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XTX8003 1. GENERAL PROPERTIES 1.1 Chemical and Physical Description. XTX (Extex) 8003 consists of PETN coated with a low-temperature vulcanizing silicone resin, Sylgard 182. Uncured XTX 8003 is putty-like and can be extruded through small openings at modest pressures. After curing, it is white and rubbery. 1.2 Common Use. XTX 8003 is used in special applications that require explosives with small detonation failure diameters. 1.3 Toxicity.‘p2 There are no known toxicity problems associated with the use of Sylgard 182. PETN, because it is insoluble in water, is slightly toxic. The recom- mended maximum atmospheric concentration over an 8-h period is 15 mg/m3. 2. MANUFACTURE AND PROCUREMENT 2.1 Manufacture. Sylgard 182 resin and its curing agent are mixed with PETN in a high-shear vertical mixer to the consistency of wet sea sand. This material is passed through a three-roll differential paint mill until it is the consistency ‘of glazier’s putty. After milling, XTX 8003 has a shelf life of 24 h at 25°C. Storage at -30°C increases the shelf life to 8 months. When it is to be used, the XTX 8003 is extruded into molds of the desired configuration. Curing or polymerization is achieved by exposure to 65°C for 8-12 h. 188
XTX 8003 2.2 Procurement. XTX 8003 can be purchased from the DOE under LASL material specification 13Y-104481 Rev. F, dated February 6,1978. 2.3 Shipping.3 Cured or uncured XTX 8003 is shipped as a Class A explosive. 2.4 Storage.4 Uncured XTX 8003 is in Storage Compatibility Group A. When cured, it is stored in Compatibility Group D. Either cured or in a device, it is in Storage Class 1.1. 3. CHEMICAL PROPERTIES 3.1 Composition. 3.2 Molecular Weight. Constituent PETN Sylgard 182 Constituent PETN 80 Sylgard 182 20 Structure Weight Volume Percent Percent NO2 0 I 0. N-0-CH,-C-CH,-O-NO, 1 I WWS4, Proprietary 69.9 30.1 Molecular Weight 316.15 189
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LOS ALAMOS SERIES ON DYNAMIC MATERI
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University of California Press Berk
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PART II. EXPLOSIVES PROPERTIES BY P
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treats pure explosives first, alpha
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EXPLOSIVES PROPERTIES BY EXPLOSIVE
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BARATOL 2.3 Shipping.2 Baratol is s
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BARATOL 6 5.4 Thermal Conductivity.
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BARATOL 6.2 Detonation Pressure. We
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BARATOL REFERENCES . . 1. N. I. Sax
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COMP B slowly. Heating and stirring
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COMP B 14 3.3 Solubility.‘The sol
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COMP B 16 5.3 Heat Capacity. Heat C
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COMP B 18 6.2 Detonation Pressure.
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COMP B 7.3 Shock Hugoniots.12J8 Com
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COMP B 9. MECHANICAL PROPERTIES 22
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CYCLOTOL 1. GENERAL PROPERTIES 1.1
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CYCLOTOL 26 3.2 Molecular Weight. C
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CYCLOTOL 4.3 Infrared Spectrum. See
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CYCLOTOL where D = detonation veloc
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CYCLOTOL 8.3 Skid Test Results. Den
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DATB 1. GENERAL PROPERTIES 1.1 Chem
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DATB 4. PHYSICAL PROPERTIES 4.1 Cry
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DATB 5.4 Thermal Conductivity, Cond
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DATB 7.3 Shock Hugoniot.9 Density k
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HMX* 1. GENERAL PROPERTIES 1.1 Chem
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HMX 3.2 Molecular Weight. 296.17 3.
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HMX 5. THERMAL PROPERTIES 46 5.1 Ph
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HMX 6. DETONATION PROPERTIES 6.1 De
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HMX 7.3 Shock Hugoniots.” Density
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NITROGUANIDINE 1. GENERAL PROPERTIE
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NQ 54 4.2 Density.’ Crystal Metho
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NQ 56 5.6 Heats of Combustion and F
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NQ 6.2 Detonation Pressure. There a
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NQ 8. SENSITIVITY 8.1 Drop Weight I
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OCTOL These are shipped to an ordna
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64 OCTOL 3.3 Solubility.6 The solub
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OCTOL 5. THERMAL PROPERTIES 66 5.1
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OCTOL 68 6.4 Plate Dent Test Result
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OCTOL 8.3 Skid Test Results. Weight
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PBX 9011 1. GENERAL PROPERTIES 1.1
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PBX 9011 3.3 Solubility. The solubi
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PBX 9011 76 5.5 Coefficient of Ther
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PBX 9011 78 6.3 Cylinder Test Resul
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PBX 9011 7.5 Detonation Failure Thi
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PBX 9011 82 9.3 Compressive Strengt
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PBX9404 1. GENERAL PROPERTIES 1.1 C
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PBX 9404 86 3.2 Molecular Weight. C
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PBX 9404 88 4.3 Infrared Spectrum.
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PBX 9404 > 1 1 o- r 0 I I I, / PYRO
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PBX 9404 7. SHOCK INITIATION PROPER
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PBX 9404 7.5 Detonation Failure Thi
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PBX 9404 8.5 Spark Sensitivity. Ele
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PBX 9404 REFERENCE‘S 1. Committee
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PBX 9407 2.3 Shipping.2 PBX-9407 mo
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PBX 9407 4.3 Infrared Spectrum. See
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PBX 9407 6. DETONATION PROPERTIES I
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PBX 9407 106 7.2 Wedge Test Results
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PBX 9407 9.3 Compressive Strength a
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PBX 9501 2.3 Shipping.* PBX-9501mol
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PBX 9501 5. THERMAL PROPERTIES 112
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PBX 9501 6. DETONATION PROPERTIES 6
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PBX 9501 7.3 Shock Hugoniot. Densit
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PBX 9501 9. MECHANICAL PROPERTIES*
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PBX9502 1. GENERAL PROPERTIES 1.1 C
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PBX 9502 3.3 Solubility. The solubi
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PBX 9502 124 5.3 Heat Capacity. 5.4
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PBX 9502 6.3 Cylinder Test Results.
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PBX 9502 9. MECHANICAL PROPERTIES 1
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PENTAERYTHRITOLTETRANITRATE (PETN)
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PETN 3.2 Molecular Weight. 316.15 3
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PETN 4.4 Refractive Indices.s Omega
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PETN 5.7 Thermal Decomposition Kine
Page 146 and 147: PETN 138 7.2 Wedge Test Results. De
Page 148 and 149: , PETN 5. US Army Materiel Command,
Page 150 and 151: RDX developed into a continuous hig
Page 152 and 153: RDX 4. PHYSICAL PROPERTIES 4.1 Crys
Page 154 and 155: RDX 146 5.2 Vapor Pressure.8 Temper
Page 156 and 157: RDX 6. DETONATION PROPERTIES 148 6.
Page 158 and 159: RDX 7.3 Shock Hugoniot.” 8. SENSI
Page 160 and 161: TATB 1. GENERAL PROPERTIES 1.1 Chem
Page 162 and 163: TATB TATB solubility in sulfuric ac
Page 164 and 165: TATB 5.2 Vapor Pressure.6 A least s
Page 166 and 167: TATB I / / I I I I I I I ! \ I 1 \
Page 168 and 169: TATB 7.3 Shock Hugoniots.“+ A num
Page 170 and 171: TATB REFERENCES 1. T. M Benziger an
Page 172 and 173: TETRYL acetone. In the second proce
Page 174 and 175: TETRYL 2.5 100 80 60 % T 40 20 0 :;
Page 176 and 177: TETRYL 6. DETONATION PROPERTIES 6.1
Page 178 and 179: TETRYL 7.5 Detonation Failure Thick
Page 180 and 181: TNT 1. GENERAL PROPERTIES 1.1 Chemi
Page 182 and 183: TNT 4. PHYSICAL PROPERTIES 4.1 Crys
Page 184 and 185: TNT 4.3 Infrared Spectrum. See Fig.
Page 186 and 187: TNT 178 5.5 Coefficient of Thermal
Page 188 and 189: TNT The charge preparation method a
Page 190 and 191: TNT 182 6.4 Plate Dent Test Results
Page 192 and 193: TNT 7.3 Shock Hugoniots.2aJ4 Densit
Page 194 and 195: TNT 9.3 Compressive Strength and Mo
Page 198 and 199: XTX 8003 3.3 Solubility.6 The solub
Page 200 and 201: XTX 8003 5.7 Thermal Decomposition
Page 202 and 203: XTX 8003 8. SENSITIVITY 8.1 Drop We
Page 204 and 205: XTX8004 1. GENERAL PROPERTIES 1.1 C
Page 206 and 207: XTX 8004 3.3 Solubility. The solubi
Page 208 and 209: XTX 8004 6. DETONATION PROPERTIES 6
Page 210 and 211: PART II EXPLOSIVES PROPERTIES BY IP
Page 212 and 213: Explosive Alex/20 Alex/30 Amatex/20
Page 214 and 215: Explosive PBX 9007 PBX 9010 PBX 901
Page 216 and 217: Explosive Constituents X-0234-60 X-
Page 218 and 219: Alex/20 Alex/30 Amatexl20 Amatexl30
Page 220 and 221: NQ octo1 PAT0 Explosive PBX 9007 PB
Page 222 and 223: X-0234-60 X-0234-70 X-0234-80 X-028
Page 224 and 225: THERMAL PROPERTIES 2. THERMAL PROPE
Page 226 and 227: THERMAL PROPERTIES k2 = kl - (4, -
Page 228 and 229: Explosive PETN RDX TNT Table 2.03 C
Page 230 and 231: THERMAL PROPERTIES AEE = standard i
Page 232 and 233: THERMAL PROPERTIES Fig. 2.02. Pyrol
Page 234 and 235: ,’ THERMAL PROPERTIES L Y !s :: B
Page 236 and 237: THERMAL PROPERTIES 228 Composition
Page 238 and 239: THERMAL PROPERTIES B Y !3 E E “I
Page 240 and 241: THERMAL PROPERTIES This assembly is
Page 242 and 243: DETONATION PROPERTIES 3. DETONATION
Page 244 and 245: DETONATION PROPERTIES 236 Table 3.0
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Shot No. c-4394 E-4672 E-4067 E-406
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DETONATION PROPERTIES Table 3.06 CY
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Table 3.08 OCTOL DETONATION VELOCIT
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Rate Stick Shot ’ Diameter No. (m
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DETONATION PROPERTIES 246 Table 3.1
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Shot No. C-4436 E-3621 - Rate Stick
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Table 3.15 GENERAL CYLINDER TEST SH
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DETONATION PROPERTIES 252 Expansion
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Expansion Radius (mm) Table 3.19 X-
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N VI UY Table 3.21 X-0285 WALL VELO
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DETONATION PROPERTIES Table 3.25 X-
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Explosive Table 3.26 DETONATION (C-
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DETONATION PROPERTIES Analysis Line
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DETONATION PROPERTIES Explosive Tab
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DETONATION PROPERTIES 3.4 Plate Den
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Exnlosive Table 3.46 (continued) De
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Explosive PBX 9501 x-0007 86 HMX/14
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85 RDX/lS Kel-F Explosive 88 RDXI12
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DETONATION PROPERTIES Table 3.47 LE
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DETONATION PROPERTIES Table 3.48 DE
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SHOCK INITIATION PROPERTIES PETN Ba
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES each sh
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SHOCK INITIATION’PROPERTIES Table
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SHOCK INITIATION PROPERTIES 300 i;
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w R Table 4.04 NITROMETHANE Composi
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SHOCK INITIATION PROPERTIES 304 Tab
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SHOCK INITIATION PROPERTIES 306 / D
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SHOCK INITIATION PROPERTIES 308 2 0
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Table 4.06 (continued) Coordinates
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SHOCK INITIATION PROPERTIES 312 I-
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SHOCK INITIATION PROPERTIES 316 05
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Table 4.07 PETN (SINGLE CRYSTAL) Co
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Table 4.08 (continued) Shot Number
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SHOCK INITIATION PROPERTIES 324 2 u
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SHOCK INITIATION PROPERTIES Table 4
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SHOCK INITIATION PROPERTIES 334 2T
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Initial Shock Parameters Table 4.12
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SHOCK INITIATION PROPERTIES 342 Ini
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3 *a i 8 3 x j > f m e c u,, = (2.3
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SHOCK INITIATION PROPERTIES 348 Dis
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w ul 0 Composition 95 wt% DATB, 5 w
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SHOCK INITIATION PROPERTIES 5.5- 5.
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5 Table 4.17 (continued) Coordinate
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SHOCK INITIATION PROPERTIES 40- 20
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Shot E-3120 3.370 $0.022 E-3131 2.4
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_. Shot Number E-771 E-781 B-4481 B
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SHOCK INITIATION PROPERTIES 364 2 I
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SHOCK INITIATION PROPERTIES 366 0.6
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SHOCK INITIATION PROPERTIES Composi
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Table 4.21 X-0219-50-14-10 Composit
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Composition 95 wt% NQ, 5 wt% Estane
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Shot Number (G?a) E-3245 16.2 5.904
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SHOCK INITIATION PROPERTIES 380 c x
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w R Table 4.24 (continued) Reduced
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Table 4.25 XTX-8003 (EXTEX) Composi
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SHOCK INITIATION PROPERTIES 386 a--
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Table 4.27 PBX 9407 Compositon 94 w
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SHOCK INITIATION PROPERTIES 390 3 g
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Table 4.28 PBX 9405 Cotiposition 93
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SHOCK INITIATION PROPERTIES 394 c 5
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% OY Table 4.30 x-0250-40-19 Compos
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SHOCK INITIATION PROPERTIES 398 Dis
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Table 4.32 95 TATB/2.5 Kel-F 800/2.
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Table 4.39 (continued) Coordinates
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z Table 4.44 FKM CLASS VII PROPELLA
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Theoretical Maximum Density >1.910
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Ammonium picrate Raratol(76/24) mix
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HMX-Based PBX 9011 PBX 9404 PBX-950
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SHOCK INITIATION PROPERTIES 0.360 c
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SHOCK INITIATION PROPERTIES 432 I I
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES Explosi
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SHOCK INITIATION PROPERTIES TRANSIT
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SHOCK INITIATION PROPERTIES 442 FOI
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SENSITIVITY TESTS 5. SENSITIVITY TE
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Ammonium nitrate Ammonium picrate B
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-’ .-- _- ..- _ “. Cyclotol75/2
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Explosive RDX-Based with Metal Fill
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SENSITIVITY TESTS 5.2 Skid Test. Th
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Explosive Comp A-3 1.638 45 PBX 901
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SENSITIVITY TESTS 5.3 Large-Scale D
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SENSITIVITY TESTS 5.4 Spark Sensiti
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GLOSSARY ABH Amatex-20 ATNI BDNPA B
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NP OFHC ONT P-16 P-22 P-40 P-80 P-1
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AUTHOR IND Ablard, J. E. 141, 151 A
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SUBJECT INDEX ABH 461 Alex/20 204,
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pentaerythritol tetranitrate (PETN)
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