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8th Liquid Matter Conference September 6-10, 2011 Wien, Austria ...

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P2.40Tue 611:23-14:00Virial equation of state of the hard tetrahedron fluidJiri Kolafa 1 and Stanislav Labik 11 Institute of Chemical Technology, Prague, Department of Physical Chemistry,Technicka 5 166 28, Praha 6, Czech RepublicA fluid of regular hard tetrahedra provides an ”extreme” test of fluid theories. It was shown thatthe structure of this fluid is similar to the structure of water. In this paper we calculate the virialcoefficients of regular hard tetrahedra up to B 9 by Monte Carlo integration in the Ree-Hooverrepresentation. The resulting virial equation of state is compared with the results of isobaric MonteCarlo simulations.40

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