Self-assembled Transition Metal Coordination Frameworks of ...

Chapter 4
for both species considered, which points towards a dx3_ _, ground state [36].
Generally, the variation in the g values indicate that the geometry around Cu(H)
centers are affected by the nature of the coordinating anions.
The geometric parameters G , empirical factor f and in-plane sigma bonding
parameter 4, exchange
interaction is negligible and if it is less than 4, considerable exchange interaction is
indicated in the solid complex [1]. Though, the two Cu(H) centers are not coupled
enough the possibility of presence of other Cu(H) centers of a second molecule may
cause considerable exchange interactions, which is usually less possible in solution.
Most of the G values calculated are greater than four and the exchange interaction of
that complexes are negligible. The value of in plane sigma bonding parameter