Self-assembled Transition Metal Coordination Frameworks of ...

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Curriculum Vitae PERSONAL PROFILE Nationality Date of Birth Permanent address e-mail EDUCATION 1996 1 996- 1 998 1998-2001 2001-2003 ACHIEVEMENTS 2004 June 2003 Indian 28"‘Febn1ary 1981 Puthen Madom Pandithitta East, Thalavoor (P.O.) Kollam-691 514, Kerala +91-475-2328535 manoj e@cusat.ac.in manuthalavoor@yahoo.c0m manoj epotti@gmail.com SSLC (84.5 %) D.V.V.H.S.S., Thalavoor, Board of public examinations, Kerala state Pre-Degree (71 .6%) St. Gregorios College, Kottarakara University of Kerala B. Sc. Chemistry (81.4%) St. Gregorios College, Kottarakara University of Kerala M. Sc. Chemistry (79.7%, Fifth Rank) (Elective: Advanced Physical Chemistry) St. Stephen’s College, Pathanapuram University of Kerala National Eligibility Test — UGC-J RF/ Lectureship KSCSTE-JRF in Chemistry Kerala State Council for Science, Technology and Environment.
RESEARCH PUBLICATIONS Structural and spectral studies of nickel(lI) complexes with N(4),N(4) (butane-1,4-diyl)thiosemicarbazones, E. Manoj, M.R.P. Kurup, Polyhedron, DOI: 10.1016/j.p0ly.2007.09.023 Synthesis and spectral studies of bisthiocarbohydrazone and biscarbohydrazone of quinolinc-2-carbaldehyde: Clystal structure of bis(quinoline-2-aldehyde) thiocarbohydrazone E. Manoj, M.R.P. Kump, E. Suresh, J. Chem. Cryst., DOI: 10.1007/sl0870-007-9267-9 Synthesis and EPR spectral studies of manganese (II) complexes derived from pyridine 2-carbaldehyde based N(4)-substituted thiosemicarbazones: Crystal structure of one complex, P.F. Rapheal, E. Manoj, M.R.P. Kurup, Polyhedron 26 (2007) 5088. Self-assembled macrocyclic molecular squares of Ni(Il) derived from carbohydrazones and thiocarbohydrazones: Structural and magnetic studies, E. Manoj, M.R.P. Kurup, H.-K. Fun, A. Pumtoose, Polyhedron 26 (2007) 4451. Macrocyclic molecular square complex of zinc(II) self-assembled with a carbohydrazone ligand, E. Manoj, M.R.P. Kurup, H.-K. Fun, Inorg. Chem. Commun. 10 (2007) 324. Synthesis and spectral characterization of zinc(H) complexes of N(4) substituted thiosemicarbazone derived from salicylaldehyde: Structural study of a novel -OH free Zn(II) complex, L. Latheef, E. Manoj, M.R.P. Kurup, Polyhedron 26 (2007) 4107. Copper(ll) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde: Crystal structure of a binuclear complex, P.F. Rapheal, E. Manoj, M.R.P. Kurup, Polyhedron 26 (2007) 818. Structural and spectral studies of novel Co(IlI) complexes of N(4) substituted thiosemicarbazones derived from pyridine-2-carbaldehyde, P.F. Rapheal, E. Manoj, M.R.P. Kurup, E. Suresh, Polyhedron 26 (2007) 607.
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7,2/H5 Self-assembled Transition Me
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, Phone orr. 0484-2575804 ; Phone R
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‘ilC7(,'NO’WLQ'I(D QEMEWT In tl
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PREFACE In its method, chemistry is
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CONTENTS CHAPTER 1 Introduction to
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4.3.5. Magnetochemistry 4.3.6. Char
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Chapter I__ _ _ irreducible, is a n
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Chapter I W 7 _ W _ 7 pg _ jg to pr
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Chapter I H_ g g 7 g 7 7 __ harvest
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Chapter I _ _ ______g__H _ g involv
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Chapter I _ g plays a pivotal role
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Chapter I g g _ exhibit considerabl
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Chapter I _, assemblies to generate
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Chapter I _ ,_ of mono or dinuclear
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Chapter I M W 7 7 _ __ 1.3.1.1. Ant
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Chapter I _ _ _ _ \_ 4- Jm _. _.
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Chapter In g_ g _ E __ _ E __( > es
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Chapter I W__‘ _ 1.6.6. MALDI MS
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Chapter I ,,_ g electron spin (the
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Chapter I W _ _ Traditional magnets
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Chapter I L.K. Thompson, O. Waldman
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Chapter I i __ _ Org. Chem. 31 (200
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Chapter In _g , g H g 85. S. Padhye
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Chapter 2 1 g anticipation of Cu(H)
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Chapter 2 _. M_ _ up 1. Quinoline-2
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Chapter 2 chloroform solution and d
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Chapter2 V _ _ _ _, 7 _ with aceton
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Chapter 2 _ 7 f __ i 2.3. Results a
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100s0- I > J 20
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— — 1 Ligands 1
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Ligands The ‘H and "C NMR spectra
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Ligands The ‘H NMR spectrum of HZ
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M1 1‘ 11 IL; Fig. 2.11. 'H NMR sp
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' | Ligands uo no 1&0 150 no no no
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Ligands Table 2. 3. Crystal data an
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Ligands The C-S bond distances of 1
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ligands between the planes of Cg(2)
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" F Ligands A indicates a typical d
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' ' Q 0' ¢ ¢" .~ 0~ I Q Q Q \ ' Q
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2.4.2. M TT Cell Proliferation Assa
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Table 2.9. Cell proliferation effec
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7 y _ i _ W Ligands B. Moubaraki, K
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CHAPTER Ni(II) complexes of carbohy
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_ _ __ g_ g W g H__ Ni(ll) complexe
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_ g A __ Ni(lI) complexes The reddi
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3.3. Results and discussion g_g _ N
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3.3.1. MALDI MS spectral studies of
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Ni(Il) complexes In the case of com
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100 U-
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3.3.2. IR and electronic spectral s
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Chapter 3 The electronic spectra of
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t§hqphw*3 v(Ni—S), further suppo
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Chapter 3 charge transfer bands. Fo
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Chapter 3 were refined anisotropica
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Chapter 3 3.3.3.1. Crystal structur
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Chapter 3 Table 3.7. Selected bond
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Chapter 3 N(l3)—C(35), N(2l)-C(58
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3.3.3.2. Crystal structures 0f[Ni(H
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Table 3.10. Selected bond lengths (
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Ni(lI) complexes significant 1t---1
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3.3.4. Magnetochemistry of the mole
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Ni(Il) complexes The allowed values
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in xn In
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g 7 Ni(Il) complexes 3.4. Concludin
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11 12 13 14 15 16 17 18 19 20 21 22
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41 42 43 44 45 46 47 48 49 50 51 52
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_ g “FOUR CHAPTER Cu(II) complexe
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_g C0pper(II) complexes complex of
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_ _ , p f 7, Copper-(II) complexes
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pp g _g _4_,_ C0pper(II) complexes
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g _,_,_ g g Copperfll) complexes in
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i ____ 3+ i --—- C 0pper(H) 2+ co
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C0pper(Il) complexes 499 100i ~04 7
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.04Copper(II) complexes 385 50.1I 1
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100-I 4 -1 U ” Q 7°-J 59-: "1
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C0pper(lI) complexes confirm the po
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C0pper(ll) complexes 100 80" I
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C0pper(1l) complexes state, similar
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2 5 2.5MW 20 Q 1.51 2oo'aoo'45o's
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Copper(lI) complexes F1 = g",3B:S:
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Chapter 4 for both species consider
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Chapter 4 The spectrum of compound
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Chapter 4 stability alone could not
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Chapter 4 zénzénzénzénénaloeé
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Chapter 4 164 | | | 252 272 2Q 31 B
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Chapter 4 The shifting of g values
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Chapter 4 _|“. / "| 1' '| |' | 1'
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Chapter 4 The solid state and some
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Chapter 4 U 1 .I - O i I . I II I
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_ I Chapter 4 — I I I — I '
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. , Chapter 4 2.5 I I ' I ' I ' I '
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Chapter 4 The field dependence of m
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Chapter 4 Where ,1’ M is the magn
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Chapter 4 g e The powder and frozen
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Chapter 4 various aspects like bond
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C0pper(ll) complexes Table 4.6. Sel
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,____ p _p C0pper(H) complexes from
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Ed. Engl. 31 (1992) 733. 7___7 7 7
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__ ,_ f W C 0pper(l1) complexes Che
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-_ FIVE CHAPTER Spectral and magnet
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__ g_ _g g H g __ Manganese(II) com
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q H _ Manganesefll) complexes [Mn2(
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Manganese(Il) complexes lcmzmoll in
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1W3 "l U 70 60 40 30 10 490 740 979
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Manganese(II) complexes MALDI MS sp
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5.3.2. EPR spectral studies Mangane
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Manganese(II) complexes D and E , e
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the pattern is uncertain and it is
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__ I . l r Manganese(II) complexes
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" |\ Man ganese(II) complexes 80" 6
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Chapter 5 thiocarbohydrazone comple
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Chapter 5 To fit and interpret the
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Chapter 5 #1 IT 0.00 1 — ‘ I '
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Chapter 5 The temperature dependenc
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Page 245 and 246: Chapter 6 g _ _ [Cd(HL2) ].,(1v0_.)
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Page 253 and 254: Chapter 6 The compound 27 exhibits
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Page 257 and 258: 1 . 1 Chapter 6 1244 100--1-; 1245
Page 259 and 260: Chapter 6 6.3.2. Electronic and IR
Page 261 and 262: Chapter 6 band at 19160 and 23920 c
Page 264 and 265: Zinc(II) & Cadmium(II) complexes Th
Page 266 and 267: .- 60- I ‘J TZinc(Il) & Cadmium(l
Page 268 and 269: Zinc(Il) & Cadmium(Il) complexes re
Page 270 and 271: Zinc(II) & C admium(ll) complexes T
Page 272 and 273: Fig. 6.25. The molecular structure
Page 274 and 275: Zinc(lI) & Cadmium(ll) complexes Al
Page 276 and 277: Zi!lC(II) & Cadmlum(II) C0mlexes Ta
Page 278 and 279: V _ i Zinc(1I) & Cadmium(lI) comple
Page 280 and 281: _ g _ g g V Zinc(lI) & Cadmiumfll)
Page 282 and 283: _, _ g pg L Summary and conclusion
Page 284 and 285: W g _ g mm Summary and conclusion a
Page 286 and 287: __ ,_ _ W A _ _ Summary and conclus
Page 290: 2-Hydroxyacetophenone 4-phenylthios
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