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Engineering plastics – The Manual - F.wood-supply.dk

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Values<br />

TECAFLON PVDF<br />

(PVDF)<br />

TECAFLON PTFE<br />

(PTFE)<br />

T g –40 °C –20 °C<br />

Density 1.78 g/cm 3 2.15 g/cm 3<br />

Modulus of elasticity 2,200 MPa 700 MPa<br />

Service temperature, long-term 150 °C 260 °C<br />

Service temperature, short-term 150 °C 260 °C<br />

Lower service temperature –30 °C –200 °C<br />

(Exceptions<br />

<br />

down to –270 °C)<br />

Application examples<br />

PTFE is the most commonly used and important fluoropolymer<br />

with the most extensive fields of application:<br />

Chemical plant engineering, food and pharmaceutical<br />

technology. PTFE is preferred for sliding applications with<br />

exposure to extreme chemical stress. PVDF is ideal for<br />

chemical plant construction and high pressure loads under<br />

exposure to elevated temperatures, for valves, filter plates,<br />

fittings, pipelines, special types for ultra-pure water treatment<br />

plants.<br />

Identifying characteristics: PVDF<br />

ˌˌColour opaque / milky white<br />

ˌˌLow flammability<br />

ˌˌBurns with luminous yellow flame<br />

ˌˌExtinguishes after removing the flame<br />

ˌˌIrritant odour<br />

ˌˌHigh density (tangibly evident)<br />

ˌˌDifficult to score with a fingernail<br />

Identifying characteristics: PTFE<br />

ˌˌRadiant white, opaque<br />

ˌˌLow flammability<br />

ˌˌDoes not burn<br />

ˌˌIrritant odour<br />

ˌˌHigh density (tangibly evident)<br />

ˌˌSoft, easily deformable, easily scored using a fingernail<br />

Summary<br />

When determining the dimension of PTFE parts, consideration<br />

must be given to the extreme increase in the coefficient<br />

of thermal expansion as a result of microstructure<br />

changes taking place in the range of around 18 °C to 20 °C.<br />

Dimensions should be defined at a range of appr. 23 °C.<br />

PVDF has higher strength, with strength values at 150 °C<br />

still approximately as high as PTFE at room temperature.<br />

PVDF has lower chemical resistance than PTFE.<br />

<strong>The</strong> reinforcement of PVDF and PTFE with glass fibres is<br />

only recommended when taking special precautionary<br />

measures and using selected additives due to a possible<br />

thermal degradation reaction resulting in a release of gas<br />

and deflagration.<br />

Products / Modifications<br />

TECAFLON PVDF (PVDF)<br />

Unreinforced basic types<br />

TECAFLON PTFE (PTFE)<br />

Unreinforced basic types<br />

TECAFLON PVDF ELS<br />

(conductive carbon black)<br />

electrically conductive<br />

29

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