3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures
3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures
3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
Chem. Listy, 102, s265–s1311 (2008) Food Chemistry & Biotechnology<br />
Table III<br />
Concentration of DBP, DEHP and ΣDBP+DEHP in oils<br />
Sample<br />
DBP DEHP ΣDBP + DEHP<br />
[mg kg –1 ] [mg kg –1 ] [mg kg –1 ]<br />
Oil A 1.11 5.71 6.82<br />
Oil C 2.13 37.38 39.51<br />
Conclusions<br />
Samples of feedstuffs for livestock (complementary<br />
feeds, premixes, feed additives and raw materials) were collected<br />
in years 2005 and 2006, oils in 2007. Various levels<br />
of contamination were determinated in feedstuffs. Feed additives,<br />
premixes and complementary feeds as well are poor<br />
in phthalates. Raw materials have higher amounts of PAEs,<br />
but the highest concentrations were measured in materials<br />
with high fat content. Because of phthalate´s lipophilic<br />
nature, they are released mainly into feedstuffs containing<br />
fat 15 . Phthalic acid esters determinated in this investigation<br />
are similar to RASZYK et al. (1998) 16 , where was DBP level<br />
in feed additives 0.207 mg kg –1 and DEHP 0.216 mg kg –1 .<br />
Oils before technological production processing (in plastic<br />
barrels) contained lower levels of PAEs than after processing,<br />
so this study confirmed, that PAEs can easily migrate from<br />
platics to fat.<br />
This study was carried out within the scope of project<br />
NAZV 234/2202/MZ260041, supported by the Department of<br />
Agriculture, Res. & Dev., Czech Republic.<br />
REFEREnCES<br />
1. Agency for Toxic Substances and Disease Registry.<br />
2001. Toxicological Profile for Di-n-butyl Phthalate.<br />
Atlanta, GA: Agency for Toxic Substances and Disease<br />
Registry.<br />
s699<br />
2. Agency for Toxic Substances and Disease Registry.<br />
2002. Toxicological Profile for Di(2-ethylhexyl) Phthalate<br />
(DEHP). Atlanta, GA: Agency for Toxic Substances<br />
and Disease Registry.<br />
<strong>3.</strong> Schettler T.: Int. J. Androl. 29, 134 (2006).<br />
4. Polo M., Llompart M., Garcia-Jares C., Cela R.: J. Chromatogr.<br />
A 63, 1072 (2005).<br />
5. Staples C. A., Peterson D. R., Parkerton T. F., Adams W.<br />
J.: Chemosphere 35, 667 (1997).<br />
6. Afshari A., Gunnarsen L., Clausen P. A., Hansen V.:<br />
Indoor Air. 14,120 (2004).<br />
7. Fujii M., Sinohara n., Lim A., Otake T., Kumagai K.,<br />
Yanagisawa Y.: Atmos. Environ. 37, 5495 (2003).<br />
8. Elsisi A. E., Carter D. E., Sipes I. G.: Fundam. Appl.<br />
Toxicol.. 12, 70 (1989).<br />
9. McKee R. H., El-Hawari M., Stoltz M., Pallas F., Lington<br />
A. W.: J. Appl. Toxicol. 22, 293 (2002).<br />
10. Wormuth M., Scheringer M., Vollenweider M., Hungerbuhler<br />
K.: Risk. Anal. 26, 803 (2006).<br />
11. Schettler T.: Int. J. Androl. 29:134, 181 (2006).<br />
12. http://www.reason.org/peg2.html<br />
1<strong>3.</strong> Lopez-Jimenez F. J., Rubio S., Perez-Bendito D.: Anal.<br />
chim. acta 142, 551 (2005).<br />
14. Jarošová A. Habilitační práce. MZLU. Brno, 2004,<br />
p.137<br />
15. Tsumura Y., Ishimitsu S., namakura Z., Yoshii K., Kaihara<br />
A., Tonogai Y.: J. Food Hyg. Soc. Jap. 42, 128<br />
(2001).<br />
16. Raszyk J., Gajdůšková V., Jarošová A., Salava J., Palac<br />
J.: Veterinární Medicína – Czech 43, 93 (1998).