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Untitled - Sciencemadness Dot Org

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Pressed Charges. The density of TNT in large billets or in ammunition varies<br />

with the method of preparation. Compression without application of a vacuum to<br />

remove the residual air gives the following densities.<br />

Pressure Density<br />

(psi) (g/ma)<br />

3 000 1.35<br />

5 000 1.40<br />

10 000 1.45<br />

15 000 1.52<br />

20 000 1.55<br />

50 000 1.60<br />

Compaction with the residual air removed and the TNT preheated to 70°C gives<br />

the following density.<br />

Pressure<br />

(Psi)<br />

12000<br />

Powder<br />

Temperature<br />

(“(3<br />

70<br />

., , .<br />

Density<br />

k/cmY<br />

1.63-l-64<br />

Cast Charges. The density of cast TNT depends on the procedures used to melt,<br />

cast, and solidify it. Typical densities are as follows.<br />

Melting”<br />

Preparative Procedure<br />

Castingb<br />

Solidification<br />

TNT<br />

Density<br />

k/cmS)<br />

Open 100% liquid Ambient 1.56-1.59<br />

Open 75% liquid Ambient 1.59-161<br />

Vacuum 50-75% liquid Ambient 1.61-1.62<br />

---- --<br />

‘In an open melt the TNT is melted in atmospheric conditions. In a vacuum melt, the molten TNT is<br />

subjected to a vacuum (-20 mm Hg) for a few minutes.<br />

bBecause of the -7% volume change associated with the liquid-to-solid transition, solid TNT is usually<br />

added to the liquid TNT. The TNT, either as a liquid or as a mixture of liquid and solids, is cast at a<br />

temperature within a degree or two of the melting point (80-82”(J).<br />

175

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