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Untitled - Sciencemadness Dot Org

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BARATOL<br />

1. GENERAL PROPERTIES<br />

1.1 Chemical and Physical Description. Baratol, a mixture of barium nitrate,<br />

Ba(NO,),, and TNT, C,HsNBOB, is off-white to gray.<br />

1.2 Common Use. During World War II, the British developed baratols that con-<br />

tained about 20 wt% barium nitrate to replace TNT. The United States used<br />

baratols that contained slightly more barium nitrate in depth charges and other<br />

limited munitions. Baratols that contain up to 76 wt% barium nitrate are now used<br />

as the low detonation velocity explosive in waveshaping devices such as plane-wave<br />

lenses.<br />

1.3 Toxicity.’ Barium nitrate can irritate skin and mucous membranes.<br />

2. MANUFACTURE AND PROCUREMENT<br />

2.1 Manufacture. Finely ground barium nitrate is added to molten TNT to form<br />

a castable slurry. To lower the slurry viscosity, which increases with the percentage<br />

of barium nitrate, about 0.1 wt% of nitrocellulose (11.8-12.2 wt% nitrogen, 18-25<br />

centipoise) is added to the TNT before the addition of the barium nitrate. After the<br />

barium nitrate is added, just before vacuum is applied to the’melt, 0.05-0.1 wt% of<br />

either decylgallophenone or stearoxyacetic acid is added to prevent cracking.<br />

Vacuum is applied to the melt just before casting to remove dissolved and occluded<br />

gas and to provide higher, more uniform density. Carefully controlled cooling of the<br />

casting also promotes uniform density and composition.<br />

2.2 Procurement. There are no purchase specifications for baratol. It is<br />

produced to the user’s specific requirements at ordnance plants that have TNT-<br />

casting facilities.<br />

3<br />

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