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NQ 56 5.6 Heats of Combustion and Formation at 25’XLe AH; (kcal/mole) -210.4 5.7 Thermal Decomposition Kinetics.loJ1 AH; (kcal/mole) -20.29 Decomposition energy 500 Cal/g Activation energy 20.9 kcal/mole Pre-exponential factor 2.84 x lO’/s 5.8 Other Thermal Stability Test Results. Source Ref. 10 Ref. 11 Test Results ___ 57.1 kcal/mole 8.75 x 1022/s Vacuum Gas evolved after 48 h at 120°C (ml/g) NQ per MIL-N-494A Water recrystallized HBD NQ DMF recrystallized HBD NQ DTA and pyrolysis Critical temperature, Tm Charge radius, a Density, p 0.0-1.0 1.4-3.6 0.6-1.2 See Fig. 2 198°C 3.9 mm 1.63 g/cm3
1 1 $’ r I,. 1 L 1 / / I II,, 1 , I,, I 0 m zco 300 TEMPER4T”RE (“Cl 6. DETONATION PROPERTIES 6.1 Detonation Velocity.12 Fig. 2. NQ DTA and pyrolysis test results. _ Effect of Density The effect of density on the infinite-diameter detonation velocity is given by D, = 1.44 + 4.015 p,, for 0.3 < p0 < 1.78, where D m = infinite-diameter detonation velocity in millimeters per microse- cond, and p. = density in grams per cubic centimeter. Failure Diameter The LBD NQ failure diameter as a function of charge density is shown. Charge Density (g/cm*) Charge Diameter 6-1 Detonates Fails 1.0 25.4 __- 1.21 15.9 14.3 1.52 14.3 12.7 m NQ 57
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LOS ALAMOS SERIES ON DYNAMIC MATERI
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University of California Press Berk
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PART II. EXPLOSIVES PROPERTIES BY P
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treats pure explosives first, alpha
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EXPLOSIVES PROPERTIES BY EXPLOSIVE
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BARATOL 2.3 Shipping.2 Baratol is s
Page 14 and 15: BARATOL 6 5.4 Thermal Conductivity.
Page 16 and 17: BARATOL 6.2 Detonation Pressure. We
Page 18 and 19: BARATOL REFERENCES . . 1. N. I. Sax
Page 20 and 21: COMP B slowly. Heating and stirring
Page 22 and 23: COMP B 14 3.3 Solubility.‘The sol
Page 24 and 25: COMP B 16 5.3 Heat Capacity. Heat C
Page 26 and 27: COMP B 18 6.2 Detonation Pressure.
Page 28 and 29: COMP B 7.3 Shock Hugoniots.12J8 Com
Page 30 and 31: COMP B 9. MECHANICAL PROPERTIES 22
Page 32 and 33: CYCLOTOL 1. GENERAL PROPERTIES 1.1
Page 34 and 35: CYCLOTOL 26 3.2 Molecular Weight. C
Page 36 and 37: CYCLOTOL 4.3 Infrared Spectrum. See
Page 38 and 39: CYCLOTOL where D = detonation veloc
Page 40 and 41: CYCLOTOL 8.3 Skid Test Results. Den
Page 42 and 43: DATB 1. GENERAL PROPERTIES 1.1 Chem
Page 44 and 45: DATB 4. PHYSICAL PROPERTIES 4.1 Cry
Page 46 and 47: DATB 5.4 Thermal Conductivity, Cond
Page 48 and 49: DATB 7.3 Shock Hugoniot.9 Density k
Page 50 and 51: HMX* 1. GENERAL PROPERTIES 1.1 Chem
Page 52 and 53: HMX 3.2 Molecular Weight. 296.17 3.
Page 54 and 55: HMX 5. THERMAL PROPERTIES 46 5.1 Ph
Page 56 and 57: HMX 6. DETONATION PROPERTIES 6.1 De
Page 58 and 59: HMX 7.3 Shock Hugoniots.” Density
Page 60 and 61: NITROGUANIDINE 1. GENERAL PROPERTIE
Page 62 and 63: NQ 54 4.2 Density.’ Crystal Metho
Page 66 and 67: NQ 6.2 Detonation Pressure. There a
Page 68 and 69: NQ 8. SENSITIVITY 8.1 Drop Weight I
Page 70 and 71: OCTOL These are shipped to an ordna
Page 72 and 73: 64 OCTOL 3.3 Solubility.6 The solub
Page 74 and 75: OCTOL 5. THERMAL PROPERTIES 66 5.1
Page 76 and 77: OCTOL 68 6.4 Plate Dent Test Result
Page 78 and 79: OCTOL 8.3 Skid Test Results. Weight
Page 80 and 81: PBX 9011 1. GENERAL PROPERTIES 1.1
Page 82 and 83: PBX 9011 3.3 Solubility. The solubi
Page 84 and 85: PBX 9011 76 5.5 Coefficient of Ther
Page 86 and 87: PBX 9011 78 6.3 Cylinder Test Resul
Page 88 and 89: PBX 9011 7.5 Detonation Failure Thi
Page 90 and 91: PBX 9011 82 9.3 Compressive Strengt
Page 92 and 93: PBX9404 1. GENERAL PROPERTIES 1.1 C
Page 94 and 95: PBX 9404 86 3.2 Molecular Weight. C
Page 96 and 97: PBX 9404 88 4.3 Infrared Spectrum.
Page 98 and 99: PBX 9404 > 1 1 o- r 0 I I I, / PYRO
Page 100 and 101: PBX 9404 7. SHOCK INITIATION PROPER
Page 102 and 103: PBX 9404 7.5 Detonation Failure Thi
Page 104 and 105: PBX 9404 8.5 Spark Sensitivity. Ele
Page 106 and 107: PBX 9404 REFERENCE‘S 1. Committee
Page 108 and 109: PBX 9407 2.3 Shipping.2 PBX-9407 mo
Page 110 and 111: PBX 9407 4.3 Infrared Spectrum. See
Page 112 and 113: PBX 9407 6. DETONATION PROPERTIES I
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PBX 9407 106 7.2 Wedge Test Results
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PBX 9407 9.3 Compressive Strength a
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PBX 9501 2.3 Shipping.* PBX-9501mol
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PBX 9501 5. THERMAL PROPERTIES 112
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PBX 9501 6. DETONATION PROPERTIES 6
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PBX 9501 7.3 Shock Hugoniot. Densit
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PBX 9501 9. MECHANICAL PROPERTIES*
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PBX9502 1. GENERAL PROPERTIES 1.1 C
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PBX 9502 3.3 Solubility. The solubi
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PBX 9502 124 5.3 Heat Capacity. 5.4
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PBX 9502 6.3 Cylinder Test Results.
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PBX 9502 9. MECHANICAL PROPERTIES 1
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PENTAERYTHRITOLTETRANITRATE (PETN)
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PETN 3.2 Molecular Weight. 316.15 3
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PETN 4.4 Refractive Indices.s Omega
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PETN 5.7 Thermal Decomposition Kine
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PETN 138 7.2 Wedge Test Results. De
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, PETN 5. US Army Materiel Command,
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RDX developed into a continuous hig
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RDX 4. PHYSICAL PROPERTIES 4.1 Crys
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RDX 146 5.2 Vapor Pressure.8 Temper
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RDX 6. DETONATION PROPERTIES 148 6.
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RDX 7.3 Shock Hugoniot.” 8. SENSI
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TATB 1. GENERAL PROPERTIES 1.1 Chem
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TATB TATB solubility in sulfuric ac
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TATB 5.2 Vapor Pressure.6 A least s
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TATB I / / I I I I I I I ! \ I 1 \
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TATB 7.3 Shock Hugoniots.“+ A num
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TATB REFERENCES 1. T. M Benziger an
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TETRYL acetone. In the second proce
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TETRYL 2.5 100 80 60 % T 40 20 0 :;
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TETRYL 6. DETONATION PROPERTIES 6.1
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TETRYL 7.5 Detonation Failure Thick
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TNT 1. GENERAL PROPERTIES 1.1 Chemi
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TNT 4. PHYSICAL PROPERTIES 4.1 Crys
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TNT 4.3 Infrared Spectrum. See Fig.
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TNT 178 5.5 Coefficient of Thermal
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TNT The charge preparation method a
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TNT 182 6.4 Plate Dent Test Results
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TNT 7.3 Shock Hugoniots.2aJ4 Densit
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TNT 9.3 Compressive Strength and Mo
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XTX8003 1. GENERAL PROPERTIES 1.1 C
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XTX 8003 3.3 Solubility.6 The solub
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XTX 8003 5.7 Thermal Decomposition
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XTX 8003 8. SENSITIVITY 8.1 Drop We
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XTX8004 1. GENERAL PROPERTIES 1.1 C
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XTX 8004 3.3 Solubility. The solubi
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XTX 8004 6. DETONATION PROPERTIES 6
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PART II EXPLOSIVES PROPERTIES BY IP
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Explosive Alex/20 Alex/30 Amatex/20
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Explosive PBX 9007 PBX 9010 PBX 901
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Explosive Constituents X-0234-60 X-
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Alex/20 Alex/30 Amatexl20 Amatexl30
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NQ octo1 PAT0 Explosive PBX 9007 PB
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X-0234-60 X-0234-70 X-0234-80 X-028
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THERMAL PROPERTIES 2. THERMAL PROPE
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THERMAL PROPERTIES k2 = kl - (4, -
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Explosive PETN RDX TNT Table 2.03 C
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THERMAL PROPERTIES AEE = standard i
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THERMAL PROPERTIES Fig. 2.02. Pyrol
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,’ THERMAL PROPERTIES L Y !s :: B
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THERMAL PROPERTIES 228 Composition
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THERMAL PROPERTIES B Y !3 E E “I
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THERMAL PROPERTIES This assembly is
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DETONATION PROPERTIES 3. DETONATION
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DETONATION PROPERTIES 236 Table 3.0
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Shot No. c-4394 E-4672 E-4067 E-406
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DETONATION PROPERTIES Table 3.06 CY
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Table 3.08 OCTOL DETONATION VELOCIT
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Rate Stick Shot ’ Diameter No. (m
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DETONATION PROPERTIES 246 Table 3.1
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Shot No. C-4436 E-3621 - Rate Stick
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Table 3.15 GENERAL CYLINDER TEST SH
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DETONATION PROPERTIES 252 Expansion
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Expansion Radius (mm) Table 3.19 X-
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N VI UY Table 3.21 X-0285 WALL VELO
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DETONATION PROPERTIES Table 3.25 X-
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Explosive Table 3.26 DETONATION (C-
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DETONATION PROPERTIES Analysis Line
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DETONATION PROPERTIES Explosive Tab
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DETONATION PROPERTIES 3.4 Plate Den
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Exnlosive Table 3.46 (continued) De
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Explosive PBX 9501 x-0007 86 HMX/14
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85 RDX/lS Kel-F Explosive 88 RDXI12
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DETONATION PROPERTIES Table 3.47 LE
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DETONATION PROPERTIES Table 3.48 DE
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SHOCK INITIATION PROPERTIES PETN Ba
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES each sh
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SHOCK INITIATION’PROPERTIES Table
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SHOCK INITIATION PROPERTIES 300 i;
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w R Table 4.04 NITROMETHANE Composi
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SHOCK INITIATION PROPERTIES 304 Tab
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SHOCK INITIATION PROPERTIES 306 / D
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SHOCK INITIATION PROPERTIES 308 2 0
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Table 4.06 (continued) Coordinates
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SHOCK INITIATION PROPERTIES 312 I-
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SHOCK INITIATION PROPERTIES 316 05
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Table 4.07 PETN (SINGLE CRYSTAL) Co
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Table 4.08 (continued) Shot Number
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SHOCK INITIATION PROPERTIES 324 2 u
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SHOCK INITIATION PROPERTIES Table 4
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SHOCK INITIATION PROPERTIES 334 2T
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Initial Shock Parameters Table 4.12
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SHOCK INITIATION PROPERTIES 342 Ini
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3 *a i 8 3 x j > f m e c u,, = (2.3
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SHOCK INITIATION PROPERTIES 348 Dis
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w ul 0 Composition 95 wt% DATB, 5 w
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SHOCK INITIATION PROPERTIES 5.5- 5.
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5 Table 4.17 (continued) Coordinate
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SHOCK INITIATION PROPERTIES 40- 20
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Shot E-3120 3.370 $0.022 E-3131 2.4
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_. Shot Number E-771 E-781 B-4481 B
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SHOCK INITIATION PROPERTIES 364 2 I
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SHOCK INITIATION PROPERTIES 366 0.6
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SHOCK INITIATION PROPERTIES Composi
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Table 4.21 X-0219-50-14-10 Composit
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Composition 95 wt% NQ, 5 wt% Estane
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Shot Number (G?a) E-3245 16.2 5.904
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SHOCK INITIATION PROPERTIES 380 c x
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w R Table 4.24 (continued) Reduced
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Table 4.25 XTX-8003 (EXTEX) Composi
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SHOCK INITIATION PROPERTIES 386 a--
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Table 4.27 PBX 9407 Compositon 94 w
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SHOCK INITIATION PROPERTIES 390 3 g
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Table 4.28 PBX 9405 Cotiposition 93
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SHOCK INITIATION PROPERTIES 394 c 5
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% OY Table 4.30 x-0250-40-19 Compos
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SHOCK INITIATION PROPERTIES 398 Dis
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Table 4.32 95 TATB/2.5 Kel-F 800/2.
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Table 4.39 (continued) Coordinates
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z Table 4.44 FKM CLASS VII PROPELLA
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Theoretical Maximum Density >1.910
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Ammonium picrate Raratol(76/24) mix
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HMX-Based PBX 9011 PBX 9404 PBX-950
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SHOCK INITIATION PROPERTIES 0.360 c
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SHOCK INITIATION PROPERTIES 432 I I
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES Explosi
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SHOCK INITIATION PROPERTIES TRANSIT
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SHOCK INITIATION PROPERTIES 442 FOI
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SENSITIVITY TESTS 5. SENSITIVITY TE
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Ammonium nitrate Ammonium picrate B
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-’ .-- _- ..- _ “. Cyclotol75/2
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Explosive RDX-Based with Metal Fill
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SENSITIVITY TESTS 5.2 Skid Test. Th
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Explosive Comp A-3 1.638 45 PBX 901
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SENSITIVITY TESTS 5.3 Large-Scale D
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SENSITIVITY TESTS 5.4 Spark Sensiti
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GLOSSARY ABH Amatex-20 ATNI BDNPA B
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NP OFHC ONT P-16 P-22 P-40 P-80 P-1
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AUTHOR IND Ablard, J. E. 141, 151 A
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SUBJECT INDEX ABH 461 Alex/20 204,
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pentaerythritol tetranitrate (PETN)
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