Self-assembled Transition Metal Coordination Frameworks of ...

Chapter 4
exact position of anions [19]. The tentative structures of complexes are shown in
Schemes 4.1. to 4.5.
,- ——— ——-4+
/ /
~
\
L 1
.
I /-4/I‘ 5"\
N \ / s\\
. '_.n\
Cu'
H/\~ \ /N /I 'cu"N\N"*"9'“"“ \N \\\ I / 0|-:2 3\
\N_.-
0| -/'
I‘ / . N \
it \ IN. 1»/1 \ 1| .' i N| "P \ ~. / \
4;
i
__ as __ __..+
Scheme 4.1. The tentative structures of complexes 8 (left) and 9 (right).
" \ri Nl \N | / l
H
Br \ / _ | \N_
H
NI/j J _ / , at % . ;
l / '\ a Cu
‘ = I * / | = 1
Br
\ -
s \ N/ X fl \
\. \
la: / 1 \ 0 /K N/ N \ /
°'\/°' "' . N , N8'
hi
. ‘ Cu _. ' \ 1" N H ‘ 1 _,,Cu\ . I ~|~| ‘~‘ .
; I _. l \ Cu \ HI
2
J_,.Cu_ - " 1‘ : “N ' 4
c|/ \\x)|\N/N\)|\/ r Br/ \x)\N,N\)|\/
Scheme 4.3. The tentative structures of Cu(Il) complexes ll and 18 (left) and 12
and l9 (right). X= S for ll and 12. X= O for 18 and 19.
-iii qa La
Scheme 4.2. The tentative structures of Cu(ll) complexes 10 (left) and 15 (right).
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