VGB POWERTECH 10 (2020) - International Journal for Generation and Storage of Electricity and Heat
VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020). Technical Journal of the VGB PowerTech Association. Energy is us! Power plant products/by-products.
VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020).
Technical Journal of the VGB PowerTech Association. Energy is us!
Power plant products/by-products.
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<strong>VGB</strong> PowerTech <strong>10</strong> l <strong>2020</strong><br />
Implementation <strong>of</strong> Basic Requirement in harmonized product st<strong>and</strong>ards<br />
Leachate<br />
demin. water<br />
S 0 , J<br />
Monolithic construction<br />
products<br />
Test specimen<br />
e. g. sheet/plate<br />
200 x 200 mm 2<br />
Vessel<br />
(e. g. glass)<br />
Fig. 2. Test method <strong>for</strong> monolithic products<br />
(dynamic surface leaching test)<br />
according to [8, <strong>10</strong>].<br />
ganic substances from monolithic (e.g. ceramic<br />
tiles, concrete, cement stabilized<br />
coal fly ash <strong>for</strong> road base) or, respectively,<br />
granular construction products (principles<br />
see F i g u r e 2 <strong>and</strong> F i g u r e 3 ). The st<strong>and</strong>ards<br />
are available as Technical Specification<br />
(TS) [<strong>10</strong>, 11]. The specification <strong>for</strong><br />
monolithic construction products was already<br />
published in 2014, the one <strong>for</strong> granular<br />
construction products in 2016 due to a<br />
longer negotiation phase. In detail, the following<br />
CEN/TSs are published:<br />
––<br />
CEN/TS 16637-1: Construction products<br />
– Assessment <strong>of</strong> release <strong>of</strong> dangerous<br />
substances – Part 1: Guidance <strong>for</strong> the determination<br />
<strong>of</strong> leaching tests <strong>and</strong> additional<br />
testing steps (2014), [9];<br />
––<br />
CEN/TS 16637-2: Construction products<br />
– Assessment <strong>of</strong> release <strong>of</strong> dangerous<br />
substances – Part 2: Horizontal dynamic<br />
surface leaching test (2014), [<strong>10</strong>];<br />
––<br />
CEN/TS 16637-3: Construction products<br />
– Assessment <strong>of</strong> release <strong>of</strong> dangerous<br />
substances – Part 3: Horizontal up-flow<br />
percolation test (2016), [11].<br />
Be<strong>for</strong>e the test methods can achieve the status<br />
<strong>of</strong> European St<strong>and</strong>ards (EN), robustness<br />
testing <strong>and</strong> as a second validation<br />
step round robin tests are necessary. The<br />
robustness programmes, where the sensitivity<br />
<strong>of</strong> changes in test parameters (e.g.<br />
temperature, air exchange rate (indoor),<br />
flow rate (soil <strong>and</strong> water), fineness <strong>of</strong><br />
the granular products (soil <strong>and</strong> water),<br />
etc.) on the result <strong>of</strong> a release test were successfully<br />
finalized. The validation procedure<br />
based on round robin tests was combined<br />
<strong>for</strong> both procedures <strong>and</strong> <strong>for</strong> the<br />
st<strong>and</strong>ards on content <strong>and</strong> eluate analysis<br />
developed in parallel <strong>and</strong> has been finished<br />
in the beginning <strong>of</strong> <strong>2020</strong>. Consequently, the<br />
test protocols are now ready <strong>for</strong> conversion<br />
into ENs to be available within the next two<br />
years.<br />
Another method h<strong>and</strong>les the testing <strong>of</strong> the<br />
release <strong>of</strong> volatile organic compounds into<br />
Granular construction<br />
products<br />
Fig. 3. Test method <strong>for</strong> granular products<br />
(upflow column percolation test)<br />
according to [8, 11].<br />
indoor air. For testing radioactivity a horizontal<br />
test st<strong>and</strong>ard was developed <strong>and</strong><br />
published as FprCEN/TS 17216 [12] which<br />
will become an EN after validation. Also<br />
a method on dose assessment <strong>of</strong> emitted<br />
gamma radiation from construction<br />
product was developed <strong>and</strong> published as<br />
CEN/TR 17113 [13], <strong>and</strong> a tender regarding<br />
the drafting <strong>of</strong> an EN was recently released.<br />
BWR 3 in product st<strong>and</strong>ards –<br />
CEN TC <strong>10</strong>4/WG 4 – status <strong>of</strong><br />
discussion<br />
CEN/TC <strong>10</strong>4/WG 4 is responsible <strong>for</strong> revision<br />
<strong>of</strong> EN 450-1 <strong>for</strong> Fly ash <strong>for</strong> Concrete<br />
[14] <strong>and</strong> started the discussion on the implementation<br />
<strong>of</strong> existing notified regulations.<br />
Up to now there are no general limit<br />
values <strong>for</strong> the release <strong>of</strong> dangerous substances<br />
into ground water, marine waters,<br />
surface waters or soil. There are only two<br />
EU countries, Germany <strong>and</strong> the Netherl<strong>and</strong>s,<br />
which have notified regulations<br />
placed on DG GROWTH website (http://<br />
ec.europa.eu/growth/tools-databases/cpds/index_en.htm)<br />
[7]. The data base entries<br />
<strong>and</strong> answers to an enquiry were compiled<br />
in a first draft background report<br />
consisting <strong>of</strong> environmental regulations <strong>for</strong><br />
fly ash in Europe [15].<br />
In Germany, the pro<strong>of</strong> <strong>of</strong> the environmental<br />
compatibility <strong>of</strong> fly ash according to DIN<br />
EN 450-1 is was given by a national approval<br />
serving as a technical pro<strong>of</strong> to demonstrate<br />
compliance with the environmental<br />
requirements <strong>for</strong> fly ash. A regular testing<br />
was required <strong>for</strong> fly ash from<br />
co-combustion. For fly ash from coal only<br />
no tests are required. This differentiation is<br />
due to the possibility <strong>of</strong> introducing dangerous<br />
substances by using co-combustion<br />
materials.<br />
Due to a judgement <strong>of</strong> the European Court<br />
<strong>of</strong> Justice (CJEU C-<strong>10</strong>0/13 from 16th October<br />
2014) regarding additional requirements<br />
<strong>for</strong> products covered by hEN Germany<br />
had to change the construction regulations.<br />
On 31st August 2017, the German building<br />
authority (DIBt) has published the “(model)<br />
Administrative Provision – Technical<br />
Building Rules” (Muster-Verwaltungsvorschrift<br />
Technische Baubestimmungen<br />
(M-VV-TB)) which include “Requirements<br />
on constructions regarding impact on soil<br />
<strong>and</strong> water” (ABuG) specifying requirements<br />
on constructions regarding environmental<br />
protection which by now were<br />
regulated in national technical approvals<br />
[16].<br />
A regular testing regarding BWR 3 is further<br />
required when fly ash is obtained from<br />
co-combustion (see Ta b l e 1 ). For fly ash<br />
from coal only <strong>and</strong> from co-combustion <strong>of</strong><br />
up to 5 % by mass <strong>of</strong> sewage sludge no tests<br />
are required due to pro<strong>of</strong>s over the last<br />
20 years. With the revised provision dated<br />
2019 the same is furnace bottom ash. As<br />
the ABuG defines requirements only, a<br />
guideline <strong>of</strong> the German Committee <strong>for</strong><br />
Structural Concrete (DAfStb) on the “Use<br />
<strong>of</strong> siliceous fly ash <strong>and</strong> bottom ash in concrete<br />
components in contact with soil,<br />
groundwater or rainfall” was prepared.<br />
The guideline is notified <strong>and</strong> publicly<br />
available (in German language) [17]. The<br />
inclusion into the MVV TB has been requested.<br />
With this guideline, an applicable, recognised<br />
technical rule was developed according<br />
to which technical documentation can<br />
be carried out with the involvement <strong>of</strong> a<br />
body qualified in accordance with Article<br />
43 <strong>of</strong> the Construction Products Regulation.<br />
The guideline provides the details <strong>for</strong><br />
initial type, autocontrol <strong>and</strong> third party<br />
testing as well as <strong>for</strong> single value exceedances.<br />
The con<strong>for</strong>mity evaluation consists<br />
in autocontrol testing <strong>of</strong> the producer <strong>and</strong><br />
third party control (by parties accredited<br />
<strong>for</strong> this test). The autocontrol testing has to<br />
include at least the requirements according<br />
EN 450-2. In addition, <strong>for</strong> fly ash from cocombustion<br />
specific parameters have to be<br />
tested once a month (at present) in autocontrol<br />
<strong>and</strong> twice a year in the third party<br />
control [17].<br />
In the Netherl<strong>and</strong>s, building materials that<br />
are used have to fulfil the requirements <strong>of</strong><br />
the Decree on Soil Quality [18] (the <strong>for</strong>mer<br />
Building Materials Decree). The decree<br />
gives limit values <strong>for</strong> the maximum<br />
leaching <strong>of</strong> inorganic compounds <strong>and</strong> <strong>for</strong><br />
the maximum content <strong>of</strong> organic compounds<br />
(see Ta b l e 2 ). The leaching behaviour<br />
has to be tested with the upflow<br />
column percolation test <strong>for</strong> unbound materials<br />
or with the tank test <strong>for</strong> bound materials<br />
like concrete <strong>and</strong> bricks which in most<br />
cases is a surface-related diffusion process.<br />
Leaching <strong>of</strong> final products has to be tested<br />
on a regular base. So, in the case <strong>of</strong> fly<br />
ash <strong>for</strong> concrete, concrete has to be tested<br />
47