />

1.0­ O I<br />

- O . OQ _<br />

OOOO o@°°°°o - 0.0015<br />

0.5 1<br />

OOQ<br />

an<br />

I | I | I | I | I | I | I | I | I<br />

0 50 100 1 50 200 250 300 350<br />

T (K)<br />

C0pper(II) complexes<br />

0.0012<br />

Fig. 4.43. Temperature dependence <strong>of</strong> effective magnetic moment pdf (n) and <strong>of</strong><br />

molar magnetic susceptibility X,“ (0) <strong>of</strong> complex ll<br />

.­II/\<br />

\-/

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