Self-assembled Transition Metal Coordination Frameworks of ...

Chapter 2
Ic1sA
Cl7A
C18A
C 1'
C14A
i
C19A
-Q 7
Cl2A N5A
3* N4A
N6A H4/\N
21A NZA
C20A
SIB
NIB N3B ' N413
CIIA
N3A
C10A
N2B
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c9
C8A ¢5A
Table 2.4. Selected bond lengths (A) and angles (°) of HZL3.
.
C. ._»
NIA C2A
cu. K C“
Fig. 2.16. ORTEP plot of the two independent molecules in the asymmetric unit of
HZL3, with 50% probability displacement ellipsoids. H atoms are shown as small
spheres of arbitrary radii and dashed lines denote the intramolecular N-H N
interactions.
S(1A)—C(1 1A)
S(1B)—C(1 1 B)
N(4B)-C(l 1B)
N(4B)—N(5B)
N(3B)—N(2B)
N (3B)-C(l 1B)
N(5B)—C(l2B)
N(3A)—C(l 1A)
N(3A)—N(2A)
C(13B)—C( 12B)
N (2A)—C(10A)
N (4A)—C( 1 1A)
N (4A)—N (5A)
N (5A)—C( 1 2A)
C(9A)—C( 10A)
C(13A)—C( 12A)
N(2B)—C(10B)
C(l0B)—C(9B)
1.657 (4)
1.651 (4)
1.345 (5)
1.365 (4)
1.358 (4)
1.362 (5)
1.292 (5)
1.353 (5)
1.355 (4)
1.457 (5)
1.290 (5)
1.347 (5)
1.366 (4)
1.286 (4)
1.454 (5)
1.466 (5)
1.289 (5)
1.463 (5)
C(l 1 B)—N(4B)—N(5B)
N(2B)—N(3B)—C(1 1B)
C(12B)—N(5B)—N(4B)
C(l 1A)-N(3A)—N(2A)
C(10A)-N(2A)—N(3A)
C( 1 1A)—N(4A)—N (5 A)
C(12A)—N(5A)—N(4A)
C(10B)—N(2B)—N(3B)
N(4B)-C(l lB)—N(3B)
N(4B)—C(11B)-S(1B)
N(3B)-C(1lB)—S(lB)
N(4A)—C(l 1A)—N(3A)
N(4A)—C(l lA)—S( 1A)
N(3A)—C(l lA)—S( 1A)
iC4A
120.0 (3)
120.3 (3)
l 16.5 (3)
120.4(3)
118.3 (3)
119.9(3)
116.5 (3)
117.7 (3)
113.0(3)
126.6(3)
120.4(3)
112.5 (3)
127.0(3)
120.5 (3)