OP-II-3

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OP-II-26DESIGN, SCALE-OUT AND OPERATION OF MILLI-CHANNELREACTOR WITH STRUCTURED Ni/CeO 2 CATALYST FORPREFERENTIAL CO METHANATIONPopova M.M. 1,2 , Snytnikov P.V. 1,2 , Amosov Yu.I. 1,2 , Kuzmin V.A. 1 ,Shigarov A.B. 1,2 , Kirillov V.A. 1,2 , Sobyanin V.A. 1,21 Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva, 5, Novosibirsk, 630090,Russia, popovamm@catalysis.ru2 Novosibirsk State University, Pirogova St., 2, Novosibirsk, 630090, RussiaPreferential CO methanation in the presence of CO 2 is one of the promisingmethods for CO removal from hydrogen-rich gas mixtures produced by hydrocarbonsconversion processes for feeding of the low temperature polymer electolytemembrane fuel cells. Compared to preferential CO oxidation reaction, preferentialCO methanation is a more feasible process as it uses no oxygen (air), hydrogen-richgas is not diluted with nitrogen and allows reducing CO level to
OP-II-26It was found that the 10 wt.% Ni/CeO 2 catalyst showed good performance anddecreased the CO concentration to
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Boreskov Institute of Catalysisof t
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INTERNATIONAL SCIENTIFIC COMMITTEEV
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SILVER SPONSORThe organizers expres
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PL-1HOW TO DESIGN OPTIMAL CATALYTIC
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MULTIFUNCTIONAL DEVICES FOR INTENSI
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PL-3DESIGN OF CATALYTIC PROCESSES F
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PL-3Indeed preparation and testing
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PL-4The second part of the lecture
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PL-5Reactor designs with intensifie
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PL-6MEMBRANE REACTORS: STATE OF THE
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KEY-NOTE PRESENTATIONS
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KN-1description, that can be charac
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KN-2selective catalytic reduction o
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KN-3Fig. 1. Experimental burner of
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KN-4~200°C. This is based on the H
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KN-5for addressing the quality of t
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KN-6reaction with ethanol and the b
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KN-7at temperature lower than 873K,
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REACTION KINETICS AND REACTION ENHA
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OP-I-2RELATION BETWEEN THE ACTIVATI
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COMPARISON OF CHEMICAL AND ENZYMATI
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OP-I-4NONLINEAR PHENOMENA DURING ME
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OP-I-5SPECIFICITY OF THE OSCILLATIO
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OP-I-6TRENDS IN BISTABILITY DOMAINS
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OP-I-7NON-STEADY-STATE CATALYST CHA
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OP-I-8TRANSIENT KINETIC STUDIES OF
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OP-I-9A REDOX KINETICS FOR THE PART
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OP-I-9500Flow of Air = 0.3 m 3 (STP
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OP-I-11ELUCIDATION OF THE REACTIVIT
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KINETIC MODELLING OF THE JOINT TRAN
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OP-I-13n-HEXANE SKELETAL ISOMERIZAT
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OP-I-14the slow branch of kinetic c
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OP-I-15The hydride palladium comple
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Energy Conservation (field j)∂∂
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OP-I-17Selectivity (mol. %)10099989
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OP-I-18According to GLC the main pr
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OP-I-19and slug dimensions, formati
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OP-I-20A RANS volume of fluids [1]
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OP-I-21the physical-chemical charac
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OP-I-22calculated values of pressur
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OP-I-23where L c - capillary length
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OP-I-24and diffuse transmission thr
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OP-I-25effect of bubble break-up wo
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OP-I-26strong influence on the soli
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OP-I-27wHCOOH=1+K2K1(1 + K3⋅ P⋅
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OP-I-28dimensional profiles detecte
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OP-I-29results. The results of the
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OP-I-30Fig. 1. Hydrodynamics and co
Page 97 and 98: OP-I-31Convection and diffusion wit
Page 99 and 100: TEMPERATURE RISE DURING REGENERATIO
Page 101 and 102: OP-II-2[4]. Similar temperature pro
Page 103 and 104: OP-II-3(Fig, 1 a, b) upon testing i
Page 105 and 106: OP-II-4In the second step optimizat
Page 107 and 108: OP-II-5membrane contactors were stu
Page 109 and 110: OP-II-6reaction over Cu/CeO 2-x cat
Page 111 and 112: OP-II-7is modelled by means of a tw
Page 113 and 114: OP-II-8the reactor [6]. However, th
Page 115 and 116: OP-II-9Figure 1. Computed volume fr
Page 117 and 118: OP-II-10assumes variables’ distri
Page 119 and 120: OP-II-11oxide support, it comes tha
Page 121 and 122: OP-II-12was connected to G.C. via s
Page 123 and 124: OP-II-13catalyst bed was 6 mm. Thre
Page 125 and 126: OP-II-14as coolant is an important
Page 127 and 128: OP-II-15Flow (L/h)7654321Bottoms ra
Page 129 and 130: OP-II-16(4) The gas recirculation r
Page 131 and 132: OP-II-17Catalytic reactions were ca
Page 133 and 134: OP-II-18At steady surface coverage
Page 135 and 136: OP-II-19gaimpulsegeneratorwateFig.
Page 137 and 138: OP-II-20examined (see Figure 1). Th
Page 139 and 140: OP-II-21References[1]. M.P. Dudukov
Page 141 and 142: OP-II-22of the hydrogen oxidation a
Page 143 and 144: OP-II-23TemperaturesensorsThe efflu
Page 145 and 146: OP-II-24of reactant conversions. Pa
Page 147: OP-II-25(surface) ‘wall-reaction
Page 151 and 152: OP-II-27non-flow type. During the M
Page 153 and 154: OP-III-A-1A NEW SIMPLE MICROCHANNEL
Page 155 and 156: BUBBLING FLUIDISED BED PYROLYSIS OF
Page 157 and 158: PINEWOOD PYROLYSIS UNDER VACUUM CON
Page 159 and 160: OP-III-A-5PYROLYSIS OF HDPE IN A CO
Page 161 and 162: OP-III-A-6REACTORS FOR THE GREEN TR
Page 163 and 164: DEHYDRATION OF GLYCEROL TO ACROLEIN
Page 165 and 166: OP-III-A-8LACTIC ACID BASED ON BIO
Page 167 and 168: RECOVERY OF ACETIC ACID FROM PYROLY
Page 169 and 170: OP-III-A-10LIPASE-CATALYZED REACTIO
Page 171 and 172: OP-III-A-11INVESTIGATION ON THERMOC
Page 173 and 174: OP-III-A-12SELECTIVE CATALYTIC DEOX
Page 175 and 176: ETHANOL STEAM REFORMING OVER COBALT
Page 177 and 178: OP-III-A-14HYDROTREATMENT CATALYSTS
Page 179 and 180: ORAL PRESENTATIONSSECTION IIIChemic
Page 181 and 182: OP-III-B-1Reactor parameters:Intern
Page 183 and 184: OP-III-B-2JOINT STEAM REFORMING OF
Page 185 and 186: OP-III-B-3LANDFILL BIOGAS PURIFICAT
Page 187 and 188: OP-III-B-4MODELING AND SIMULATION O
Page 189 and 190: OP-III-B-5DemonstratorThe medium-te
Page 191 and 192: OP-III-B-630/19.6 Nl/min (space vel
Page 193 and 194: OP-III-B-7mixed in the ratios: 94,8
Page 195 and 196: OP-III-B-8Table 1.Material balance
Page 197 and 198: OP-III-B-9Based on the results of t
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OP-III-B-10On this basis it can be
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OP-III-B-11Similar trends caused by
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OP-III-B-12(mol/s g cat)x108r4,6-DM
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OP-III-B-13carbon in Wyoming coal i
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OP-III-B-14MODELING PRODUCT DISTRIB
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OP-III-B-15COMBINED TECHNOLOGY OF U
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MATEMATICAL MODEL FOR DOWNDRAFT BIO
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OP-III-B-17CATALYTIC DEHYDRATION OF
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OP-III-B-18SYNGAS AND HYDROGEN PROD
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POSTER PRESENTATIONSSECTION I
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PP-I-1influence of the direction of
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PP-I-2At the agitation of the liqui
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PP-I-3NOLINEAR PHENOMENA IN CATALYT
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PP-I-4A NEW APPROACH TO KINETIC STU
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PP-I-5KINETICS OF PROX REACTION OVE
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PP-I-6PHENOMENA OF SUPERADIABATIC T
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ELECTROMAGNETIC REACTOR OF WATER TR
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PP-I-8DIRECT SYNTHESIS OF HYDROGEN
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PP-I-9DYNAMICS OF FIRST-ORDER PHASE
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PP-I-10ELECTROCHEMICAL OXIDATION OF
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PP-I-11CHEMPAK SOFTWARE PACKAGE: OP
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PP-I-12COMPUTER SIMULATION OF ENDOT
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PP-I-13MODELLING KINETICS OF PROCES
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PP-I-14THE INVESTIGATION OF REACTIO
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PP-I-15The qualitative picture of s
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Thus, knowing the composition of ra
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PP-I-17current density. Preliminary
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PP-I-18Hydrogenation kinetics was d
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PP-I-19the active mixing, amplitude
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PP-I-20where r, h indicate the radi
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PP-I-21model is very anisotropic be
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PP-I-22- Reduction of the number of
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PP-I-23oscillations of intermediate
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PP-I-25SYNTHESIS OF ETHYLENE OXIDE
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PP-I-26OPTIMUM KINETICS FOR POLYSTY
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PP-I-27TableSpecific surface area (
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PP-I-28γ-preirradiated sample), th
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PP-I-29commercial CFD solver FLUENT
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PP-I-30modulus, a considerable decr
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PP-I-31The destruction ways of CF 3
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PP-I-32[7]. Karoor S, Sirkar K. Gas
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PP-I-33above 750°. The catalytic p
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PP-I-35REVERSE FLOW REACTOR WITH FO
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FLOW-RECIRCULATION METHOD FOR INVES
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TO A PROBLEM OF OPTIMIZATION OF FUN
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PP-I-38THE INFLUENCE OF REACTION MI
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PP-I-39METHANOL OXIDATIVE STEAM REF
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PP-I-41CORRECT INVESTIGATION OF THE
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PP-I-42NEW APPROACH OF DEFINITION O
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PP-I-43STREAM HEAT EXCHANGE OF AERO
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PP-I-44HIGH TEMPERATURE OXYGEN TRAN
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PP-I-45KINETICS OF TRANSESTERIFICAT
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MATHEMATICAL MODELING AND OPTIMIZAT
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PP-I-47The basic side reaction is r
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PP-I-49EXPERIMENTAL STUDY OF THE HA
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PP-I-51ON THE KINETICS AND REGULARI
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PP-I-52DIFFERENTIAL THERMAL ANALYSI
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PP-I-53oxidation reaction demonstra
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PP-I-54of reaction. It is establish
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PP-I-55effects, are energetically c
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PP-I-56The experiments and simulati
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PP-I-57In the studied range of temp
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PP-I-58HeadingsAdvances in Chemical
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PP-I-59calculated. During the aroma
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PP-I-60with honeycomb catalyst) act
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Т - temperature, K, D eff - effect
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PP-I-62stirring rate were adopted u
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PP-I-63m 2 = (k 1 y 0 1 +k -1 +k 1
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POSTER PRESENTATIONSSECTION II
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PP-II-1values of operating paramete
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⎡⎛⎢⎜bF⎣⎝=2ab ⎞ 6+ ⎟
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PP-II-4HONEYCOMB MONOLITHIC CATALYS
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MATHEMATICAL MODELING OF THE ALUMIN
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PP-II-6MODELING OF VINYL ACETATE SY
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PP-II-7СENTRIFUGAL DISK REACTORAvv
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PP-II-83) An opportunity of operati
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PP-II-10UV-ACTIVATION OF METHANE CO
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PP-II-11COMBINED APPROACH (FMEA- HA
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PP-II-12Testing the pilot variant o
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PP-II-14NOVEL MICROREACTOR FOR THE
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PP-II-15of 1-2.5 lead to a decreasi
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PP-II-16stages. Kinetic parameters
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PP-II-17whiskers, which assure an a
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PP-II-18с m , с cat - density of
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PP-II-19decrease. So, the potential
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PP-II-20products became a mixture o
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PP-II-21A numerical algorithm and s
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PP-II-22motions at any external con
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PP-II-23One of the main technologic
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PP-II-24100 m x 250 μm x 0.5 μm,
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PP-II-25A model was developed to ca
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PP-II-26The results of calculations
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PP-II-27modes of reaction and two d
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PP-II-29OZONE-DESTRUCTION REACTOR B
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PP-II-30Fig. 1. Axial profile of me
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PP-II-31isobutylene in butene fract
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PP-II-322.5x10 -3 ( i )2.5x10 -3 (
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PP-II-33No olefinreadsorptionWith o
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PP-II-34using titania or Ag-doped t
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PP-II-35accidents, is condition dep
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PP-II-36be seen that at temperature
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PP-II-37the solid phase solute conc
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PP-II-38As shown in Table 1, the ca
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PP-II-39better to the obtained in t
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PP-II-40Hydrodynamic regime in the
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PP-II-41activity, relative unit1,21
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PP-II-42One of the major indicators
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PP-II-43These conditions are confor
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PP-II-44For the hepten, alpha-methy
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PP-II-46PARTIAL OXIDATION OF METHAN
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PP-II-47DEVELOPMENT OF VORTEX APPAR
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MODELING OF CFTALYTIC α-OLEFINS OL
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PP-II-49Hinselwood kinetic equation
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3) iterate concentrations at a cut
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PP-II-51data such flow sheet provid
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PP-II-53ON THE TECNOLOGY OF TECHNIC
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PP-II-54PROPYLENE POLYMERIZATION AN
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REACTOR FOR LIQUID-PHASE PROCESSES
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PP-II-56MODELING OF CATALYTIC MICRO
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PP-II-57MATHEMATICAL MODELING OF BE
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PP-II-58HONEYCOMB CATALYSTS WITH PO
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POSTER PRESENTATIONSSECTION IIISECT
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ReferencesPP-III-1[1]. A.N. Pestrya
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PP-III-2Table1. Percentages of diff
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PP-III-3conversion for the reaction
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PP-III-4900Reformer temperature (K)
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PP-III-5Catalytic performance of th
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PP-III-6optimization permit better
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PP-III-8DE-NO X SYSTEM BASED ON H 2
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PP-III-9SEPARATION BETWEEN CHLORIDE
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CONVERSION OF WASTE COTTON TO BIOET
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PP-III-12THE METHOD OF GLYCERIC ACI
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NOx conversion vs. temperature is p
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PP-III-14intermetallic diffusion at
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PP-III-15The conversion of O 2 was
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PP-III-16H 2consumpition (a.u)(a)39
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PP-III-17the characteristic structu
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PP-III-18Figure 1. Influence of tem
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PP-III-19(a)(b)CH 4conversion, %100
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PP-III-20take into account own size
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PP-III-2110080CS-18CS-34CHZ30CHZ801
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EXPERIMENTALPP-III-22We synthesized
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PP-III-23Base composition component
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PP-III-25CO REMOVAL AT THE MICROSCA
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HYDROGEN PRODUCTION FROM METHANOL U
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PP-III-27NON CATALITIC PRODUCTION O
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PP-III-28Different reaction conditi
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PP-III-29followed by WGS reaction.
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PP-III-30As a solvent-coreactants w
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PP-III-31It was concluded that on t
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PP-III-32Hydrogenolysis of glycerol
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PP-III-331,6W 0, μmol Н 2/min1,20
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PP-III-34preparation (glass fiber f
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PP-III-35In the modification proces
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PP-III-36The kinetics of acid hydro
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PP-III-37reaction: i) C=O double bo
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PP-III-38methane and carbon monoxid
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PP-III-39from 25 to 60, which was d
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PP-III-401% w/w for Pd with respect
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PP-III-41material. Besides, the mol
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PP-III-43METHANOL AND DIMETHYL ETHE
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PP-III-44goal is attained by using
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OLIGOMERISATION OF TERTIARY AMINE L
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PP-III-47meter (Shimazu Co.; TOC-50
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PP-III-48the range of 29-87 kJ/mol
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PP-III-49determine the optimal type
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PP-III-50NEW CONCEPT FOR A SELF CLE
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PP-III-51HYDROGEN PRODUCTION BY MET
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PP-III-52CATALYTIC UPGRADING OF PRO
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PP-III-53CATALYTIC CONVERSION OF FI
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PROCESS FOR THE PRODUCTION OF BUTYL
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PP-III-55been previously fixed and
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PP-III-56The influence of reaction
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PP-III-57sample does not contain so
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PP-III-58The re-activation of the e
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PP-III-59The aim of this work is th
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PP-III-61BIODIESEL FROM MICROALGAE
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DEVELOPING MICROFLUIDIC DEVICE WITH
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THREE-PHASE DIRECT OILS HYDROGENATI
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Co-BASED CATALYSTS FOR THE HYDROLYS
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PP-III-65KINETIC STUDY OF THE CATAL
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PP-III-66PRODUCTION OF HYDROGEN AND
Page 563 and 564:
PP-III-67ENHANCED GASIFICATION OF P
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PP-III-68INFLUENCE OF SPILLOVER ON
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PP-III-69AEROBIC OXIDATIVE COUPLING
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PP-III-70MECHANISMS FOR CHEMICAL RE
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PP-III-70SBS molecules and increase
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PP-III-71and as a resut, could enha
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PP-III-72conversion). Al 2 O 3 /PSS
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PP-III-73SBA50TiSBA% Transmittance5
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PP-III-74stove heating. Another par
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PP-III-75TG [%]0-10-20-30380°C400
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PP-III-76The elementary version of
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PP-III-77thermodynamically enhanced
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PP-III-78GFC textileStructuringmeta
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PP-III-79All the prepared spinel-ox
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PP-III-80Our new process is polluti
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PP-III-81Fig. 1. Scheme of the biog
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PP-III-82Pic. 1 Pic. 2Pic. 1. Schem
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ARKHIPOV Vladimir AfanasievichResea
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CENTENO Felipe OrlandoNúcleo de Ex
Page 601 and 602:
FLID Mark RafailovichScientific Res
Page 603 and 604:
HOSEN Mohammad AnwarUniversity of M
Page 605 and 606:
KOZLOVA EkaterinaBoreskov Institute
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MAKARSHIN Lev LvovichBoreskov Insti
Page 609 and 610:
ONSAN Zeynep IlsenDepartment of Che
Page 611 and 612:
REBOLLAR MoisesInstituto De Investi
Page 613 and 614:
SHEIKH Munir AhmedTraining and Staf
Page 615 and 616:
SULMAN Esfir MikhailovnaTver Techni
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ZHAPBASBYEV Uzak KairbekovichKazakh
Page 619 and 620:
OP-I-3 Pécar D., Gorsek A.COMPARIS
Page 621 and 622:
OP-II-3Kucherov A.V., Finashina E.D
Page 623 and 624:
OP-III-A-9 Rasrendra C.B., Girisuta
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PP-I-9Bykov V., Tsybenova S.B.DYNAM
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PP-I-43 Pechenegov Y.Y., Kuzmina R.
Page 629 and 630:
PP-II-10 Basov N.L., Oreshkin I., T
Page 631 and 632:
PP-II-45 Stepanek J., Koci P., Kubi
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PP-III-19 Fedorova Z.A., Danilova M
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PP-III-53 Pölczmann G., Valyon J.,
Page 637:
XIX International Conference on Che
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