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Engineering plastics – The Manual - F.wood-supply.dk

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F<br />

C<br />

F<br />

F<br />

C<br />

F<br />

n<br />

80<br />

PTFE<br />

F F<br />

C C<br />

F F<br />

n<br />

60<br />

40<br />

PTFE Structural formula PTFE<br />

H F<br />

C C<br />

n<br />

H F<br />

PVDF Structural formula PVDF<br />

H F<br />

C C<br />

n<br />

H F<br />

• Stress [MPa]<br />

20<br />

0<br />

0 5 10 15<br />

20<br />

• Strain [%]<br />

TECAFLON PVDF (?)<br />

TECAFLON PVDF<br />

PVDF<br />

TECAFLON<br />

PVDF, PTFE (DIN designation)<br />

Polyvinylidene fluoride (PVDF) and polytetrafluoroethylene<br />

(PTFE) belong to the group of highly chemically resistant<br />

fluorothermo<strong>plastics</strong>. Due to its high molecular<br />

weight, highly chemically resistant PTFE cannot be processed<br />

by melting, but only by pressing and sintering to<br />

create semi-finished products. PVDF can be formed by extrusion.<br />

Properties: PVDF<br />

ˌˌHigh density<br />

ˌˌStrong and tough<br />

ˌˌMinimal toughness at low temperatures<br />

ˌˌHigh chemical resistance<br />

ˌˌHydrolysis-resistant<br />

ˌˌVery low moisture absorption<br />

ˌˌHigh thermal expansion<br />

ˌˌHigh dissipation factor, polar,<br />

not suitable for high-frequency applications<br />

ˌˌHigh resistance to UV radiation<br />

ˌˌPVDF is significantly more resistant to energetic<br />

radiation than all other fluorothermo<strong>plastics</strong><br />

ˌˌInherently flame resistant, self-extinguishing<br />

ˌˌReleases highly toxic gas in case of fire<br />

Properties: PTFE<br />

ˌˌVery high crystallinity<br />

ˌˌHighest density of all polymers<br />

ˌˌVery tough down to low temperatures<br />

ˌˌMinimal strength and hardness<br />

ˌˌPoor creep strength<br />

ˌˌExtremely high resistance to chemicals,<br />

also to oxidizing acids<br />

ˌˌHydrolysis-resistant<br />

ˌˌNo stress crack formation<br />

ˌˌVery low moisture absorption<br />

ˌˌHigh thermal stability, but low<br />

dimensional stability at temperature<br />

ˌˌAnti-adhesive properties, very good<br />

sliding properties, no stick-slip behaviour<br />

ˌˌHigh resistance to UV radiation<br />

ˌˌVery sensitive to severe radiation (gamma and X-rays)<br />

ˌˌNot bondable with conventional materials<br />

ˌˌHigh thermal expansion<br />

ˌˌMinimal dissipation factor<br />

ˌˌVery good electrical insulation properties<br />

due to their low microstructure density, RAM extruded<br />

products offer characteristics such as minimal dielectric<br />

strength under high voltage)<br />

ˌˌInherently flame resistant, self-extinguishing<br />

ˌˌCombustion gases are fluoric, highly toxic<br />

28

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