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VGB POWERTECH 10 (2020) - International Journal for Generation and Storage of Electricity and Heat

VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020). Technical Journal of the VGB PowerTech Association. Energy is us! Power plant products/by-products.

VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020).
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<strong>VGB</strong> PowerTech <strong>10</strong> l <strong>2020</strong><br />

Developments in CCP management in Europe<br />

after 1987 had to comply with the emission<br />

limits in the LCPD <strong>and</strong> were either closed<br />

or retr<strong>of</strong>itted with more effective flue gas<br />

cleaning devices <strong>for</strong> de-dusting, de-nitrification<br />

(de-NOx) <strong>and</strong> de-sulphurisation<br />

(de-SOx). The technologies influence type,<br />

amount <strong>and</strong> quality <strong>of</strong> the resulting coal<br />

combustion products (ashes <strong>and</strong> de-sulphurisation<br />

products). De-NOx technologies<br />

cover catalytic (SCR in high dust or<br />

tail-end installation) or non-catalytic reduction<br />

(SNCR). For the proper operation<br />

if the plant <strong>and</strong> to minimise the impact on<br />

the CCPs proper maintenance <strong>of</strong> the system<br />

is needed [12]. De-SOx technologies<br />

cover dry <strong>and</strong> wet desulphurisation technologies<br />

resulting in either spray-dry absorption<br />

(SDA) product or flue gas desulphurisation<br />

(FGD) gypsum. The wet process<br />

is mostly used <strong>and</strong> in some cases<br />

<strong>for</strong>merly installed SDA processes are meanwhile<br />

replaced with wet FGD systems.<br />

The IED aims to achieve a high level <strong>of</strong> protection<br />

<strong>of</strong> human health <strong>and</strong> the environment<br />

taken as a whole by reducing harmful<br />

industrial emissions across the EU, in particular<br />

through better application <strong>of</strong> Best<br />

Available Techniques (BAT) [13]. Around<br />

50,000 installations undertaking the industrial<br />

activities listed in Annex I <strong>of</strong> the<br />

IED are required to operate in accordance<br />

with a permit (granted by the authorities<br />

in the Member States). This permit should<br />

contain conditions set in accordance with<br />

the principles <strong>and</strong> provisions <strong>of</strong> the IED.<br />

The IED is based on several pillars, in particular<br />

an integrated approach, the use <strong>of</strong><br />

best available techniques, flexibility, inspections<br />

<strong>and</strong> public participation.<br />

The integrated approach means that the<br />

permits must take into account the whole<br />

environmental per<strong>for</strong>mance <strong>of</strong> the plant,<br />

covering e.g. emissions to air, water <strong>and</strong><br />

l<strong>and</strong>, generation <strong>of</strong> waste, use <strong>of</strong> raw materials,<br />

energy efficiency, noise, prevention<br />

<strong>of</strong> accidents, <strong>and</strong> restoration <strong>of</strong> the site<br />

upon closure. To fulfill the approach also<br />

other Directives as the Waste Directive [14]<br />

<strong>for</strong> utilisation <strong>of</strong> waste <strong>and</strong> REACH Regulation<br />

[15] <strong>and</strong> several product st<strong>and</strong>ards<br />

<strong>and</strong> requirements <strong>for</strong> the use as products<br />

have to considered. It is a continuous task<br />

<strong>of</strong> ECOBA <strong>and</strong> its members to highlight<br />

that CCPs are valuable resources which can<br />

be <strong>and</strong> which are used as replacement <strong>for</strong><br />

natural materials in several applications<br />

<strong>and</strong> to in<strong>for</strong>m about related regulations.<br />

The permit conditions including emission<br />

limit values must be based on the Best<br />

Available Techniques (BAT). In order to<br />

define BAT <strong>and</strong> the BAT-associated environmental<br />

per<strong>for</strong>mance at EU level, the<br />

Commission organises an exchange <strong>of</strong> in<strong>for</strong>mation<br />

with experts from Member<br />

States, industry <strong>and</strong> environmental organisations.<br />

This work is co-ordinated by the<br />

European IPPC Bureau <strong>of</strong> the Institute <strong>for</strong><br />

Prospective Technology Studies at the EU<br />

Joint Research Centre in Seville (Spain).<br />

This process results in BAT Reference Documents<br />

(BREFs); the BAT conclusions contained<br />

are adopted by the Commission as<br />

Implementing Decisions. The IED requires<br />

that these BAT conclusions are the reference<br />

<strong>for</strong> setting permit conditions.<br />

In 2011, the revision <strong>of</strong> the Best Available<br />

Techniques Reference Document <strong>for</strong> Large<br />

Combustion Plants (BREF LCP) BREF LCP<br />

was started <strong>and</strong> major commenting work<br />

via <strong>VGB</strong> <strong>and</strong> EURELECTRIC was organised<br />

in addition to meetings with the<br />

European Integrated Pollution Prevention<br />

<strong>and</strong> Control (IPPC) Bureau (EIPPCB) in Sevilla.<br />

In June 2016, the EIPPC has published the<br />

final draft <strong>of</strong> the BREF LCP <strong>and</strong> the conclusions<br />

(chapter <strong>10</strong> <strong>of</strong> BREF LCP) [16]. The<br />

conclusions will provide stricter emission<br />

limit values <strong>for</strong> all existing parameters. In<br />

addition, requirements <strong>for</strong> Hg, HCl abd HF<br />

will be implemented. Early 2017, the Comitology<br />

procedure <strong>for</strong> the BREF LCP will be<br />

started. After acceptance <strong>of</strong> the BREF LCP<br />

it will be translated <strong>and</strong> published in the<br />

Official <strong>Journal</strong> <strong>of</strong> the EU. With that the revision<br />

may be concluded by midth <strong>of</strong> 2017.<br />

After publication in the Official <strong>Journal</strong><br />

members states have to implement the conclusions<br />

within four years, e.g. by midth<br />

2021.<br />

In Germany, producers <strong>for</strong>med the ‘Hgcapture<br />

Initiative’ to publicly in<strong>for</strong>m about the<br />

success when using BAT as defined in the<br />

BREF. This is <strong>of</strong> special importance as the<br />

CCPs from hard coal are used nearly completely<br />

in the construction industry <strong>and</strong> as<br />

changes in compositions may complicate<br />

continued use. The research work currently<br />

at lab <strong>and</strong> pilot scale demonstrate that<br />

the expected very low Hg emission values<br />

may not be reached with only one BAT. In<br />

addition, the systems has different effects<br />

in different power plants which has not<br />

been considered in the revision phase although<br />

commented several times [17].<br />

Impact by markets<br />

As coal-fired power plants do not only produce<br />

electricity <strong>and</strong> heat but also construction<br />

materials the market developments<br />

<strong>and</strong> dem<strong>and</strong>s <strong>for</strong> all markets have to be<br />

considered.<br />

To achieve the aims in CO 2 reduction the<br />

side conditions <strong>for</strong> the operation <strong>of</strong> coalfired<br />

plants were modified. In addition to<br />

the legal framework described above also<br />

national incentives <strong>for</strong> renewable production<br />

were established aiming in “renewables<br />

first” <strong>and</strong> based on this changing the<br />

merit order (ranking <strong>of</strong> available sources <strong>of</strong><br />

energy production). In addition several national<br />

energy markets are based on stock<br />

prices.<br />

The merit order or ranking achieve that<br />

those with the lowest marginal costs are<br />

the first ones to be brought online to meet<br />

dem<strong>and</strong>, <strong>and</strong> the plants with the highest<br />

marginal costs are the last to be brought on<br />

line. Dispatching generation in this way<br />

minimizes the cost <strong>of</strong> production <strong>of</strong> electricity.<br />

Sometimes generating units must<br />

be started out <strong>of</strong> merit order, due to transmission<br />

congestion, system reliability or<br />

other reasons driving costs.<br />

Furthermore, the spot markets <strong>for</strong> electricity<br />

in Germany, Austria, Switzerl<strong>and</strong>, Belgium,<br />

Netherl<strong>and</strong>s <strong>and</strong> the United Kingdom<br />

are managed by EPEX Spot. The trade<br />

<strong>for</strong> the spot market is all year through <strong>for</strong><br />

24 h <strong>of</strong> the next day, consist <strong>of</strong> intraday<br />

(business the same day) <strong>and</strong> day-ahead<br />

business (<strong>for</strong> the next day) <strong>and</strong> are especially<br />

designed <strong>for</strong> integration <strong>of</strong> renewable<br />

power. Phelix – the reference price <strong>for</strong><br />

the European trade market – is published<br />

on a daily base <strong>for</strong> energy in base <strong>and</strong> peak<br />

load [18]. In future, also power-to-purchase-agreements<br />

may be used. As long<br />

term direct marketing instruments they<br />

will influence also the existing market systems.<br />

Impact on coal combustion<br />

products<br />

For the utilisation <strong>of</strong> CCPs quality <strong>and</strong><br />

availability are important parameters <strong>for</strong><br />

the construction market. The quality is defined<br />

by technical <strong>and</strong> environmental requirements<br />

in st<strong>and</strong>ards <strong>and</strong> regulations<br />

which have to be met all the time. A continuous<br />

quality management including<br />

auto <strong>and</strong> third party control is required.<br />

The st<strong>and</strong>ards <strong>and</strong> requirements are subject<br />

<strong>of</strong> regular updates to meet regulatory<br />

as well as market needs.<br />

In addition to quality, availability is important<br />

to serve construction projects especially<br />

in member states with existing markets.<br />

Forecasting <strong>of</strong> production to serve<br />

market needs cause more ef<strong>for</strong>ts in CCP<br />

management. Stock management whether<br />

in silo or on site as well as beneficiation <strong>for</strong><br />

fresh produced or stockpiled ash is being<br />

discussed together with cross border transport<br />

as options <strong>for</strong> safeguarding availability<br />

<strong>of</strong> CCPs.<br />

The figures <strong>for</strong> production <strong>and</strong> use in<br />

EU15/EU28/EU are given in Ta b l e 2 .<br />

Tab. 2. Production <strong>and</strong> utilisation <strong>of</strong> CCPs in<br />

Europe (EU-15, EU-28, EU) [1].<br />

Produktion<br />

EU15 EU28* EU*<br />

[mill.t]<br />

CCPs total 40.4 ><strong>10</strong>2 >140<br />

Ashes 30,.1 >84 >120<br />

Desulph. products <strong>10</strong>.3 >20 >21<br />

Utilisation rate<br />

Construction ind. 50 % ** **<br />

Constr. + reclam. 92 % ** **<br />

* Estimate based on coal consumption<br />

** In<strong>for</strong>mation on utilisation only partly available<br />

37

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