OP-II-3

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PP-<strong>II</strong>-55Pic. 1. Scheme of chemical reactor with radial raw material injection.1 – reactor body; 2,3 – flanges; 4 – rabbets for densifier; 5,6 – inlet nozzles,7 – outlet nozzle; 8,9 – porous pipes; 10 – hanger bolt; 11 – screw nut.Reactor design described above provides for radial injection of raw material(water in our case) into reaction zone, which allows decrease thickness of fibrouscatalyst or sorbent layer and, thus, lower its hydraulic resistance.References[1]. Yegiazarov Yu.G. // Energeticheskaya strategiya. 2009. N 3. P. 52-67.434
PP-<strong>II</strong>-56MODELING OF CATALYTIC MICROREACTORSFOR NAPHTHA STEAM REFORMINGMustafa Karakaya, Ahmet K. AvciDepartment of Chemical Engineering, Bogazici University, Bebek 34342,Istanbul, Turkey, avciahme@boun.edu.trThis study involves comparison of two microreactor configurations, the multipleadiabatic bed (MAB) and the microchannel reactors, to produce hydrogen needed todrive a 2-kW PEM fuel cell. In the MAB system, composed of adiabatic catalyticpacked beds and microchannel heat exchangers interconnected to each other,hydrogen is produced via steam reforming (SR) of n-heptane, model compound fornaphtha, in a number of adiabatic reactors packed with a Ni-based catalyst. Heatrequirement of endothermic SR is supplied by exothermic combustion of methanerunning in a separate array of adiabatic reactors packed with a Pt-based catalyst.Heat transfer between the two reactions is achieved in microchannel heatexchangers that connect the effluent streams of the combustion and reforming beds.Upon heat exchange the streams are fed to the successive adiabatic beds and thereaction-heat exchange cycle is repeated until the desired amount of hydrogen isproduced [1,2].The second configuration, microchannel reactor, has parallel, identical channelswith dimensions in the sub-millimeter range and is characterized by laminar flowconditions. The microchannel reactor design in this study involves n-heptane SR inchannels whose walls are coated by a Ni-based catalyst. Heat needed to drive SR issupplied by methane combustion running in parallel channels coated with a Pt-basedcatalyst. Sets of parallel, straight channels, all of which have identical square crosssections,are etched on metallic plates and coated with either a Ni- or Pt-basedcatalyst. The plates are then bonded on top of each other so as to form an alternatingstack of endothermic and exothermic channels. Heat transfer between the channelsof the same plate is assumed to be negligible, allowing the multichannel system to becharacterized by a representative unit involving a single pair of exothermic andendothermic channels separated by a metallic wall. The system operates at steadystate and counter-current flow of reactive streams is considered.The representative microchannel unit is modeled by 2D continuity, momentum,energy conservation and species mass transport equations for the fluid and catalytic435
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Boreskov Institute of Catalysisof t
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INTERNATIONAL SCIENTIFIC COMMITTEEV
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SILVER SPONSORThe organizers expres
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PL-1HOW TO DESIGN OPTIMAL CATALYTIC
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MULTIFUNCTIONAL DEVICES FOR INTENSI
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PL-3DESIGN OF CATALYTIC PROCESSES F
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PL-3Indeed preparation and testing
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PL-4The second part of the lecture
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PL-5Reactor designs with intensifie
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PL-6MEMBRANE REACTORS: STATE OF THE
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KEY-NOTE PRESENTATIONS
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KN-1description, that can be charac
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KN-2selective catalytic reduction o
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KN-3Fig. 1. Experimental burner of
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KN-4~200°C. This is based on the H
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KN-5for addressing the quality of t
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KN-6reaction with ethanol and the b
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KN-7at temperature lower than 873K,
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REACTION KINETICS AND REACTION ENHA
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OP-I-2RELATION BETWEEN THE ACTIVATI
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COMPARISON OF CHEMICAL AND ENZYMATI
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OP-I-4NONLINEAR PHENOMENA DURING ME
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OP-I-5SPECIFICITY OF THE OSCILLATIO
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OP-I-6TRENDS IN BISTABILITY DOMAINS
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OP-I-7NON-STEADY-STATE CATALYST CHA
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OP-I-8TRANSIENT KINETIC STUDIES OF
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OP-I-9A REDOX KINETICS FOR THE PART
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OP-I-9500Flow of Air = 0.3 m 3 (STP
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OP-I-11ELUCIDATION OF THE REACTIVIT
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KINETIC MODELLING OF THE JOINT TRAN
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OP-I-13n-HEXANE SKELETAL ISOMERIZAT
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OP-I-14the slow branch of kinetic c
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OP-I-15The hydride palladium comple
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Energy Conservation (field j)∂∂
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OP-I-17Selectivity (mol. %)10099989
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OP-I-18According to GLC the main pr
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OP-I-19and slug dimensions, formati
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OP-I-20A RANS volume of fluids [1]
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OP-I-21the physical-chemical charac
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OP-I-22calculated values of pressur
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OP-I-23where L c - capillary length
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OP-I-24and diffuse transmission thr
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OP-I-25effect of bubble break-up wo
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OP-I-26strong influence on the soli
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OP-I-27wHCOOH=1+K2K1(1 + K3⋅ P⋅
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OP-I-28dimensional profiles detecte
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OP-I-29results. The results of the
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OP-I-30Fig. 1. Hydrodynamics and co
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OP-I-31Convection and diffusion wit
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TEMPERATURE RISE DURING REGENERATIO
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OP-II-2[4]. Similar temperature pro
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OP-II-3(Fig, 1 a, b) upon testing i
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OP-II-4In the second step optimizat
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OP-II-5membrane contactors were stu
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OP-II-6reaction over Cu/CeO 2-x cat
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OP-II-7is modelled by means of a tw
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OP-II-8the reactor [6]. However, th
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OP-II-9Figure 1. Computed volume fr
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OP-II-10assumes variables’ distri
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OP-II-11oxide support, it comes tha
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OP-II-12was connected to G.C. via s
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OP-II-13catalyst bed was 6 mm. Thre
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OP-II-14as coolant is an important
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OP-II-15Flow (L/h)7654321Bottoms ra
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OP-II-16(4) The gas recirculation r
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OP-II-17Catalytic reactions were ca
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OP-II-18At steady surface coverage
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OP-II-19gaimpulsegeneratorwateFig.
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OP-II-20examined (see Figure 1). Th
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OP-II-21References[1]. M.P. Dudukov
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OP-II-22of the hydrogen oxidation a
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OP-II-23TemperaturesensorsThe efflu
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OP-II-24of reactant conversions. Pa
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OP-II-25(surface) ‘wall-reaction
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OP-II-26It was found that the 10 wt
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OP-II-27non-flow type. During the M
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OP-III-A-1A NEW SIMPLE MICROCHANNEL
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BUBBLING FLUIDISED BED PYROLYSIS OF
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PINEWOOD PYROLYSIS UNDER VACUUM CON
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OP-III-A-5PYROLYSIS OF HDPE IN A CO
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OP-III-A-6REACTORS FOR THE GREEN TR
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DEHYDRATION OF GLYCEROL TO ACROLEIN
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OP-III-A-8LACTIC ACID BASED ON BIO
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RECOVERY OF ACETIC ACID FROM PYROLY
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OP-III-A-10LIPASE-CATALYZED REACTIO
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OP-III-A-11INVESTIGATION ON THERMOC
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OP-III-A-12SELECTIVE CATALYTIC DEOX
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ETHANOL STEAM REFORMING OVER COBALT
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OP-III-A-14HYDROTREATMENT CATALYSTS
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ORAL PRESENTATIONSSECTION IIIChemic
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OP-III-B-1Reactor parameters:Intern
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OP-III-B-2JOINT STEAM REFORMING OF
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OP-III-B-3LANDFILL BIOGAS PURIFICAT
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OP-III-B-4MODELING AND SIMULATION O
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OP-III-B-5DemonstratorThe medium-te
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OP-III-B-630/19.6 Nl/min (space vel
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OP-III-B-7mixed in the ratios: 94,8
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OP-III-B-8Table 1.Material balance
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OP-III-B-9Based on the results of t
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OP-III-B-10On this basis it can be
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OP-III-B-11Similar trends caused by
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OP-III-B-12(mol/s g cat)x108r4,6-DM
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OP-III-B-13carbon in Wyoming coal i
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OP-III-B-14MODELING PRODUCT DISTRIB
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OP-III-B-15COMBINED TECHNOLOGY OF U
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MATEMATICAL MODEL FOR DOWNDRAFT BIO
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OP-III-B-17CATALYTIC DEHYDRATION OF
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OP-III-B-18SYNGAS AND HYDROGEN PROD
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POSTER PRESENTATIONSSECTION I
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PP-I-1influence of the direction of
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PP-I-2At the agitation of the liqui
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PP-I-3NOLINEAR PHENOMENA IN CATALYT
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PP-I-4A NEW APPROACH TO KINETIC STU
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PP-I-5KINETICS OF PROX REACTION OVE
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PP-I-6PHENOMENA OF SUPERADIABATIC T
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ELECTROMAGNETIC REACTOR OF WATER TR
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PP-I-8DIRECT SYNTHESIS OF HYDROGEN
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PP-I-9DYNAMICS OF FIRST-ORDER PHASE
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PP-I-10ELECTROCHEMICAL OXIDATION OF
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PP-I-11CHEMPAK SOFTWARE PACKAGE: OP
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PP-I-12COMPUTER SIMULATION OF ENDOT
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PP-I-13MODELLING KINETICS OF PROCES
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PP-I-14THE INVESTIGATION OF REACTIO
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PP-I-15The qualitative picture of s
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Thus, knowing the composition of ra
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PP-I-17current density. Preliminary
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PP-I-18Hydrogenation kinetics was d
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PP-I-19the active mixing, amplitude
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PP-I-20where r, h indicate the radi
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PP-I-21model is very anisotropic be
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PP-I-22- Reduction of the number of
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PP-I-23oscillations of intermediate
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PP-I-25SYNTHESIS OF ETHYLENE OXIDE
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PP-I-26OPTIMUM KINETICS FOR POLYSTY
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PP-I-27TableSpecific surface area (
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PP-I-28γ-preirradiated sample), th
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PP-I-29commercial CFD solver FLUENT
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PP-I-30modulus, a considerable decr
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PP-I-31The destruction ways of CF 3
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PP-I-32[7]. Karoor S, Sirkar K. Gas
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PP-I-33above 750°. The catalytic p
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PP-I-35REVERSE FLOW REACTOR WITH FO
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FLOW-RECIRCULATION METHOD FOR INVES
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TO A PROBLEM OF OPTIMIZATION OF FUN
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PP-I-38THE INFLUENCE OF REACTION MI
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PP-I-39METHANOL OXIDATIVE STEAM REF
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PP-I-41CORRECT INVESTIGATION OF THE
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PP-I-42NEW APPROACH OF DEFINITION O
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PP-I-43STREAM HEAT EXCHANGE OF AERO
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PP-I-44HIGH TEMPERATURE OXYGEN TRAN
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PP-I-45KINETICS OF TRANSESTERIFICAT
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MATHEMATICAL MODELING AND OPTIMIZAT
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PP-I-47The basic side reaction is r
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PP-I-49EXPERIMENTAL STUDY OF THE HA
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PP-I-51ON THE KINETICS AND REGULARI
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PP-I-52DIFFERENTIAL THERMAL ANALYSI
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PP-I-53oxidation reaction demonstra
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PP-I-54of reaction. It is establish
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PP-I-55effects, are energetically c
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PP-I-56The experiments and simulati
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PP-I-57In the studied range of temp
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PP-I-58HeadingsAdvances in Chemical
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PP-I-59calculated. During the aroma
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PP-I-60with honeycomb catalyst) act
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Т - temperature, K, D eff - effect
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PP-I-62stirring rate were adopted u
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PP-I-63m 2 = (k 1 y 0 1 +k -1 +k 1
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POSTER PRESENTATIONSSECTION II
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PP-II-1values of operating paramete
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⎡⎛⎢⎜bF⎣⎝=2ab ⎞ 6+ ⎟
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PP-II-4HONEYCOMB MONOLITHIC CATALYS
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MATHEMATICAL MODELING OF THE ALUMIN
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PP-II-6MODELING OF VINYL ACETATE SY
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PP-II-7СENTRIFUGAL DISK REACTORAvv
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PP-II-83) An opportunity of operati
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PP-II-10UV-ACTIVATION OF METHANE CO
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PP-II-11COMBINED APPROACH (FMEA- HA
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PP-II-12Testing the pilot variant o
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PP-II-14NOVEL MICROREACTOR FOR THE
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PP-II-15of 1-2.5 lead to a decreasi
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PP-II-16stages. Kinetic parameters
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PP-II-17whiskers, which assure an a
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PP-II-18с m , с cat - density of
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PP-II-19decrease. So, the potential
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PP-II-20products became a mixture o
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PP-II-21A numerical algorithm and s
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PP-II-22motions at any external con
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PP-II-23One of the main technologic
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PP-II-24100 m x 250 μm x 0.5 μm,
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PP-II-25A model was developed to ca
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PP-II-26The results of calculations
Page 383 and 384: PP-II-27modes of reaction and two d
Page 385 and 386: PP-II-29OZONE-DESTRUCTION REACTOR B
Page 387 and 388: PP-II-30Fig. 1. Axial profile of me
Page 389 and 390: PP-II-31isobutylene in butene fract
Page 391 and 392: PP-II-322.5x10 -3 ( i )2.5x10 -3 (
Page 393 and 394: PP-II-33No olefinreadsorptionWith o
Page 395 and 396: PP-II-34using titania or Ag-doped t
Page 397 and 398: PP-II-35accidents, is condition dep
Page 399 and 400: PP-II-36be seen that at temperature
Page 401 and 402: PP-II-37the solid phase solute conc
Page 403 and 404: PP-II-38As shown in Table 1, the ca
Page 405 and 406: PP-II-39better to the obtained in t
Page 407 and 408: PP-II-40Hydrodynamic regime in the
Page 409 and 410: PP-II-41activity, relative unit1,21
Page 411 and 412: PP-II-42One of the major indicators
Page 413 and 414: PP-II-43These conditions are confor
Page 415 and 416: PP-II-44For the hepten, alpha-methy
Page 417 and 418: PP-II-46PARTIAL OXIDATION OF METHAN
Page 419 and 420: PP-II-47DEVELOPMENT OF VORTEX APPAR
Page 421 and 422: MODELING OF CFTALYTIC α-OLEFINS OL
Page 423 and 424: PP-II-49Hinselwood kinetic equation
Page 425 and 426: 3) iterate concentrations at a cut
Page 427 and 428: PP-II-51data such flow sheet provid
Page 429 and 430: PP-II-53ON THE TECNOLOGY OF TECHNIC
Page 431 and 432: PP-II-54PROPYLENE POLYMERIZATION AN
Page 433: REACTOR FOR LIQUID-PHASE PROCESSES
Page 437 and 438: PP-II-57MATHEMATICAL MODELING OF BE
Page 439 and 440: PP-II-58HONEYCOMB CATALYSTS WITH PO
Page 441 and 442: POSTER PRESENTATIONSSECTION IIISECT
Page 443 and 444: ReferencesPP-III-1[1]. A.N. Pestrya
Page 445 and 446: PP-III-2Table1. Percentages of diff
Page 447 and 448: PP-III-3conversion for the reaction
Page 449 and 450: PP-III-4900Reformer temperature (K)
Page 451 and 452: PP-III-5Catalytic performance of th
Page 453 and 454: PP-III-6optimization permit better
Page 455 and 456: PP-III-8DE-NO X SYSTEM BASED ON H 2
Page 457 and 458: PP-III-9SEPARATION BETWEEN CHLORIDE
Page 459 and 460: CONVERSION OF WASTE COTTON TO BIOET
Page 461 and 462: PP-III-12THE METHOD OF GLYCERIC ACI
Page 463 and 464: NOx conversion vs. temperature is p
Page 465 and 466: PP-III-14intermetallic diffusion at
Page 467 and 468: PP-III-15The conversion of O 2 was
Page 469 and 470: PP-III-16H 2consumpition (a.u)(a)39
Page 471 and 472: PP-III-17the characteristic structu
Page 473 and 474: PP-III-18Figure 1. Influence of tem
Page 475 and 476: PP-III-19(a)(b)CH 4conversion, %100
Page 477 and 478: PP-III-20take into account own size
Page 479 and 480: PP-III-2110080CS-18CS-34CHZ30CHZ801
Page 481 and 482: EXPERIMENTALPP-III-22We synthesized
Page 483 and 484: PP-III-23Base composition component
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PP-III-25CO REMOVAL AT THE MICROSCA
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HYDROGEN PRODUCTION FROM METHANOL U
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PP-III-27NON CATALITIC PRODUCTION O
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PP-III-28Different reaction conditi
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PP-III-29followed by WGS reaction.
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PP-III-30As a solvent-coreactants w
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PP-III-31It was concluded that on t
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PP-III-32Hydrogenolysis of glycerol
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PP-III-331,6W 0, μmol Н 2/min1,20
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PP-III-34preparation (glass fiber f
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PP-III-35In the modification proces
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PP-III-36The kinetics of acid hydro
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PP-III-37reaction: i) C=O double bo
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PP-III-38methane and carbon monoxid
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PP-III-39from 25 to 60, which was d
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PP-III-401% w/w for Pd with respect
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PP-III-41material. Besides, the mol
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PP-III-43METHANOL AND DIMETHYL ETHE
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PP-III-44goal is attained by using
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OLIGOMERISATION OF TERTIARY AMINE L
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PP-III-47meter (Shimazu Co.; TOC-50
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PP-III-48the range of 29-87 kJ/mol
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PP-III-49determine the optimal type
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PP-III-50NEW CONCEPT FOR A SELF CLE
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PP-III-51HYDROGEN PRODUCTION BY MET
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PP-III-52CATALYTIC UPGRADING OF PRO
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PP-III-53CATALYTIC CONVERSION OF FI
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PROCESS FOR THE PRODUCTION OF BUTYL
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PP-III-55been previously fixed and
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PP-III-56The influence of reaction
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PP-III-57sample does not contain so
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PP-III-58The re-activation of the e
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PP-III-59The aim of this work is th
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PP-III-61BIODIESEL FROM MICROALGAE
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DEVELOPING MICROFLUIDIC DEVICE WITH
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THREE-PHASE DIRECT OILS HYDROGENATI
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Co-BASED CATALYSTS FOR THE HYDROLYS
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PP-III-65KINETIC STUDY OF THE CATAL
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PP-III-66PRODUCTION OF HYDROGEN AND
Page 563 and 564:
PP-III-67ENHANCED GASIFICATION OF P
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PP-III-68INFLUENCE OF SPILLOVER ON
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PP-III-69AEROBIC OXIDATIVE COUPLING
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PP-III-70MECHANISMS FOR CHEMICAL RE
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PP-III-70SBS molecules and increase
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PP-III-71and as a resut, could enha
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PP-III-72conversion). Al 2 O 3 /PSS
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PP-III-73SBA50TiSBA% Transmittance5
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PP-III-74stove heating. Another par
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PP-III-75TG [%]0-10-20-30380°C400
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PP-III-76The elementary version of
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PP-III-77thermodynamically enhanced
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PP-III-78GFC textileStructuringmeta
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PP-III-79All the prepared spinel-ox
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PP-III-80Our new process is polluti
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PP-III-81Fig. 1. Scheme of the biog
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PP-III-82Pic. 1 Pic. 2Pic. 1. Schem
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ARKHIPOV Vladimir AfanasievichResea
Page 599 and 600:
CENTENO Felipe OrlandoNúcleo de Ex
Page 601 and 602:
FLID Mark RafailovichScientific Res
Page 603 and 604:
HOSEN Mohammad AnwarUniversity of M
Page 605 and 606:
KOZLOVA EkaterinaBoreskov Institute
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MAKARSHIN Lev LvovichBoreskov Insti
Page 609 and 610:
ONSAN Zeynep IlsenDepartment of Che
Page 611 and 612:
REBOLLAR MoisesInstituto De Investi
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SHEIKH Munir AhmedTraining and Staf
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SULMAN Esfir MikhailovnaTver Techni
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ZHAPBASBYEV Uzak KairbekovichKazakh
Page 619 and 620:
OP-I-3 Pécar D., Gorsek A.COMPARIS
Page 621 and 622:
OP-II-3Kucherov A.V., Finashina E.D
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OP-III-A-9 Rasrendra C.B., Girisuta
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PP-I-9Bykov V., Tsybenova S.B.DYNAM
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PP-I-43 Pechenegov Y.Y., Kuzmina R.
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PP-II-10 Basov N.L., Oreshkin I., T
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PP-II-45 Stepanek J., Koci P., Kubi
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PP-III-19 Fedorova Z.A., Danilova M
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PP-III-53 Pölczmann G., Valyon J.,
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XIX International Conference on Che
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