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TATB I / / I I I I I I I ! \ I 1 \ I\- I I I / 1 I I I I 1 I I I30 200 300 400 TEMPER*T”RE rc 1 Fig. 2. TATB DTA and pyrolysis test results. Effect of Densities Density affects the infinite diameter detonation velocity as follows: D = 2.480 + 2.852 pO, where D = infinite diameter velocity in millimeters per microseconds, and p0 = density in grams per cubic centimeter. Effect of Charge Diameter Charge diameter affects the detonation velocity of unconfined TATB pressed to a density of 1.860 g/ems as follows: 158 D = 7.758 - 0.472/d for d 2 4 mm where D = the detonation velocity in millimeters per microsecond, and d = charge diameter in millimeters. Failure Diameter The failure diameter of TATB pressed to a density of 1.860 g/cm3 is 4.0 mm. 6.2 Detonation Pressure.” Density Wcm3) Detonation Detonation Velocity Pressure (mdps) (GM 1.847 7.66 25.9 1.50 ___ 17.5
6.3 Cylinder Test. Results. Density k/cm? R-R,=5mm 1.860 1.268 6.4 Plate Dent Test Results. Charge Diameter Density (mm) k/cmY 41.3 1.87 7. SHOCK INITIATION PROPERTIES 7.1 Gap Test Results. 7.2 Wedge Test Results. Density (g/cm? 1.714 1.841 Density GO (g/ma) (mm) Cylinder Wall Velocity (rndw) at Large Scale 1.870 21.92 1.872 Small Scale Distance, x* , and Time, t*, to Detonation (mm and gs) R-R,= 19mm 1.446 Dent Charge Depth Height (mm) (mm) 8.31 203 LO5 (mm) 0.43 0.127 0.10 log P = (1.09 f 0.02) - (0.41 f 0.17) log x* log P = (0.8 f 0.07) - (0.32 f 0.12) log t*, log P = (1.39 f 0.07) - (0.52 f 0.07) log x* log P = (1.01 f 0.02) - (0.46 * 0.05) log t*, 1.876 log P = (1.42 f 0.02) - (0.40 f 0.03) log x* log P = (1.11 f 0.01) - (0.36 f 0.03) log t*, where P = pressure in gigapascals. Pressure Range (GPa) 3.27 < P < 5.64 5.93 < P < 16.5 TATB 11.4 < P < 16.22 159
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LOS ALAMOS SERIES ON DYNAMIC MATERI
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University of California Press Berk
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PART II. EXPLOSIVES PROPERTIES BY P
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treats pure explosives first, alpha
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EXPLOSIVES PROPERTIES BY EXPLOSIVE
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BARATOL 2.3 Shipping.2 Baratol is s
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BARATOL 6 5.4 Thermal Conductivity.
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BARATOL 6.2 Detonation Pressure. We
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BARATOL REFERENCES . . 1. N. I. Sax
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COMP B slowly. Heating and stirring
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COMP B 14 3.3 Solubility.‘The sol
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COMP B 16 5.3 Heat Capacity. Heat C
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COMP B 18 6.2 Detonation Pressure.
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COMP B 7.3 Shock Hugoniots.12J8 Com
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COMP B 9. MECHANICAL PROPERTIES 22
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CYCLOTOL 1. GENERAL PROPERTIES 1.1
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CYCLOTOL 26 3.2 Molecular Weight. C
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CYCLOTOL 4.3 Infrared Spectrum. See
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CYCLOTOL where D = detonation veloc
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CYCLOTOL 8.3 Skid Test Results. Den
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DATB 1. GENERAL PROPERTIES 1.1 Chem
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DATB 4. PHYSICAL PROPERTIES 4.1 Cry
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DATB 5.4 Thermal Conductivity, Cond
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DATB 7.3 Shock Hugoniot.9 Density k
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HMX* 1. GENERAL PROPERTIES 1.1 Chem
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HMX 3.2 Molecular Weight. 296.17 3.
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HMX 5. THERMAL PROPERTIES 46 5.1 Ph
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HMX 6. DETONATION PROPERTIES 6.1 De
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HMX 7.3 Shock Hugoniots.” Density
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NITROGUANIDINE 1. GENERAL PROPERTIE
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NQ 54 4.2 Density.’ Crystal Metho
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NQ 56 5.6 Heats of Combustion and F
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NQ 6.2 Detonation Pressure. There a
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NQ 8. SENSITIVITY 8.1 Drop Weight I
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OCTOL These are shipped to an ordna
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64 OCTOL 3.3 Solubility.6 The solub
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OCTOL 5. THERMAL PROPERTIES 66 5.1
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OCTOL 68 6.4 Plate Dent Test Result
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OCTOL 8.3 Skid Test Results. Weight
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PBX 9011 1. GENERAL PROPERTIES 1.1
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PBX 9011 3.3 Solubility. The solubi
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PBX 9011 76 5.5 Coefficient of Ther
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PBX 9011 78 6.3 Cylinder Test Resul
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PBX 9011 7.5 Detonation Failure Thi
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PBX 9011 82 9.3 Compressive Strengt
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PBX9404 1. GENERAL PROPERTIES 1.1 C
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PBX 9404 86 3.2 Molecular Weight. C
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PBX 9404 88 4.3 Infrared Spectrum.
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PBX 9404 > 1 1 o- r 0 I I I, / PYRO
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PBX 9404 7. SHOCK INITIATION PROPER
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PBX 9404 7.5 Detonation Failure Thi
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PBX 9404 8.5 Spark Sensitivity. Ele
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PBX 9404 REFERENCE‘S 1. Committee
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PBX 9407 2.3 Shipping.2 PBX-9407 mo
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PBX 9407 4.3 Infrared Spectrum. See
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PBX 9407 6. DETONATION PROPERTIES I
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PBX 9407 106 7.2 Wedge Test Results
Page 116 and 117: PBX 9407 9.3 Compressive Strength a
Page 118 and 119: PBX 9501 2.3 Shipping.* PBX-9501mol
Page 120 and 121: PBX 9501 5. THERMAL PROPERTIES 112
Page 122 and 123: PBX 9501 6. DETONATION PROPERTIES 6
Page 124 and 125: PBX 9501 7.3 Shock Hugoniot. Densit
Page 126 and 127: PBX 9501 9. MECHANICAL PROPERTIES*
Page 128 and 129: PBX9502 1. GENERAL PROPERTIES 1.1 C
Page 130 and 131: PBX 9502 3.3 Solubility. The solubi
Page 132 and 133: PBX 9502 124 5.3 Heat Capacity. 5.4
Page 134 and 135: PBX 9502 6.3 Cylinder Test Results.
Page 136 and 137: PBX 9502 9. MECHANICAL PROPERTIES 1
Page 138 and 139: PENTAERYTHRITOLTETRANITRATE (PETN)
Page 140 and 141: PETN 3.2 Molecular Weight. 316.15 3
Page 142 and 143: PETN 4.4 Refractive Indices.s Omega
Page 144 and 145: PETN 5.7 Thermal Decomposition Kine
Page 146 and 147: PETN 138 7.2 Wedge Test Results. De
Page 148 and 149: , PETN 5. US Army Materiel Command,
Page 150 and 151: RDX developed into a continuous hig
Page 152 and 153: RDX 4. PHYSICAL PROPERTIES 4.1 Crys
Page 154 and 155: RDX 146 5.2 Vapor Pressure.8 Temper
Page 156 and 157: RDX 6. DETONATION PROPERTIES 148 6.
Page 158 and 159: RDX 7.3 Shock Hugoniot.” 8. SENSI
Page 160 and 161: TATB 1. GENERAL PROPERTIES 1.1 Chem
Page 162 and 163: TATB TATB solubility in sulfuric ac
Page 164 and 165: TATB 5.2 Vapor Pressure.6 A least s
Page 168 and 169: TATB 7.3 Shock Hugoniots.“+ A num
Page 170 and 171: TATB REFERENCES 1. T. M Benziger an
Page 172 and 173: TETRYL acetone. In the second proce
Page 174 and 175: TETRYL 2.5 100 80 60 % T 40 20 0 :;
Page 176 and 177: TETRYL 6. DETONATION PROPERTIES 6.1
Page 178 and 179: TETRYL 7.5 Detonation Failure Thick
Page 180 and 181: TNT 1. GENERAL PROPERTIES 1.1 Chemi
Page 182 and 183: TNT 4. PHYSICAL PROPERTIES 4.1 Crys
Page 184 and 185: TNT 4.3 Infrared Spectrum. See Fig.
Page 186 and 187: TNT 178 5.5 Coefficient of Thermal
Page 188 and 189: TNT The charge preparation method a
Page 190 and 191: TNT 182 6.4 Plate Dent Test Results
Page 192 and 193: TNT 7.3 Shock Hugoniots.2aJ4 Densit
Page 194 and 195: TNT 9.3 Compressive Strength and Mo
Page 196 and 197: XTX8003 1. GENERAL PROPERTIES 1.1 C
Page 198 and 199: XTX 8003 3.3 Solubility.6 The solub
Page 200 and 201: XTX 8003 5.7 Thermal Decomposition
Page 202 and 203: XTX 8003 8. SENSITIVITY 8.1 Drop We
Page 204 and 205: XTX8004 1. GENERAL PROPERTIES 1.1 C
Page 206 and 207: XTX 8004 3.3 Solubility. The solubi
Page 208 and 209: XTX 8004 6. DETONATION PROPERTIES 6
Page 210 and 211: PART II EXPLOSIVES PROPERTIES BY IP
Page 212 and 213: Explosive Alex/20 Alex/30 Amatex/20
Page 214 and 215: Explosive PBX 9007 PBX 9010 PBX 901
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Explosive Constituents X-0234-60 X-
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Alex/20 Alex/30 Amatexl20 Amatexl30
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NQ octo1 PAT0 Explosive PBX 9007 PB
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X-0234-60 X-0234-70 X-0234-80 X-028
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THERMAL PROPERTIES 2. THERMAL PROPE
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THERMAL PROPERTIES k2 = kl - (4, -
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Explosive PETN RDX TNT Table 2.03 C
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THERMAL PROPERTIES AEE = standard i
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THERMAL PROPERTIES Fig. 2.02. Pyrol
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,’ THERMAL PROPERTIES L Y !s :: B
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THERMAL PROPERTIES 228 Composition
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THERMAL PROPERTIES B Y !3 E E “I
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THERMAL PROPERTIES This assembly is
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DETONATION PROPERTIES 3. DETONATION
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DETONATION PROPERTIES 236 Table 3.0
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Shot No. c-4394 E-4672 E-4067 E-406
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DETONATION PROPERTIES Table 3.06 CY
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Table 3.08 OCTOL DETONATION VELOCIT
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Rate Stick Shot ’ Diameter No. (m
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DETONATION PROPERTIES 246 Table 3.1
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Shot No. C-4436 E-3621 - Rate Stick
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Table 3.15 GENERAL CYLINDER TEST SH
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DETONATION PROPERTIES 252 Expansion
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Expansion Radius (mm) Table 3.19 X-
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N VI UY Table 3.21 X-0285 WALL VELO
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DETONATION PROPERTIES Table 3.25 X-
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Explosive Table 3.26 DETONATION (C-
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DETONATION PROPERTIES Analysis Line
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DETONATION PROPERTIES Explosive Tab
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DETONATION PROPERTIES 3.4 Plate Den
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Exnlosive Table 3.46 (continued) De
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Explosive PBX 9501 x-0007 86 HMX/14
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85 RDX/lS Kel-F Explosive 88 RDXI12
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DETONATION PROPERTIES Table 3.47 LE
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DETONATION PROPERTIES Table 3.48 DE
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SHOCK INITIATION PROPERTIES PETN Ba
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES each sh
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SHOCK INITIATION’PROPERTIES Table
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SHOCK INITIATION PROPERTIES 300 i;
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w R Table 4.04 NITROMETHANE Composi
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SHOCK INITIATION PROPERTIES 304 Tab
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SHOCK INITIATION PROPERTIES 306 / D
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SHOCK INITIATION PROPERTIES 308 2 0
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Table 4.06 (continued) Coordinates
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SHOCK INITIATION PROPERTIES 312 I-
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SHOCK INITIATION PROPERTIES 316 05
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Table 4.07 PETN (SINGLE CRYSTAL) Co
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Table 4.08 (continued) Shot Number
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SHOCK INITIATION PROPERTIES 324 2 u
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SHOCK INITIATION PROPERTIES Table 4
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SHOCK INITIATION PROPERTIES 334 2T
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Initial Shock Parameters Table 4.12
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SHOCK INITIATION PROPERTIES 342 Ini
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3 *a i 8 3 x j > f m e c u,, = (2.3
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SHOCK INITIATION PROPERTIES 348 Dis
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w ul 0 Composition 95 wt% DATB, 5 w
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SHOCK INITIATION PROPERTIES 5.5- 5.
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5 Table 4.17 (continued) Coordinate
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SHOCK INITIATION PROPERTIES 40- 20
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Shot E-3120 3.370 $0.022 E-3131 2.4
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_. Shot Number E-771 E-781 B-4481 B
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SHOCK INITIATION PROPERTIES 364 2 I
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SHOCK INITIATION PROPERTIES 366 0.6
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SHOCK INITIATION PROPERTIES Composi
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Table 4.21 X-0219-50-14-10 Composit
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Composition 95 wt% NQ, 5 wt% Estane
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Shot Number (G?a) E-3245 16.2 5.904
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SHOCK INITIATION PROPERTIES 380 c x
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w R Table 4.24 (continued) Reduced
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Table 4.25 XTX-8003 (EXTEX) Composi
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SHOCK INITIATION PROPERTIES 386 a--
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Table 4.27 PBX 9407 Compositon 94 w
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SHOCK INITIATION PROPERTIES 390 3 g
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Table 4.28 PBX 9405 Cotiposition 93
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SHOCK INITIATION PROPERTIES 394 c 5
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% OY Table 4.30 x-0250-40-19 Compos
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SHOCK INITIATION PROPERTIES 398 Dis
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Table 4.32 95 TATB/2.5 Kel-F 800/2.
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Table 4.39 (continued) Coordinates
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z Table 4.44 FKM CLASS VII PROPELLA
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Theoretical Maximum Density >1.910
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Ammonium picrate Raratol(76/24) mix
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HMX-Based PBX 9011 PBX 9404 PBX-950
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SHOCK INITIATION PROPERTIES 0.360 c
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SHOCK INITIATION PROPERTIES 432 I I
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES Explosi
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SHOCK INITIATION PROPERTIES TRANSIT
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SHOCK INITIATION PROPERTIES 442 FOI
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SENSITIVITY TESTS 5. SENSITIVITY TE
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Ammonium nitrate Ammonium picrate B
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-’ .-- _- ..- _ “. Cyclotol75/2
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Explosive RDX-Based with Metal Fill
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SENSITIVITY TESTS 5.2 Skid Test. Th
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Explosive Comp A-3 1.638 45 PBX 901
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SENSITIVITY TESTS 5.3 Large-Scale D
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SENSITIVITY TESTS 5.4 Spark Sensiti
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GLOSSARY ABH Amatex-20 ATNI BDNPA B
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NP OFHC ONT P-16 P-22 P-40 P-80 P-1
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AUTHOR IND Ablard, J. E. 141, 151 A
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SUBJECT INDEX ABH 461 Alex/20 204,
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pentaerythritol tetranitrate (PETN)
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