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Untitled - Sciencemadness Dot Org

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DATB<br />

5.4 Thermal Conductivity,<br />

Conductivity<br />

(Cal/s-cm-%)<br />

6.19 x lo-”<br />

5.6 Heats of Combustion and Formatioh at 25”C6<br />

5.7 Thermal Decomposition Kinetics.7<br />

AH; AH;<br />

(kcal/mole) (kcal/mole)<br />

-711.5 -23.6<br />

Decomposition energy 300 Cal/g<br />

Activation energy 46.3 kcal/mole<br />

Pre-exponential factor 1.17 X 1016/s<br />

5.8 Other Thermal Stability Test Results.<br />

Vacuum<br />

DTA and pyrolysis<br />

Critical temperature, Tm<br />

Charge radius, a<br />

Density, p<br />

6. DETONATION PROPERTIES<br />

38<br />

6.1 Detonation Velocity.8,8<br />

Test Results<br />

O.l-0;3 ml/g of gas evolved<br />

after 48 hat 120°C<br />

See Fig. 2<br />

322 “C<br />

3.5 mm<br />

1.74 g/cm3<br />

Effect of Density<br />

The infinite-diameter detonation velocity as a function of density is given by<br />

D = 2.480 + 2.852 p. ,<br />

where D = detonation velocity in millimeters per microsecond<br />

and p,, = charge density in grams per cubic centimeter.

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