VGB POWERTECH 10 (2020) - International Journal for Generation and Storage of Electricity and Heat
VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020). Technical Journal of the VGB PowerTech Association. Energy is us! Power plant products/by-products.
VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020).
Technical Journal of the VGB PowerTech Association. Energy is us!
Power plant products/by-products.
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Implementation <strong>of</strong> Basic Requirement in harmonized product st<strong>and</strong>ards <strong>VGB</strong> PowerTech <strong>10</strong> l <strong>2020</strong><br />
Tab. 1. Limit values <strong>for</strong> content <strong>and</strong> concrete <strong>for</strong><br />
fly ash from co-combustion in Germany<br />
(emission E64d) [16].<br />
Parameter content concrete<br />
leaching<br />
[mg/kg] [mg/m 2 ]<br />
antimony (Sb) 5.5<br />
arsenic (As) 150 11<br />
barium (Ba) 375<br />
lead (Pb) 700 7.7<br />
bromium (Br)<br />
cadmium (Cd) <strong>10</strong> 0.56<br />
chromium VI (Cr) 6.6<br />
Chromium, total(Cr) 600 7.7<br />
cobalt (Co) 8.8<br />
copper (Cu) 400 15.4<br />
molybdenium (Mo) 38.6<br />
nickel (Ni) 500 15.4<br />
mercury (Hg) 5 0.22<br />
selenium (Se)<br />
thallium (Tl) 7 0.88<br />
vanadium (V) 1,500 4.4*<br />
zink (Zn) 1,500 63.9<br />
tin (Sn)<br />
chloride (Cl-) 27,5515<br />
fluoride (F-) 826<br />
sulfate (SO42-) 26,4495<br />
PAK16 30<br />
PCB6 0.5<br />
PCDD/PCDF<br />
* evaluation adjourned<br />
** TE = toxicity equivalent<br />
<strong>10</strong>0 ng/<br />
kgTE**<br />
<strong>and</strong> not the constituent <strong>for</strong> producing concrete.<br />
The so-called NL BSB Productcertificaat<br />
(Dutch Building materials Decree product<br />
certificate) is used in the market to prove<br />
that the requirements <strong>of</strong> the decree [18]<br />
are fulfilled. A product certificate can be<br />
declared <strong>for</strong> the product (group) <strong>of</strong> one<br />
company or <strong>for</strong> a cluster <strong>of</strong> companies with<br />
the same product (group). The minimum<br />
test frequency has to be derived based on<br />
the k-concept (different from the k-value<br />
<strong>for</strong> use <strong>of</strong> fly ash in concrete) or the gamma-scheme<br />
[18].<br />
It is obvious from Ta b l e 1 <strong>and</strong> Ta b l e 2<br />
that the limit values <strong>for</strong> leachates from concrete<br />
in the two countries are different.<br />
But also the evaluation systems are different<br />
as they were developed separately<br />
with different background consideration<br />
(place <strong>of</strong> evaluation, sorption capacity <strong>of</strong><br />
soils, …) .<br />
The implementation <strong>of</strong> BWR 3 into harmonised<br />
product st<strong>and</strong>ards requires:<br />
––<br />
Parameters, methods <strong>and</strong> limit values,<br />
––<br />
Evaluation scheme <strong>for</strong> auto control <strong>and</strong><br />
third party control.<br />
Tab. 2. Limit values maximum leaching<br />
inorganic compounds <strong>for</strong> bound applications<br />
in NL (emission E64d) [18].<br />
Parameter<br />
concrete<br />
leaching<br />
[mg/m 2 ]<br />
antimony (Sb) 8.7<br />
arsenic (As) 260<br />
barium (Ba) 1,500<br />
lead (Pb) 400<br />
bromium (Br) 670<br />
cadmium (Cd) 3.8<br />
chromium VI (Cr)<br />
Chromium, total(Cr) 120<br />
cobalt (Co) 60<br />
copper (Cu) 98<br />
molybdenium (Mo) 144<br />
nickel (Ni) 81<br />
mercury (Hg) 1.4<br />
selenium (Se) 4.8<br />
thallium (Tl)<br />
vanadium (V) 320<br />
zink (Zn) 800<br />
tin (Sn) 50<br />
chloride (Cl-) 1<strong>10</strong>,000<br />
fluoride (F-) 2,500<br />
sulfate (SO42-) 165,000<br />
It further requires producers to declare<br />
the environmental per<strong>for</strong>mance <strong>of</strong> products<br />
according harmonized product st<strong>and</strong>ards.<br />
Based on the CPR [2], this can be<br />
done by declared values or by classes with<br />
the consequence that the customer finally<br />
has to decide whether the product can be<br />
used according national limit values. In<br />
both cases the required parameters have to<br />
be listed in the Declaration <strong>of</strong> Per<strong>for</strong>mance<br />
(DoP) <strong>and</strong> CE-mark. The EC <strong>and</strong><br />
CEN prefer declared values or classes as<br />
required by the CPR. The use <strong>of</strong> declared<br />
values is also the easiest way to prepare a<br />
st<strong>and</strong>ard. But placing a product on the<br />
market is not the responsibility <strong>of</strong> the EC<br />
as free trade is the overall aim. There<strong>for</strong>e,<br />
the consequences <strong>of</strong> such requirements<br />
regarding perception <strong>of</strong> customers <strong>for</strong><br />
products on the existing <strong>and</strong> long term<br />
served market is not sufficiently considered<br />
by now. A list <strong>of</strong> trace parameter with<br />
maximum declared values or with classes<br />
based on minimum <strong>and</strong> maximum values<br />
in the DoP <strong>and</strong>/or CE-mark will result<br />
in confusion in the market, will not promote<br />
free movement <strong>of</strong> goods <strong>and</strong> use <strong>of</strong><br />
secondary materials, <strong>and</strong> is finally against<br />
competition <strong>for</strong> materials with testing<br />
needs as not <strong>for</strong> all materials environmental<br />
requirements exist. It is obvious that a<br />
fly ash with a long list <strong>of</strong> environmental<br />
parameters (F i g u r e 4 ) like arsenic, cadmium,<br />
chromium, ... , will not be used<br />
when the competing product does not need<br />
such a declaration. The confusion or mistrust<br />
will further grow if such a fly ash has<br />
to place always NPD indicating that the<br />
producer may not be willing to declare the<br />
values or to per<strong>for</strong>m such tests. Competing<br />
construction products without testing<br />
needs will be preferred as causing no additional<br />
work <strong>for</strong> constructors regarding<br />
environmental requirements <strong>and</strong> work<br />
load to control whether declared values are<br />
meeting national requirements.<br />
Based on the requirements <strong>of</strong> existing environmental<br />
regulations WG 4 has proposed<br />
a system <strong>of</strong> categories to allow neutral in<strong>for</strong>mation<br />
on BWR3 in DoP <strong>and</strong> CE-mark<br />
[19]. By this, a “category” is defined as “a<br />
set or parameters, test procedures (as developed<br />
by TC 351) <strong>and</strong> limit values to be<br />
considered in a member state”. For each<br />
type <strong>of</strong> requirement (organics, content,<br />
leaching, concrete leaching) a category has<br />
to be defined <strong>for</strong> requirements in a member<br />
state leading to maximum three lines (organics,<br />
content, concrete leaching) <strong>for</strong> declaring<br />
environmental per<strong>for</strong>mance in<br />
DoP <strong>and</strong> CE-mark. In member states without<br />
respective environmental requirements<br />
NPD (no per<strong>for</strong>mance determined – or better:<br />
no test required) can be placed. This<br />
process however requires the preparation<br />
<strong>of</strong> a delegated act by the EC. As this is a<br />
time consuming process which will lead<br />
to a further postponement <strong>of</strong> the revision<br />
work <strong>of</strong> the st<strong>and</strong>ard, WG 4 has also proposed<br />
to consider the existing experience<br />
in the countries where requirements <strong>for</strong> either<br />
release into soil <strong>and</strong> ground or <strong>for</strong><br />
radioactivity have to be provided in a test<br />
report which is considered “neutral”, <strong>and</strong><br />
in case <strong>of</strong> radioactivity also to be declared<br />
by partly nuclide concentration or an<br />
index.<br />
Examples <strong>for</strong> the Declaration <strong>of</strong> Per<strong>for</strong>mance<br />
<strong>and</strong>/or CE marking by the four options<br />
“Declared values” , “Classes”, “Categories”<br />
<strong>and</strong> “Existing Systems” are given in<br />
F i g u r e 4 . It is obvious that the declaration<br />
via declared values <strong>and</strong> classes leads<br />
to a long list <strong>of</strong> parameters <strong>for</strong> environment<br />
which are predominant to the few technical<br />
parameters. The declaration via categories<br />
<strong>and</strong> by existing systems however, allow<br />
the in<strong>for</strong>mation on environmental parameters<br />
by a few lines only.<br />
In June 2018, TC <strong>10</strong>4 has tasked WG 4 to<br />
update the discussion paper on pros <strong>and</strong><br />
cons <strong>of</strong> the in<strong>for</strong>mation systems by the systems<br />
existing in the place <strong>of</strong> use. The updated<br />
report was sent to TC <strong>10</strong>4 <strong>and</strong> other<br />
TCs dealing with the revision <strong>of</strong> harmonized<br />
product st<strong>and</strong>ard to develop a common<br />
view <strong>for</strong> an acceptable solution on<br />
environmental in<strong>for</strong>mation in DoP <strong>and</strong> CEmark<br />
<strong>for</strong> all construction products. It was<br />
considered in a report <strong>of</strong> TC <strong>10</strong>4/WG14 on<br />
health aspects <strong>for</strong> concrete <strong>and</strong> concrete<br />
products provided as an input to TC 351/<br />
WG1 which decided to deal with this issue<br />
in a CEN Technical Report.<br />
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