Self-assembled Transition Metal Coordination Frameworks of ...

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Zinc(lI) & Cadmium(ll) complexes All molecules are intercomiected by a number of hydrogen bonding interactions (Table 6.6, Fig. 6.27) to form a three dimensional motif in the lattice. 6 085 212 162 Table 6.6. Hydrogen bonding interactions of complex 29. Residue D—H---A D-H(A) H---A(A) D---A(A) D—H---A (°) O(lW)—H(lWl) ...1:(13) 2.944(9) 6 O(lW)—H(2Wl) '"O(l0W) 0.85 2.21 2.847(7) O(3W)—H(lW3) ...p(11) O(3W)—H(2W3) ...O(5w)= N(4)—H(4B)-'-O(8W)° O(4W)—H(lW4) ...()(7w) 1.00 0.86 0.86 0.85 1.84 2.00 2.12 2.03 2.813(5) 2.798(6) 2.885(5) 2.768(5) O(4W)—H(2W4) ...O(8w) O(5W)—H(lW5) ...F(3) O(5W)—H(2W5) ...F(9) 0.85 0.85 0.85 2.10 2.10 2.43 2.950(5) 2.944(6) 3.097(9) O(5W)—H(2W5) ...F(1O) O(6W)—H(1W6) ...O(7w) 0.85 0.85 2.30 2.36 3.044(7) 3.051(6) O(6W)—H(2W6) ...O(2w) N(l0)—H(l0C)-- o(9w)° o(7w)-11(1w7) ---N(15)" 0.85 0.86 0.85 2.16 2.15 2.46 2.782(6) 2.917(4) 3.006(5) O(7W)—H(2W7) ...0(6w) 0.85 2.21 3.051(6) O(8W)—H(1W8) ...l::(7) 0.85 2.02 2.760(7) o(8w)-11(2w8) ...0(4w) o(9w)-11(2w9) ---F(l 5)‘ N(l6)—H(16B)--o(7w)° 15 O(l0W)-H(lWA)---N(2l)’ N(22)—H(22B)--o(10w)“ 0.85 0.84 0.86 0.90 0.86 2.15 2.29 2.01 2.41 2.09 2.950(5) 2.847(6) 2.791(5) 2.991(5) 2.801(5) C(2)—H(2A)---F( 1)‘ 0.93 2.51 3.224(6) C(4)—H(4A)---F( 1) 0.93 2.52 3.261(5) C(l2)—H(l2A)--F(9)° 0.93 2.53 3.337(7) C(2O)—H(20A)--o(2w)@ C(23)—H(23A)--F(3)° 0.93 0.93 2.45 2.49 3.358(6) 3.207(6) C(25)—H(25A)--1=(16)" C(27)—H(27A)--F(5)° C(29)—H(29A)--F(9)" 0.93 0.93 0.93 2.43 2.49 2.50 3.224(6) 3.258(6) 3.235(9) C(54)—H(54A)--F(4)° 0.93 2.46 3.166(5) C(68)—H(68A)--o(10w)= 0.93 2.51 3.418(6) C(7O)—H(7OA)--N(3)* 0.93 2.58 3.498(6) C(72)—H(72A)--F(3) 0.93 2.51 3.163(6) C(73)—H(73A)--F(2) 0.93 2.41 3.270(5) C(76)—H(76A)--o(2w)° 1 C(95)—H(95A)-- F(4)f 0.93 0.93 2.58 2.41 3.263(6) 3.305(6) D= donor, A= acceptor; * intramolecular; Eqivalent position codes: a= '/z+x, 3/2-y, 1-z; b= 2-x, -l/2+ y, l/2-z; c= 2-x, 1/2+y, 1/2-z; d= -1/2+x, 3/2-y, 1-z; e= 2-x, -1/2+y, 3/2-z; f= 1/2+x, 3/2-y, -z; g= x, 1+y, z; h= 3/2-x, 2-y, -1/2+2. 263
Chapter 6 In the crystal packing (Fig. 6.27) molecules are arranged along the a axis The packing is directed by various C—H---7: interactions, in addition to hydrogen bond1ng networks including water and BF4' anions. The crystal structure cohesion may also be reinforced by weak 7:---1: interactions. The interactions are given in Tables 6 7 and 6 8 Table 6.7. 7t--~7t interactions seen in the crystal packing of square complex 29 C8(I)~"C8(J) 969614)
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
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Ligands The ‘H and "C NMR spectra
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Ligands The ‘H NMR spectrum of HZ
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M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
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' | Ligands uo no 1&0 150 no no no
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Ligands Table 2. 3. Crystal data an
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Ligands The C-S bond distances of 1
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ligands between the planes of Cg(2)
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" F Ligands A indicates a typical d
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' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
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2.4.2. M TT Cell Proliferation Assa
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Table 2.9. Cell proliferation effec
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7 y _ i _ W Ligands B. Moubaraki, K
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CHAPTER Ni(II) complexes of carbohy
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_ _ __ g_ g W g H__ Ni(ll) complexe
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_ g A __ Ni(lI) complexes The reddi
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3.3. Results and discussion g_g _ N
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
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t§hqphw*3 v(Ni—S), further suppo
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Chapter 3 charge transfer bands. Fo
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Chapter 3 were refined anisotropica
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Chapter 3 3.3.3.1. Crystal structur
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Chapter 3 Table 3.7. Selected bond
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Chapter 3 N(l3)—C(35), N(2l)-C(58
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3.3.3.2. Crystal structures 0f[Ni(H
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Table 3.10. Selected bond lengths (
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Ni(lI) complexes significant 1t---1
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3.3.4. Magnetochemistry of the mole
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Ni(Il) complexes The allowed values
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in xn In
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g 7 Ni(Il) complexes 3.4. Concludin
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11 12 13 14 15 16 17 18 19 20 21 22
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41 42 43 44 45 46 47 48 49 50 51 52
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_ g “FOUR CHAPTER Cu(II) complexe
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_g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
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i ____ 3+ i --—- C 0pper(H) 2+ co
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C0pper(Il) complexes 499 100i ~04 7
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.04Copper(II) complexes 385 50.1I 1
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100-I 4 -1 U ” Q 7°-J 59-: "1
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C0pper(lI) complexes confirm the po
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C0pper(ll) complexes 100 80" I
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C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
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Copper(lI) complexes F1 = g",3B:S:
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Chapter 4 for both species consider
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Chapter 4 The spectrum of compound
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Chapter 4 stability alone could not
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Chapter 4 zénzénzénzénénaloeé
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Chapter 4 164 | | | 252 272 2Q 31 B
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Chapter 4 The shifting of g values
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Chapter 4 _|“. / "| 1' '| |' | 1'
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Chapter 4 The solid state and some
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Chapter 4 U 1 .I - O i I . I II I
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_ I Chapter 4 — I I I — I '
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. , Chapter 4 2.5 I I ' I ' I ' I '
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Chapter 4 The field dependence of m
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Chapter 4 Where ,1’ M is the magn
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Chapter 4 g e The powder and frozen
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Chapter 4 various aspects like bond
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C0pper(ll) complexes Table 4.6. Sel
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,____ p _p C0pper(H) complexes from
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Ed. Engl. 31 (1992) 733. 7___7 7 7
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__ ,_ f W C 0pper(l1) complexes Che
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-_ FIVE CHAPTER Spectral and magnet
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__ g_ _g g H g __ Manganese(II) com
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q H _ Manganesefll) complexes [Mn2(
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Manganese(Il) complexes lcmzmoll in
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1W3 "l U 70 60 40 30 10 490 740 979
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Manganese(II) complexes MALDI MS sp
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5.3.2. EPR spectral studies Mangane
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Manganese(II) complexes D and E , e
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the pattern is uncertain and it is
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Page 229 and 230: Chapter 5 thiocarbohydrazone comple
Page 231 and 232: Chapter 5 To fit and interpret the
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Page 249 and 250: 1 | Chapter 6 100m__ ‘ 76$ mi, 16
Page 251 and 252: 3 - i El Q I Chapter 6 - '3“ 1999
Page 253 and 254: Chapter 6 The compound 27 exhibits
Page 255 and 256: (T71aq7tew'¢5 centered at 1711.9 c
Page 257 and 258: 1 . 1 Chapter 6 1244 100--1-; 1245
Page 259 and 260: Chapter 6 6.3.2. Electronic and IR
Page 261 and 262: Chapter 6 band at 19160 and 23920 c
Page 264 and 265: Zinc(II) & Cadmium(II) complexes Th
Page 266 and 267: .- 60- I ‘J TZinc(Il) & Cadmium(l
Page 268 and 269: Zinc(Il) & Cadmium(Il) complexes re
Page 270 and 271: Zinc(II) & C admium(ll) complexes T
Page 272 and 273: Fig. 6.25. The molecular structure
Page 276 and 277: Zi!lC(II) & Cadmlum(II) C0mlexes Ta
Page 278 and 279: V _ i Zinc(1I) & Cadmium(lI) comple
Page 280 and 281: _ g _ g g V Zinc(lI) & Cadmiumfll)
Page 282 and 283: _, _ g pg L Summary and conclusion
Page 284 and 285: W g _ g mm Summary and conclusion a
Page 286 and 287: __ ,_ _ W A _ _ Summary and conclus
Page 288 and 289: Curriculum Vitae PERSONAL PROFILE N
Page 290: 2-Hydroxyacetophenone 4-phenylthios
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