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3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures

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Chem. Listy, 102, s265–s1311 (2008) Food Chemistry & Biotechnology<br />

Table III<br />

Concentration of DBP, DEHP and ΣDBP+DEHP in oils<br />

Sample<br />

DBP DEHP ΣDBP + DEHP<br />

[mg kg –1 ] [mg kg –1 ] [mg kg –1 ]<br />

Oil A 1.11 5.71 6.82<br />

Oil C 2.13 37.38 39.51<br />

Conclusions<br />

Samples of feedstuffs for livestock (complementary<br />

feeds, premixes, feed additives and raw materials) were collected<br />

in years 2005 and 2006, oils in 2007. Various levels<br />

of contamination were determinated in feedstuffs. Feed additives,<br />

premixes and complementary feeds as well are poor<br />

in phthalates. Raw materials have higher amounts of PAEs,<br />

but the highest concentrations were measured in materials<br />

with high fat content. Because of phthalate´s lipophilic<br />

nature, they are released mainly into feedstuffs containing<br />

fat 15 . Phthalic acid esters determinated in this investigation<br />

are similar to RASZYK et al. (1998) 16 , where was DBP level<br />

in feed additives 0.207 mg kg –1 and DEHP 0.216 mg kg –1 .<br />

Oils before technological production processing (in plastic<br />

barrels) contained lower levels of PAEs than after processing,<br />

so this study confirmed, that PAEs can easily migrate from<br />

platics to fat.<br />

This study was carried out within the scope of project<br />

NAZV 234/2202/MZ260041, supported by the Department of<br />

Agriculture, Res. & Dev., Czech Republic.<br />

REFEREnCES<br />

1. Agency for Toxic Substances and Disease Registry.<br />

2001. Toxicological Profile for Di-n-butyl Phthalate.<br />

Atlanta, GA: Agency for Toxic Substances and Disease<br />

Registry.<br />

s699<br />

2. Agency for Toxic Substances and Disease Registry.<br />

2002. Toxicological Profile for Di(2-ethylhexyl) Phthalate<br />

(DEHP). Atlanta, GA: Agency for Toxic Substances<br />

and Disease Registry.<br />

<strong>3.</strong> Schettler T.: Int. J. Androl. 29, 134 (2006).<br />

4. Polo M., Llompart M., Garcia-Jares C., Cela R.: J. Chromatogr.<br />

A 63, 1072 (2005).<br />

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Indoor Air. 14,120 (2004).<br />

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Yanagisawa Y.: Atmos. Environ. 37, 5495 (2003).<br />

8. Elsisi A. E., Carter D. E., Sipes I. G.: Fundam. Appl.<br />

Toxicol.. 12, 70 (1989).<br />

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A. W.: J. Appl. Toxicol. 22, 293 (2002).<br />

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K.: Risk. Anal. 26, 803 (2006).<br />

11. Schettler T.: Int. J. Androl. 29:134, 181 (2006).<br />

12. http://www.reason.org/peg2.html<br />

1<strong>3.</strong> Lopez-Jimenez F. J., Rubio S., Perez-Bendito D.: Anal.<br />

chim. acta 142, 551 (2005).<br />

14. Jarošová A. Habilitační práce. MZLU. Brno, 2004,<br />

p.137<br />

15. Tsumura Y., Ishimitsu S., namakura Z., Yoshii K., Kaihara<br />

A., Tonogai Y.: J. Food Hyg. Soc. Jap. 42, 128<br />

(2001).<br />

16. Raszyk J., Gajdůšková V., Jarošová A., Salava J., Palac<br />

J.: Veterinární Medicína – Czech 43, 93 (1998).

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