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DETONATION PROPERTIES Explosive Table 3.34 OCTOL ON DURAL HMX/TNT: 76.3 f 0.8 wt% HMX. 1.809 f 0.007 g/cmS. 155-mm-thick conical frustum of 279-mm small diameter and 324-mm large diameter with large end toward plate. P-080 and 32-mm-thick Plexiglas booster. D = 8.478 km/s at p0 = 1.814 g/cm3 and 77 wt% HMX. D increases -0.8031 km/s per O.OOl-g/cm3 density increase and -0.013 km/s per 1 wt% HMX increase. Plates Dural. Analysis Shot No. Plate Density (g/cm*) Plate Thickness (mm) Free-Surface Velocity (km/s)” 8A 1322 2.774 2.54 3.674 f 0.035 7c 151 2.782 6.31 3.644 f 0.064 8A 1337 2.774 6.37 3.698 f 0.039 7c 117 2.784 12.88 3.476 f 0.048 8A 1177 2.790 19.15 3.438 f 0.025 8A 1178 2.782 25.51 3.348 f 0.021 8A 1189 2.786 38.13 3.232 f 0.008 8A 1180 2.783 50.88 3.113 f 0.012 7c 166 2.783 76.76 2.859 f 0.010 “Mean and standard deviation of seven determinations on the first three shots listed, five determinations on the next five, and three determinations on the last. Linear least squares fitting gives U, = 3.695 km/s - 0.01160 t (mm). At t = 0, plate U, = 7.811 km/s, and P, = 39.72 GPa. Acoustic approximation with D = 8.452 km/s, pox = 1.809 g/cm3, and porn = 2.781 g/cm3 gives corresponding explosive parameters of P, = 33.84 GPa, U,, = 2.213 km/s, and y = 2.819. 268
Explosive Table 3.35 PBX 9206 (HMX/KEL-F) ON DURAL DETONATION PROPERTIES HMX/Kel.-F 3700: 92/8. 1.837 f 0.001 g/cm3. Two 76-mm-thick, 156-mm-diam pieces to ma.ke a 152-mm thickness. P-080 booster. D = 8.725 km/s at 41-mm diam and p. = 1852 g/cm2. Plates Dural. Analysis Shot No. Plate Plate Density Thickness k/cmS) (mm) Free-Surface Velocity (km/s)8 7c 225 2.788 6.34 3.658 zt 0.018 7c 210 2.774 12.81 3.560 f 0.032 7c 211 2.774 19.14 3.487 f 0.022 7c 212 2.774 25.10 3.511 f 0.014 7C 254 2.782 25.74 3.445 f 0.017 7C 214 2.782 38.13 3.307 z!z 0.008 7C 215 2.782 50.79 3.195 f 0.027 ----- ---- BMean and standard deviation of seven determinations on each shot. Linear le,ast squares fitting gives Uf, = 3.710 km/s - 0.01016 t (mm). At t = 0, plate US =7.821 km/s and P, = 39.93 GPa. Acoustic approximation with D = 8.685 km/s, pox =- 1.837 g/cm3, and porn = 2.779 g/cm3 gives corresponding explosive parameters of P, = 34.62 GPa, Up, = 2.170 km/s, and y = 3.002. 269
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LOS ALAMOS SERIES ON DYNAMIC MATERI
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University of California Press Berk
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PART II. EXPLOSIVES PROPERTIES BY P
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treats pure explosives first, alpha
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EXPLOSIVES PROPERTIES BY EXPLOSIVE
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BARATOL 2.3 Shipping.2 Baratol is s
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BARATOL 6 5.4 Thermal Conductivity.
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BARATOL 6.2 Detonation Pressure. We
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BARATOL REFERENCES . . 1. N. I. Sax
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COMP B slowly. Heating and stirring
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COMP B 14 3.3 Solubility.‘The sol
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COMP B 16 5.3 Heat Capacity. Heat C
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COMP B 18 6.2 Detonation Pressure.
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COMP B 7.3 Shock Hugoniots.12J8 Com
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COMP B 9. MECHANICAL PROPERTIES 22
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CYCLOTOL 1. GENERAL PROPERTIES 1.1
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CYCLOTOL 26 3.2 Molecular Weight. C
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CYCLOTOL 4.3 Infrared Spectrum. See
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CYCLOTOL where D = detonation veloc
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CYCLOTOL 8.3 Skid Test Results. Den
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DATB 1. GENERAL PROPERTIES 1.1 Chem
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DATB 4. PHYSICAL PROPERTIES 4.1 Cry
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DATB 5.4 Thermal Conductivity, Cond
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DATB 7.3 Shock Hugoniot.9 Density k
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HMX* 1. GENERAL PROPERTIES 1.1 Chem
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HMX 3.2 Molecular Weight. 296.17 3.
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HMX 5. THERMAL PROPERTIES 46 5.1 Ph
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HMX 6. DETONATION PROPERTIES 6.1 De
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HMX 7.3 Shock Hugoniots.” Density
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NITROGUANIDINE 1. GENERAL PROPERTIE
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NQ 54 4.2 Density.’ Crystal Metho
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NQ 56 5.6 Heats of Combustion and F
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NQ 6.2 Detonation Pressure. There a
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NQ 8. SENSITIVITY 8.1 Drop Weight I
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OCTOL These are shipped to an ordna
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64 OCTOL 3.3 Solubility.6 The solub
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OCTOL 5. THERMAL PROPERTIES 66 5.1
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OCTOL 68 6.4 Plate Dent Test Result
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OCTOL 8.3 Skid Test Results. Weight
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PBX 9011 1. GENERAL PROPERTIES 1.1
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PBX 9011 3.3 Solubility. The solubi
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PBX 9011 76 5.5 Coefficient of Ther
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PBX 9011 78 6.3 Cylinder Test Resul
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PBX 9011 7.5 Detonation Failure Thi
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PBX 9011 82 9.3 Compressive Strengt
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PBX9404 1. GENERAL PROPERTIES 1.1 C
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PBX 9404 86 3.2 Molecular Weight. C
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PBX 9404 88 4.3 Infrared Spectrum.
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PBX 9404 > 1 1 o- r 0 I I I, / PYRO
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PBX 9404 7. SHOCK INITIATION PROPER
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PBX 9404 7.5 Detonation Failure Thi
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PBX 9404 8.5 Spark Sensitivity. Ele
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PBX 9404 REFERENCE‘S 1. Committee
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PBX 9407 2.3 Shipping.2 PBX-9407 mo
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PBX 9407 4.3 Infrared Spectrum. See
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PBX 9407 6. DETONATION PROPERTIES I
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PBX 9407 106 7.2 Wedge Test Results
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PBX 9407 9.3 Compressive Strength a
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PBX 9501 2.3 Shipping.* PBX-9501mol
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PBX 9501 5. THERMAL PROPERTIES 112
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PBX 9501 6. DETONATION PROPERTIES 6
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PBX 9501 7.3 Shock Hugoniot. Densit
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PBX 9501 9. MECHANICAL PROPERTIES*
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PBX9502 1. GENERAL PROPERTIES 1.1 C
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PBX 9502 3.3 Solubility. The solubi
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PBX 9502 124 5.3 Heat Capacity. 5.4
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PBX 9502 6.3 Cylinder Test Results.
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PBX 9502 9. MECHANICAL PROPERTIES 1
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PENTAERYTHRITOLTETRANITRATE (PETN)
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PETN 3.2 Molecular Weight. 316.15 3
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PETN 4.4 Refractive Indices.s Omega
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PETN 5.7 Thermal Decomposition Kine
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PETN 138 7.2 Wedge Test Results. De
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, PETN 5. US Army Materiel Command,
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RDX developed into a continuous hig
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RDX 4. PHYSICAL PROPERTIES 4.1 Crys
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RDX 146 5.2 Vapor Pressure.8 Temper
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RDX 6. DETONATION PROPERTIES 148 6.
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RDX 7.3 Shock Hugoniot.” 8. SENSI
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TATB 1. GENERAL PROPERTIES 1.1 Chem
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TATB TATB solubility in sulfuric ac
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TATB 5.2 Vapor Pressure.6 A least s
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TATB I / / I I I I I I I ! \ I 1 \
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TATB 7.3 Shock Hugoniots.“+ A num
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TATB REFERENCES 1. T. M Benziger an
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TETRYL acetone. In the second proce
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TETRYL 2.5 100 80 60 % T 40 20 0 :;
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TETRYL 6. DETONATION PROPERTIES 6.1
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TETRYL 7.5 Detonation Failure Thick
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TNT 1. GENERAL PROPERTIES 1.1 Chemi
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TNT 4. PHYSICAL PROPERTIES 4.1 Crys
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TNT 4.3 Infrared Spectrum. See Fig.
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TNT 178 5.5 Coefficient of Thermal
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TNT The charge preparation method a
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TNT 182 6.4 Plate Dent Test Results
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TNT 7.3 Shock Hugoniots.2aJ4 Densit
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TNT 9.3 Compressive Strength and Mo
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XTX8003 1. GENERAL PROPERTIES 1.1 C
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XTX 8003 3.3 Solubility.6 The solub
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XTX 8003 5.7 Thermal Decomposition
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XTX 8003 8. SENSITIVITY 8.1 Drop We
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XTX8004 1. GENERAL PROPERTIES 1.1 C
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XTX 8004 3.3 Solubility. The solubi
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XTX 8004 6. DETONATION PROPERTIES 6
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PART II EXPLOSIVES PROPERTIES BY IP
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Explosive Alex/20 Alex/30 Amatex/20
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Explosive PBX 9007 PBX 9010 PBX 901
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Explosive Constituents X-0234-60 X-
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Alex/20 Alex/30 Amatexl20 Amatexl30
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NQ octo1 PAT0 Explosive PBX 9007 PB
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X-0234-60 X-0234-70 X-0234-80 X-028
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THERMAL PROPERTIES 2. THERMAL PROPE
Page 226 and 227: THERMAL PROPERTIES k2 = kl - (4, -
Page 228 and 229: Explosive PETN RDX TNT Table 2.03 C
Page 230 and 231: THERMAL PROPERTIES AEE = standard i
Page 232 and 233: THERMAL PROPERTIES Fig. 2.02. Pyrol
Page 234 and 235: ,’ THERMAL PROPERTIES L Y !s :: B
Page 236 and 237: THERMAL PROPERTIES 228 Composition
Page 238 and 239: THERMAL PROPERTIES B Y !3 E E “I
Page 240 and 241: THERMAL PROPERTIES This assembly is
Page 242 and 243: DETONATION PROPERTIES 3. DETONATION
Page 244 and 245: DETONATION PROPERTIES 236 Table 3.0
Page 246 and 247: Shot No. c-4394 E-4672 E-4067 E-406
Page 248 and 249: DETONATION PROPERTIES Table 3.06 CY
Page 250 and 251: Table 3.08 OCTOL DETONATION VELOCIT
Page 252 and 253: Rate Stick Shot ’ Diameter No. (m
Page 254 and 255: DETONATION PROPERTIES 246 Table 3.1
Page 256 and 257: Shot No. C-4436 E-3621 - Rate Stick
Page 258 and 259: Table 3.15 GENERAL CYLINDER TEST SH
Page 260 and 261: DETONATION PROPERTIES 252 Expansion
Page 262 and 263: Expansion Radius (mm) Table 3.19 X-
Page 264 and 265: N VI UY Table 3.21 X-0285 WALL VELO
Page 266 and 267: DETONATION PROPERTIES Table 3.25 X-
Page 268 and 269: Explosive Table 3.26 DETONATION (C-
Page 270 and 271: DETONATION PROPERTIES Analysis Line
Page 272 and 273: DETONATION PROPERTIES Explosive Tab
Page 288 and 289: DETONATION PROPERTIES 3.4 Plate Den
Page 290 and 291: Exnlosive Table 3.46 (continued) De
Page 292 and 293: Explosive PBX 9501 x-0007 86 HMX/14
Page 294 and 295: 85 RDX/lS Kel-F Explosive 88 RDXI12
Page 296 and 297: DETONATION PROPERTIES Table 3.47 LE
Page 298 and 299: DETONATION PROPERTIES Table 3.48 DE
Page 300 and 301: SHOCK INITIATION PROPERTIES PETN Ba
Page 302 and 303: SHOCK INITIATION PROPERTIES Fig. 4.
Page 304 and 305: SHOCK INITIATION PROPERTIES each sh
Page 306 and 307: SHOCK INITIATION’PROPERTIES Table
Page 308 and 309: SHOCK INITIATION PROPERTIES 300 i;
Page 310 and 311: w R Table 4.04 NITROMETHANE Composi
Page 312 and 313: SHOCK INITIATION PROPERTIES 304 Tab
Page 314 and 315: SHOCK INITIATION PROPERTIES 306 / D
Page 316 and 317: SHOCK INITIATION PROPERTIES 308 2 0
Page 318 and 319: Table 4.06 (continued) Coordinates
Page 320 and 321: SHOCK INITIATION PROPERTIES 312 I-
Page 322 and 323: SHOCK INITIATION PROPERTIES 314 4 3
Page 324 and 325: SHOCK INITIATION PROPERTIES 316 05
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Table 4.07 PETN (SINGLE CRYSTAL) Co
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Table 4.08 (continued) Shot Number
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SHOCK INITIATION PROPERTIES 322 20
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SHOCK INITIATION PROPERTIES 324 2 u
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SHOCK INITIATION PROPERTIES 326 2 0
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SHOCK INITIATION PROPERTIES Table 4
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SHOCK INITIATION PROPERTIES 334 2T
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Initial Shock Parameters Table 4.12
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SHOCK INITIATION PROPERTIES 342 Ini
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3 *a i 8 3 x j > f m e c u,, = (2.3
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SHOCK INITIATION PROPERTIES 348 Dis
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w ul 0 Composition 95 wt% DATB, 5 w
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SHOCK INITIATION PROPERTIES 5.5- 5.
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5 Table 4.17 (continued) Coordinate
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SHOCK INITIATION PROPERTIES 40- 20
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Shot E-3120 3.370 $0.022 E-3131 2.4
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_. Shot Number E-771 E-781 B-4481 B
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SHOCK INITIATION PROPERTIES 364 2 I
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SHOCK INITIATION PROPERTIES 366 0.6
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SHOCK INITIATION PROPERTIES 368 20
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SHOCK INITIATION PROPERTIES Composi
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Table 4.21 X-0219-50-14-10 Composit
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Composition 95 wt% NQ, 5 wt% Estane
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Shot Number (G?a) E-3245 16.2 5.904
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SHOCK INITIATION PROPERTIES 380 c x
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w R Table 4.24 (continued) Reduced
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Table 4.25 XTX-8003 (EXTEX) Composi
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SHOCK INITIATION PROPERTIES 386 a--
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Table 4.27 PBX 9407 Compositon 94 w
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SHOCK INITIATION PROPERTIES 390 3 g
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Table 4.28 PBX 9405 Cotiposition 93
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SHOCK INITIATION PROPERTIES 394 c 5
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% OY Table 4.30 x-0250-40-19 Compos
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SHOCK INITIATION PROPERTIES 398 Dis
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Table 4.32 95 TATB/2.5 Kel-F 800/2.
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SHOCK INITIATION PROPERTIES 402 Tab
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Table 4.39 (continued) Coordinates
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z Table 4.44 FKM CLASS VII PROPELLA
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Theoretical Maximum Density >1.910
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Ammonium picrate Raratol(76/24) mix
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HMX-Based PBX 9011 PBX 9404 PBX-950
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SHOCK INITIATION PROPERTIES 0.360 c
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SHOCK INITIATION PROPERTIES 432 I I
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SHOCK INITIATION PROPERTIES Fig. 4.
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SHOCK INITIATION PROPERTIES Explosi
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SHOCK INITIATION PROPERTIES TRANSIT
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SHOCK INITIATION PROPERTIES 442 FOI
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SENSITIVITY TESTS 5. SENSITIVITY TE
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Ammonium nitrate Ammonium picrate B
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-’ .-- _- ..- _ “. Cyclotol75/2
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Explosive RDX-Based with Metal Fill
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SENSITIVITY TESTS 5.2 Skid Test. Th
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Explosive Comp A-3 1.638 45 PBX 901
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SENSITIVITY TESTS 5.3 Large-Scale D
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SENSITIVITY TESTS 5.4 Spark Sensiti
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GLOSSARY ABH Amatex-20 ATNI BDNPA B
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NP OFHC ONT P-16 P-22 P-40 P-80 P-1
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AUTHOR IND Ablard, J. E. 141, 151 A
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SUBJECT INDEX ABH 461 Alex/20 204,
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pentaerythritol tetranitrate (PETN)
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