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VGB POWERTECH 10 (2020) - International Journal for Generation and Storage of Electricity and Heat

VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020). Technical Journal of the VGB PowerTech Association. Energy is us! Power plant products/by-products.

VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020).
Technical Journal of the VGB PowerTech Association. Energy is us!
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Implementation <strong>of</strong> Basic Requirement in harmonized product st<strong>and</strong>ards <strong>VGB</strong> PowerTech <strong>10</strong> l <strong>2020</strong><br />

Tab. 1. Limit values <strong>for</strong> content <strong>and</strong> concrete <strong>for</strong><br />

fly ash from co-combustion in Germany<br />

(emission E64d) [16].<br />

Parameter content concrete<br />

leaching<br />

[mg/kg] [mg/m 2 ]<br />

antimony (Sb) 5.5<br />

arsenic (As) 150 11<br />

barium (Ba) 375<br />

lead (Pb) 700 7.7<br />

bromium (Br)<br />

cadmium (Cd) <strong>10</strong> 0.56<br />

chromium VI (Cr) 6.6<br />

Chromium, total(Cr) 600 7.7<br />

cobalt (Co) 8.8<br />

copper (Cu) 400 15.4<br />

molybdenium (Mo) 38.6<br />

nickel (Ni) 500 15.4<br />

mercury (Hg) 5 0.22<br />

selenium (Se)<br />

thallium (Tl) 7 0.88<br />

vanadium (V) 1,500 4.4*<br />

zink (Zn) 1,500 63.9<br />

tin (Sn)<br />

chloride (Cl-) 27,5515<br />

fluoride (F-) 826<br />

sulfate (SO42-) 26,4495<br />

PAK16 30<br />

PCB6 0.5<br />

PCDD/PCDF<br />

* evaluation adjourned<br />

** TE = toxicity equivalent<br />

<strong>10</strong>0 ng/<br />

kgTE**<br />

<strong>and</strong> not the constituent <strong>for</strong> producing concrete.<br />

The so-called NL BSB Productcertificaat<br />

(Dutch Building materials Decree product<br />

certificate) is used in the market to prove<br />

that the requirements <strong>of</strong> the decree [18]<br />

are fulfilled. A product certificate can be<br />

declared <strong>for</strong> the product (group) <strong>of</strong> one<br />

company or <strong>for</strong> a cluster <strong>of</strong> companies with<br />

the same product (group). The minimum<br />

test frequency has to be derived based on<br />

the k-concept (different from the k-value<br />

<strong>for</strong> use <strong>of</strong> fly ash in concrete) or the gamma-scheme<br />

[18].<br />

It is obvious from Ta b l e 1 <strong>and</strong> Ta b l e 2<br />

that the limit values <strong>for</strong> leachates from concrete<br />

in the two countries are different.<br />

But also the evaluation systems are different<br />

as they were developed separately<br />

with different background consideration<br />

(place <strong>of</strong> evaluation, sorption capacity <strong>of</strong><br />

soils, …) .<br />

The implementation <strong>of</strong> BWR 3 into harmonised<br />

product st<strong>and</strong>ards requires:<br />

––<br />

Parameters, methods <strong>and</strong> limit values,<br />

––<br />

Evaluation scheme <strong>for</strong> auto control <strong>and</strong><br />

third party control.<br />

Tab. 2. Limit values maximum leaching<br />

inorganic compounds <strong>for</strong> bound applications<br />

in NL (emission E64d) [18].<br />

Parameter<br />

concrete<br />

leaching<br />

[mg/m 2 ]<br />

antimony (Sb) 8.7<br />

arsenic (As) 260<br />

barium (Ba) 1,500<br />

lead (Pb) 400<br />

bromium (Br) 670<br />

cadmium (Cd) 3.8<br />

chromium VI (Cr)<br />

Chromium, total(Cr) 120<br />

cobalt (Co) 60<br />

copper (Cu) 98<br />

molybdenium (Mo) 144<br />

nickel (Ni) 81<br />

mercury (Hg) 1.4<br />

selenium (Se) 4.8<br />

thallium (Tl)<br />

vanadium (V) 320<br />

zink (Zn) 800<br />

tin (Sn) 50<br />

chloride (Cl-) 1<strong>10</strong>,000<br />

fluoride (F-) 2,500<br />

sulfate (SO42-) 165,000<br />

It further requires producers to declare<br />

the environmental per<strong>for</strong>mance <strong>of</strong> products<br />

according harmonized product st<strong>and</strong>ards.<br />

Based on the CPR [2], this can be<br />

done by declared values or by classes with<br />

the consequence that the customer finally<br />

has to decide whether the product can be<br />

used according national limit values. In<br />

both cases the required parameters have to<br />

be listed in the Declaration <strong>of</strong> Per<strong>for</strong>mance<br />

(DoP) <strong>and</strong> CE-mark. The EC <strong>and</strong><br />

CEN prefer declared values or classes as<br />

required by the CPR. The use <strong>of</strong> declared<br />

values is also the easiest way to prepare a<br />

st<strong>and</strong>ard. But placing a product on the<br />

market is not the responsibility <strong>of</strong> the EC<br />

as free trade is the overall aim. There<strong>for</strong>e,<br />

the consequences <strong>of</strong> such requirements<br />

regarding perception <strong>of</strong> customers <strong>for</strong><br />

products on the existing <strong>and</strong> long term<br />

served market is not sufficiently considered<br />

by now. A list <strong>of</strong> trace parameter with<br />

maximum declared values or with classes<br />

based on minimum <strong>and</strong> maximum values<br />

in the DoP <strong>and</strong>/or CE-mark will result<br />

in confusion in the market, will not promote<br />

free movement <strong>of</strong> goods <strong>and</strong> use <strong>of</strong><br />

secondary materials, <strong>and</strong> is finally against<br />

competition <strong>for</strong> materials with testing<br />

needs as not <strong>for</strong> all materials environmental<br />

requirements exist. It is obvious that a<br />

fly ash with a long list <strong>of</strong> environmental<br />

parameters (F i g u r e 4 ) like arsenic, cadmium,<br />

chromium, ... , will not be used<br />

when the competing product does not need<br />

such a declaration. The confusion or mistrust<br />

will further grow if such a fly ash has<br />

to place always NPD indicating that the<br />

producer may not be willing to declare the<br />

values or to per<strong>for</strong>m such tests. Competing<br />

construction products without testing<br />

needs will be preferred as causing no additional<br />

work <strong>for</strong> constructors regarding<br />

environmental requirements <strong>and</strong> work<br />

load to control whether declared values are<br />

meeting national requirements.<br />

Based on the requirements <strong>of</strong> existing environmental<br />

regulations WG 4 has proposed<br />

a system <strong>of</strong> categories to allow neutral in<strong>for</strong>mation<br />

on BWR3 in DoP <strong>and</strong> CE-mark<br />

[19]. By this, a “category” is defined as “a<br />

set or parameters, test procedures (as developed<br />

by TC 351) <strong>and</strong> limit values to be<br />

considered in a member state”. For each<br />

type <strong>of</strong> requirement (organics, content,<br />

leaching, concrete leaching) a category has<br />

to be defined <strong>for</strong> requirements in a member<br />

state leading to maximum three lines (organics,<br />

content, concrete leaching) <strong>for</strong> declaring<br />

environmental per<strong>for</strong>mance in<br />

DoP <strong>and</strong> CE-mark. In member states without<br />

respective environmental requirements<br />

NPD (no per<strong>for</strong>mance determined – or better:<br />

no test required) can be placed. This<br />

process however requires the preparation<br />

<strong>of</strong> a delegated act by the EC. As this is a<br />

time consuming process which will lead<br />

to a further postponement <strong>of</strong> the revision<br />

work <strong>of</strong> the st<strong>and</strong>ard, WG 4 has also proposed<br />

to consider the existing experience<br />

in the countries where requirements <strong>for</strong> either<br />

release into soil <strong>and</strong> ground or <strong>for</strong><br />

radioactivity have to be provided in a test<br />

report which is considered “neutral”, <strong>and</strong><br />

in case <strong>of</strong> radioactivity also to be declared<br />

by partly nuclide concentration or an<br />

index.<br />

Examples <strong>for</strong> the Declaration <strong>of</strong> Per<strong>for</strong>mance<br />

<strong>and</strong>/or CE marking by the four options<br />

“Declared values” , “Classes”, “Categories”<br />

<strong>and</strong> “Existing Systems” are given in<br />

F i g u r e 4 . It is obvious that the declaration<br />

via declared values <strong>and</strong> classes leads<br />

to a long list <strong>of</strong> parameters <strong>for</strong> environment<br />

which are predominant to the few technical<br />

parameters. The declaration via categories<br />

<strong>and</strong> by existing systems however, allow<br />

the in<strong>for</strong>mation on environmental parameters<br />

by a few lines only.<br />

In June 2018, TC <strong>10</strong>4 has tasked WG 4 to<br />

update the discussion paper on pros <strong>and</strong><br />

cons <strong>of</strong> the in<strong>for</strong>mation systems by the systems<br />

existing in the place <strong>of</strong> use. The updated<br />

report was sent to TC <strong>10</strong>4 <strong>and</strong> other<br />

TCs dealing with the revision <strong>of</strong> harmonized<br />

product st<strong>and</strong>ard to develop a common<br />

view <strong>for</strong> an acceptable solution on<br />

environmental in<strong>for</strong>mation in DoP <strong>and</strong> CEmark<br />

<strong>for</strong> all construction products. It was<br />

considered in a report <strong>of</strong> TC <strong>10</strong>4/WG14 on<br />

health aspects <strong>for</strong> concrete <strong>and</strong> concrete<br />

products provided as an input to TC 351/<br />

WG1 which decided to deal with this issue<br />

in a CEN Technical Report.<br />

48

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