22.12.2012 Views

3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures

3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures

3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

Chem. Listy, 102, s265–s1311 (2008) Food Chemistry & Biotechnology<br />

fatty acids ratios varied from <strong>3.</strong>96 to 10.62 for the total lipid<br />

extracts. For the studied ESF’s, these ratios varied from 2.64<br />

to <strong>3.</strong>44.<br />

The polyunsaturated fatty acids were the most abundant<br />

out of the unsaturated fatty acids of TLE’s, in all studied oils,<br />

except for peanut oil. The polyunsaturated/monounsaturated<br />

fatty acids ratios ranged from 0.92 to 4.49 for the analyzed<br />

TLE’s and from 1.83 to <strong>3.</strong>06 for ESF’s, respectively.<br />

S t e r o l C o m p o s i t i o n<br />

The predominant phytosterols in all four samples were<br />

sitosterol, campesterol and ∆5-avenasterol (see Table I).The<br />

proportion of free and esterified sterols varied widely among<br />

samples (see Fig. 2.). In all oils except sesame oil, most of the<br />

β-sitosterol was esterified.<br />

Conclusions<br />

The determination of fatty acids and sterols’ composition<br />

is essential for the analytical assessment of the quality,<br />

s621<br />

origin, extraction method, refining procedure and possible<br />

adulteration of the vegetable oils.<br />

REFEREnCES<br />

1. Christie W. W.: Gas Chromatography and Lipids. The<br />

Oily Press Ltd., Glasgow 1989.<br />

2. Abidi S. L.: J. Chromatogr. A 935, 173 (2001).<br />

<strong>3.</strong> Phillips K. M., Ruggio D. M., Toivo J.I., Swank M.A.,<br />

Simpkins A. H.: J. Food Comp. Anal. 15, 123 (2002).<br />

4. Phillips K. M., Ruggio D. M., Ashraf-Khorassani M.: J.<br />

Agric. Food Chem. 53, 9436 (2005).<br />

5. Yang B., Karlsson R. M., Oksman P. H., Kallio H.P.: J.<br />

Agric. Food Chem. 49, 5620 (2001).<br />

6. Dubois V., Breton S., Linder M., Fanni J., Parmentier<br />

M.: Eur. J. Lipid Sci. Tehnol. 109, 710 (2007).<br />

7. Beardsell D., Francis J., Ridley D.: J. Food Lipids 9, 1<br />

(2002).

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!