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RDX 7.3 Shock Hugoniot.” 8. SENSITIVITY 8.1 Drop Weight Impact Height. 8.5 Spark Sensitivity. Electrode 150 Density Shock Hugoniot” khm3) (mm/d 1.799 U, = 2.78 + 1.9 U, *Computed from the isothermal volume compression data. Two RDX phases were observed in the course of determin- ing its isothermal volume compression. The shock Hugoniot tabulated is that for the orthorhombic form described previously in Sec. 4.1. Another RDX polymorph, Form III, occurs at pressures of 4.4 GPa. The volume change between the two polymorphs was about 1.6% (from 0.4651 to 0.4566 cm”/g). The isothermal Hugoniots of the two polymorphs were RDX(1) U,, = 2.68 + 1.9 U,, and RDX(I1) U,, = 2.49 + 1.8 U,,, where the subscript “t” denotes isothermal conditions. Tool Type 12 12I3 Lead Foil Sample Thickness Size (mils) (mg) &I (cm) Brass 3 61.1 0.22 50 Rrass 10 61.1 0.55 50 Steel 1 64.0 0.12 50 Steel 10 64.0 0.87 50 22 41 Energy (J) Occurrence of Explosion (%)
REFERENCES RDX 1. J. E. Ablard, US Naval Ordnance Laboratory report NAVSEA-03-TR-058 (July 1977). 2. T. Urbanski, The Chemistry and Technology of Explosives 3rd Ed. (Pergamon Press, Oxford, 1965). 3. C. R. Buck and S. E. Wilson, Jr., US Army report USEHA-32-049 (1975). 4. Code of Federal Regulations, 49, Transportation Parts 100-199, Rev. 12-1-76 (Office of the Federal Register, General Services Administration, Washington, DC, 1976). 5. US Army Materiel Command, Regulation No. AMCR-385-100 (1977). 6. W. C. McCrone, Analytical Chemistry 22, (7), 954-955 (1950). 7. C. S. Choi and E. Prince, Acta Crystallographica B28,2857-2862 (1972). 8. J. M. Rosen and C. Dickenson, Naval Ordnance Laboratory report NOLTR- 69-67 (April 1969). 9. H. H. Cady, Journal of Chemical and Engineering Data 17, (3), 369-371 (1972). 10. 0. H. Johnson, Naval Ordnance Laboratory report NAVORD-4371 (October 1956). 11. R. N. Rogers, Thermochimica Acta 11,131-139 (1975). 12. W. E. De,al, Journal of Chemical Physics 27, (l), 796-800 (1957). 13. Manuel ?J. Urizar, Suzanne W. Peterson, and Louis C., Smith, Los Alamos Scientific Laboratory report LA-7193-MS (April 1978). 14. Bart Olinger, Brad Roof, and Howard Cady, Symposium (International) on High Dynamic Pressures, Paris, France (August 1978). 151
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LOS ALAMOS SERIES ON DYNAMIC MATERI
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University of California Press Berk
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PART II. EXPLOSIVES PROPERTIES BY P
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treats pure explosives first, alpha
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EXPLOSIVES PROPERTIES BY EXPLOSIVE
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BARATOL 2.3 Shipping.2 Baratol is s
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BARATOL 6 5.4 Thermal Conductivity.
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BARATOL 6.2 Detonation Pressure. We
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BARATOL REFERENCES . . 1. N. I. Sax
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COMP B slowly. Heating and stirring
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COMP B 14 3.3 Solubility.‘The sol
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COMP B 16 5.3 Heat Capacity. Heat C
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COMP B 18 6.2 Detonation Pressure.
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COMP B 7.3 Shock Hugoniots.12J8 Com
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COMP B 9. MECHANICAL PROPERTIES 22
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CYCLOTOL 1. GENERAL PROPERTIES 1.1
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CYCLOTOL 26 3.2 Molecular Weight. C
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CYCLOTOL 4.3 Infrared Spectrum. See
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CYCLOTOL where D = detonation veloc
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CYCLOTOL 8.3 Skid Test Results. Den
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DATB 1. GENERAL PROPERTIES 1.1 Chem
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DATB 4. PHYSICAL PROPERTIES 4.1 Cry
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DATB 5.4 Thermal Conductivity, Cond
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DATB 7.3 Shock Hugoniot.9 Density k
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HMX* 1. GENERAL PROPERTIES 1.1 Chem
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HMX 3.2 Molecular Weight. 296.17 3.
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HMX 5. THERMAL PROPERTIES 46 5.1 Ph
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HMX 6. DETONATION PROPERTIES 6.1 De
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HMX 7.3 Shock Hugoniots.” Density
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NITROGUANIDINE 1. GENERAL PROPERTIE
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NQ 54 4.2 Density.’ Crystal Metho
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NQ 56 5.6 Heats of Combustion and F
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NQ 6.2 Detonation Pressure. There a
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NQ 8. SENSITIVITY 8.1 Drop Weight I
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OCTOL These are shipped to an ordna
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64 OCTOL 3.3 Solubility.6 The solub
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OCTOL 5. THERMAL PROPERTIES 66 5.1
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OCTOL 68 6.4 Plate Dent Test Result
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OCTOL 8.3 Skid Test Results. Weight
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PBX 9011 1. GENERAL PROPERTIES 1.1
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PBX 9011 3.3 Solubility. The solubi
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PBX 9011 76 5.5 Coefficient of Ther
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PBX 9011 78 6.3 Cylinder Test Resul
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PBX 9011 7.5 Detonation Failure Thi
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PBX 9011 82 9.3 Compressive Strengt
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PBX9404 1. GENERAL PROPERTIES 1.1 C
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PBX 9404 86 3.2 Molecular Weight. C
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PBX 9404 88 4.3 Infrared Spectrum.
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PBX 9404 > 1 1 o- r 0 I I I, / PYRO
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PBX 9404 7. SHOCK INITIATION PROPER
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PBX 9404 7.5 Detonation Failure Thi
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PBX 9404 8.5 Spark Sensitivity. Ele
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PBX 9404 REFERENCE‘S 1. Committee
Page 108 and 109: PBX 9407 2.3 Shipping.2 PBX-9407 mo
Page 110 and 111: PBX 9407 4.3 Infrared Spectrum. See
Page 112 and 113: PBX 9407 6. DETONATION PROPERTIES I
Page 114 and 115: PBX 9407 106 7.2 Wedge Test Results
Page 116 and 117: PBX 9407 9.3 Compressive Strength a
Page 118 and 119: PBX 9501 2.3 Shipping.* PBX-9501mol
Page 120 and 121: PBX 9501 5. THERMAL PROPERTIES 112
Page 122 and 123: PBX 9501 6. DETONATION PROPERTIES 6
Page 124 and 125: PBX 9501 7.3 Shock Hugoniot. Densit
Page 126 and 127: PBX 9501 9. MECHANICAL PROPERTIES*
Page 128 and 129: PBX9502 1. GENERAL PROPERTIES 1.1 C
Page 130 and 131: PBX 9502 3.3 Solubility. The solubi
Page 132 and 133: PBX 9502 124 5.3 Heat Capacity. 5.4
Page 134 and 135: PBX 9502 6.3 Cylinder Test Results.
Page 136 and 137: PBX 9502 9. MECHANICAL PROPERTIES 1
Page 138 and 139: PENTAERYTHRITOLTETRANITRATE (PETN)
Page 140 and 141: PETN 3.2 Molecular Weight. 316.15 3
Page 142 and 143: PETN 4.4 Refractive Indices.s Omega
Page 144 and 145: PETN 5.7 Thermal Decomposition Kine
Page 146 and 147: PETN 138 7.2 Wedge Test Results. De
Page 148 and 149: , PETN 5. US Army Materiel Command,
Page 150 and 151: RDX developed into a continuous hig
Page 152 and 153: RDX 4. PHYSICAL PROPERTIES 4.1 Crys
Page 154 and 155: RDX 146 5.2 Vapor Pressure.8 Temper
Page 156 and 157: RDX 6. DETONATION PROPERTIES 148 6.
Page 160 and 161: TATB 1. GENERAL PROPERTIES 1.1 Chem
Page 162 and 163: TATB TATB solubility in sulfuric ac
Page 164 and 165: TATB 5.2 Vapor Pressure.6 A least s
Page 166 and 167: TATB I / / I I I I I I I ! \ I 1 \
Page 168 and 169: TATB 7.3 Shock Hugoniots.“+ A num
Page 170 and 171: TATB REFERENCES 1. T. M Benziger an
Page 172 and 173: TETRYL acetone. In the second proce
Page 174 and 175: TETRYL 2.5 100 80 60 % T 40 20 0 :;
Page 176 and 177: TETRYL 6. DETONATION PROPERTIES 6.1
Page 178 and 179: TETRYL 7.5 Detonation Failure Thick
Page 180 and 181: TNT 1. GENERAL PROPERTIES 1.1 Chemi
Page 182 and 183: TNT 4. PHYSICAL PROPERTIES 4.1 Crys
Page 184 and 185: TNT 4.3 Infrared Spectrum. See Fig.
Page 186 and 187: TNT 178 5.5 Coefficient of Thermal
Page 188 and 189: TNT The charge preparation method a
Page 190 and 191: TNT 182 6.4 Plate Dent Test Results
Page 192 and 193: TNT 7.3 Shock Hugoniots.2aJ4 Densit
Page 194 and 195: TNT 9.3 Compressive Strength and Mo
Page 196 and 197: XTX8003 1. GENERAL PROPERTIES 1.1 C
Page 198 and 199: XTX 8003 3.3 Solubility.6 The solub
Page 200 and 201: XTX 8003 5.7 Thermal Decomposition
Page 202 and 203: XTX 8003 8. SENSITIVITY 8.1 Drop We
Page 204 and 205: XTX8004 1. GENERAL PROPERTIES 1.1 C
Page 206 and 207: XTX 8004 3.3 Solubility. The solubi
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XTX 8004 6. DETONATION PROPERTIES 6
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PART II EXPLOSIVES PROPERTIES BY IP
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Explosive Alex/20 Alex/30 Amatex/20
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Explosive PBX 9007 PBX 9010 PBX 901
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Explosive Constituents X-0234-60 X-
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Alex/20 Alex/30 Amatexl20 Amatexl30
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NQ octo1 PAT0 Explosive PBX 9007 PB
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X-0234-60 X-0234-70 X-0234-80 X-028
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THERMAL PROPERTIES 2. THERMAL PROPE
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THERMAL PROPERTIES k2 = kl - (4, -
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Explosive PETN RDX TNT Table 2.03 C
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THERMAL PROPERTIES AEE = standard i
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THERMAL PROPERTIES Fig. 2.02. Pyrol
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,’ THERMAL PROPERTIES L Y !s :: B
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THERMAL PROPERTIES 228 Composition
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THERMAL PROPERTIES B Y !3 E E “I
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THERMAL PROPERTIES This assembly is
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DETONATION PROPERTIES 3. DETONATION
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DETONATION PROPERTIES 236 Table 3.0
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Shot No. c-4394 E-4672 E-4067 E-406
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DETONATION PROPERTIES Table 3.06 CY
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Table 3.08 OCTOL DETONATION VELOCIT
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Rate Stick Shot ’ Diameter No. (m
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DETONATION PROPERTIES 246 Table 3.1
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Shot No. C-4436 E-3621 - Rate Stick
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Table 3.15 GENERAL CYLINDER TEST SH
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DETONATION PROPERTIES 252 Expansion
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Expansion Radius (mm) Table 3.19 X-
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N VI UY Table 3.21 X-0285 WALL VELO
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DETONATION PROPERTIES Table 3.25 X-
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Explosive Table 3.26 DETONATION (C-
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DETONATION PROPERTIES Analysis Line
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DETONATION PROPERTIES Explosive Tab
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DETONATION PROPERTIES 3.4 Plate Den
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Exnlosive Table 3.46 (continued) De
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Explosive PBX 9501 x-0007 86 HMX/14
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85 RDX/lS Kel-F Explosive 88 RDXI12
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DETONATION PROPERTIES Table 3.47 LE
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DETONATION PROPERTIES Table 3.48 DE
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SHOCK INITIATION PROPERTIES PETN Ba
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES each sh
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SHOCK INITIATION’PROPERTIES Table
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SHOCK INITIATION PROPERTIES 300 i;
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w R Table 4.04 NITROMETHANE Composi
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SHOCK INITIATION PROPERTIES 304 Tab
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SHOCK INITIATION PROPERTIES 306 / D
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SHOCK INITIATION PROPERTIES 308 2 0
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Table 4.06 (continued) Coordinates
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SHOCK INITIATION PROPERTIES 312 I-
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SHOCK INITIATION PROPERTIES 316 05
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Table 4.07 PETN (SINGLE CRYSTAL) Co
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Table 4.08 (continued) Shot Number
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SHOCK INITIATION PROPERTIES 324 2 u
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SHOCK INITIATION PROPERTIES Table 4
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SHOCK INITIATION PROPERTIES 334 2T
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Initial Shock Parameters Table 4.12
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SHOCK INITIATION PROPERTIES 342 Ini
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3 *a i 8 3 x j > f m e c u,, = (2.3
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SHOCK INITIATION PROPERTIES 348 Dis
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w ul 0 Composition 95 wt% DATB, 5 w
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SHOCK INITIATION PROPERTIES 5.5- 5.
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5 Table 4.17 (continued) Coordinate
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SHOCK INITIATION PROPERTIES 40- 20
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Shot E-3120 3.370 $0.022 E-3131 2.4
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_. Shot Number E-771 E-781 B-4481 B
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SHOCK INITIATION PROPERTIES 364 2 I
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SHOCK INITIATION PROPERTIES 366 0.6
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SHOCK INITIATION PROPERTIES Composi
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Table 4.21 X-0219-50-14-10 Composit
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Composition 95 wt% NQ, 5 wt% Estane
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Shot Number (G?a) E-3245 16.2 5.904
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SHOCK INITIATION PROPERTIES 380 c x
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w R Table 4.24 (continued) Reduced
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Table 4.25 XTX-8003 (EXTEX) Composi
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SHOCK INITIATION PROPERTIES 386 a--
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Table 4.27 PBX 9407 Compositon 94 w
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SHOCK INITIATION PROPERTIES 390 3 g
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Table 4.28 PBX 9405 Cotiposition 93
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SHOCK INITIATION PROPERTIES 394 c 5
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% OY Table 4.30 x-0250-40-19 Compos
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SHOCK INITIATION PROPERTIES 398 Dis
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Table 4.32 95 TATB/2.5 Kel-F 800/2.
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Table 4.39 (continued) Coordinates
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z Table 4.44 FKM CLASS VII PROPELLA
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Theoretical Maximum Density >1.910
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Ammonium picrate Raratol(76/24) mix
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HMX-Based PBX 9011 PBX 9404 PBX-950
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SHOCK INITIATION PROPERTIES 0.360 c
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SHOCK INITIATION PROPERTIES 432 I I
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES Explosi
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SHOCK INITIATION PROPERTIES TRANSIT
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SHOCK INITIATION PROPERTIES 442 FOI
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SENSITIVITY TESTS 5. SENSITIVITY TE
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Ammonium nitrate Ammonium picrate B
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-’ .-- _- ..- _ “. Cyclotol75/2
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Explosive RDX-Based with Metal Fill
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SENSITIVITY TESTS 5.2 Skid Test. Th
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Explosive Comp A-3 1.638 45 PBX 901
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SENSITIVITY TESTS 5.3 Large-Scale D
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SENSITIVITY TESTS 5.4 Spark Sensiti
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GLOSSARY ABH Amatex-20 ATNI BDNPA B
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NP OFHC ONT P-16 P-22 P-40 P-80 P-1
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AUTHOR IND Ablard, J. E. 141, 151 A
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SUBJECT INDEX ABH 461 Alex/20 204,
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pentaerythritol tetranitrate (PETN)
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