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Engineering plastics – The Manual - F.wood-supply.dk

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<strong>The</strong>rmal properties<br />

Characteristic temperatures<br />

Service temperatures<br />

Glass transition temperature<br />

<strong>The</strong> glass transition temperature T g is the temperature at<br />

which polymers change from a hard elastic and brittle state<br />

to a flexible rubbery elastic state. A distinction must be<br />

made here between amorphous and partially crystalline<br />

thermo<strong>plastics</strong>.<br />

• Modulus<br />

• Temperature<br />

amorphous<br />

T g<br />

T g<br />

T m<br />

• Modulus<br />

• Temperature<br />

semi-crystalline<br />

An amorphous material can be subjected to mechanical<br />

wear above the T g , as here its mechanical strength decreases<br />

sharply. Partially crystalline materials, in contrast, still<br />

demonstrate a certain mechanical strength beyond the T g<br />

due to their crystalline areas, and are therefore particularly<br />

well suited for components exposed to mechanical stress.<br />

Melting temperature<br />

<strong>The</strong> melting temperature T m is the temperature at which a<br />

material melts, i.e. changes from the solid to the fluid aggregate<br />

state and its crystalline structures break down.<br />

Long-term service temperature<br />

<strong>The</strong> long-term service temperature is defined as the maximum<br />

temperature at which a plastic has lost no more than<br />

50 % of its initial properties after 20,000 hours of storage in<br />

hot air (in accordance with IEC 216).<br />

Short-term service temperature<br />

<strong>The</strong> short-term service temperature is the short-term peak<br />

temperature which the plastic can tolerate over a short period<br />

(from minutes to occasionally hours) taking into consideration<br />

the stress level and duration, without sustaining<br />

damage.<br />

<strong>The</strong> maximum service temperature is dependent upon the<br />

following factors:<br />

ˌˌDuration of exposure to temperature<br />

ˌˌMaximum admissible deformation<br />

ˌˌDegradation of strength characteristics<br />

due to thermal oxidation<br />

ˌˌAmbient conditions<br />

Negative service temperatures<br />

<strong>The</strong> service temperature in the negative temperature range<br />

is not precisely defined and depends largely on different<br />

characteristics and ambient conditions:<br />

ˌˌToughness / brittleness of a material<br />

ˌˌModification: materials with reinforcement<br />

fibres tend to demonstrate hard-brittle behaviour<br />

ˌˌTemperature<br />

ˌˌDuration of load<br />

ˌˌType of load (e.g. impact or vibration load)<br />

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