Self-assembled Transition Metal Coordination Frameworks of ...

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Chapter 4 146 100..‘ r “ .\‘\ 80 60 40 20 9 "T ' | ' | ' | ' | ' | ' I ' | 4000 3500 3000 2500 2000 1 500 1 000 500 Wavenumber (cm"l 20 Fig. 4.10. IR spectrum of thiocarbohydrazone Cu(II) complex 8. 10-f60un 600 500 400 300 200 1 I00 Wavenumber (cm") Fig. 4.11. Far IR spectrum of thiocarbohydrazone Cu(II) complex 8 100ao 40— 0 -| | | I | | | | | | | 0 20 0 "| ' I I | ' | ' | ' I ' | ' I 4000 3500 3000 2500 2000 1 500 1 000 Wavenumber (cm") Fig. 4.12. IR spectrum of thiocarbohydrazone Cu(lI) complex 9.
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
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Ligands The ‘H and "C NMR spectra
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Ligands The ‘H NMR spectrum of HZ
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M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
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' | Ligands uo no 1&0 150 no no no
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Ligands Table 2. 3. Crystal data an
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Ligands The C-S bond distances of 1
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ligands between the planes of Cg(2)
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" F Ligands A indicates a typical d
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' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
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2.4.2. M TT Cell Proliferation Assa
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Table 2.9. Cell proliferation effec
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7 y _ i _ W Ligands B. Moubaraki, K
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CHAPTER Ni(II) complexes of carbohy
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_ _ __ g_ g W g H__ Ni(ll) complexe
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_ g A __ Ni(lI) complexes The reddi
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3.3. Results and discussion g_g _ N
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
Page 105 and 106: t§hqphw*3 v(Ni—S), further suppo
Page 107 and 108: Chapter 3 charge transfer bands. Fo
Page 109 and 110: Chapter 3 were refined anisotropica
Page 111 and 112: Chapter 3 3.3.3.1. Crystal structur
Page 113 and 114: Chapter 3 Table 3.7. Selected bond
Page 115 and 116: Chapter 3 N(l3)—C(35), N(2l)-C(58
Page 118 and 119: 3.3.3.2. Crystal structures 0f[Ni(H
Page 120 and 121: Table 3.10. Selected bond lengths (
Page 122 and 123: Ni(lI) complexes significant 1t---1
Page 124 and 125: 3.3.4. Magnetochemistry of the mole
Page 126 and 127: Ni(Il) complexes The allowed values
Page 128 and 129: in xn In
Page 130 and 131: g 7 Ni(Il) complexes 3.4. Concludin
Page 132 and 133: 11 12 13 14 15 16 17 18 19 20 21 22
Page 134 and 135: 41 42 43 44 45 46 47 48 49 50 51 52
Page 136 and 137: _ g “FOUR CHAPTER Cu(II) complexe
Page 138 and 139: _g C0pper(II) complexes complex of
Page 140 and 141: _ _ , p f 7, Copper-(II) complexes
Page 142 and 143: pp g _g _4_,_ C0pper(II) complexes
Page 144 and 145: g _,_,_ g g Copperfll) complexes in
Page 146 and 147: i ____ 3+ i --—- C 0pper(H) 2+ co
Page 148 and 149: C0pper(Il) complexes 499 100i ~04 7
Page 150 and 151: .04Copper(II) complexes 385 50.1I 1
Page 152 and 153: 100-I 4 -1 U ” Q 7°-J 59-: "1
Page 154: C0pper(lI) complexes confirm the po
Page 159 and 160: Chapter 4 4.3.3. Electronic spectra
Page 161 and 162: Chapter 4 o'a6o 20 l 300 400 500 00
Page 163 and 164: Chapter 4 4.3.4. EPR spectral studi
Page 166 and 167: C0pper(II) complexes The spectrum o
Page 168 and 169: the biomimetic (N, O or S) donors r
Page 170 and 171: Copper(Il) complexes different spec
Page 172 and 173: l F/’ Copper(II) complexes l L .1
Page 174 and 175: C0pper(II) complexes The carbohydra
Page 176 and 177: J K” ‘ | | | | | | | 263 2&3 3]
Page 178 and 179: C 0pper( II ) complexes rise to rho
Page 180 and 181: V,‘ _| _I> I / tux '1'] V /fr
Page 182 and 183: C0pper(ll) complexes The room tempe
Page 184 and 185: 2.5 2.0 1.5 0.5 — I O _ . . ..
Page 186 and 187: _ - |'|'|'|'|'|'|'1' I C0pper(II)
Page 188 and 189: 2.5 — 2.0 1.5 — 1.0- I I '1‘
Page 190 and 191: Copper(II) complexes When two or mo
Page 192 and 193: C 0pper( ll ) complexes bis[(1E)-1-
Page 194 and 195: C0pper(II) complexes The powder spe
Page 197 and 198: Chapter 4 Table 4.5. Crystal data a
Page 199 and 200: Chapter 4 Table 4.7. Cell survival
Page 201 and 202: Chapter 4 _ g g ,4 pp if magnetic s
Page 203 and 204: Chapter 4 g _, 17 18 19 20 21 22 23
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Chapter 4 7 W *_ ?_ _ _ 53. Y.D. La
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Chapter 5 _ g _ g g _g_ g _g magnet
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Chapter5 __ ,4 4 4 4 __ _, after th
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Chapter 5 _ H _ g g A temperature,
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Chapter 5 5.3.1. AIALDI MS spectral
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Chapter 5 The spectrum of 20 shows
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Chapter 5 The peaks of complex 22 a
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Chapter 5 lower than cubic. However
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Chapter 5 value of 265 MI-lz (94.9
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Chapter 5 Broad signals above g=2,
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Chapter 5 5.3.3. IR and electronic
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Manganese(ll) complexes .l 70 60
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5.3.4. Magnetochemistry Manganese(l
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Manganese(lI) complexes The best-fi
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ml lManganese(Il) complexes 4-5 "I
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W 7 N A _ gm g_ g Manganesefll) com
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_, f _ ,_ Manganesefll) complexes L
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_ {{{{ o SIX CHAPTER Self-assembled
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pg p_ g g _ Zinc(lI) & Cadmiumfll)
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g pg __ V g A Zinc(II) & Cadmium(II
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__ A A A __AA_*_Ag Zinc(Il) & Cadmi
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6.3.1 . MALDI MS spectral studies Z
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Zinc(Il) & Cadmium(lI) complexes 24
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Zinc(lI) & Cadmium(lI) complexes -
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Zinc(ll) & Cadmium(II) complexes di
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Zinc(II) & Cadmium(Il) complexes m
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ml ~81 70 ‘O . 30. 1. I00. 50 108
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08 ‘ 00 0.0 07 06 05 Zinc(lI) &
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Zinc(II) & Cadmium(Il) complexes Th
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Chapter 6 with v |(B—F) at ~777 c
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Chapter 6 strong v(C=S) bands of fr
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Chapter 6 6.3.3.1. Crystal structur
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Chapter 6 comparatively greater tha
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Chapter 6 Zn(4)=9O.78(l)°}. The Zn
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Chapter 6 In the crystal packing (F
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Chapter 6 H 6.4. Concluding remarks
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Chapter6 H f f _ j i W f W ‘ ,_ A
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Chapter 6 j ,_ , 40. A.L. Spek,Acta
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4. 1,5-Bis(di-2-pyridyl ketone) car
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g g 7 g Self-Assembled Transition M
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A Self-Assembled Transition Metal C
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RESEARCH PUBLICATIONS Structural an
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