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Laboratory Manual for Introductory Geology 4e

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FIGURE 6.4 Textures of chemical sedimentary rocks.

(a) Coarse, interlocking halite grains in rock salt.

(b) Cryptocrystalline silica grains (chert). Note the almost

glassy appearance and conchoidal fracture.

The composition of a chemical sedimentary rock depends on the composition

of the solution it was derived from—some chemical sedimentary rocks consist of

salts (e.g., halite, gypsum), whereas others consist of silica or carbonate. In some

chemical sedimentary rocks, the grains are large enough to see (FIG. 6.4a). But in

others, the grains are so small that the rock looks almost like porcelain or obsidian

(FIG. 6.4b). Such rocks are called cryptocrystalline rocks, from the Latin crypta–,

meaning hidden.

Geologists distinguish among different types of chemical sedimentary rocks primarily

by their composition:

■ Evaporites are chemical sedimentary rocks, composed of crystals formed when

salt water evaporates, and typically occur in thick deposits. The most common examples

of evaporites are rock salt and rock gypsum (alabaster).

■ Oolitic limestone is a unique form of limestone in which calcite precipitates

onto small mineral grains; as the grains roll back and forth, the calcite coating thickens,

producing bead-shaped grains that are then lithified.

■ Travertine (chemical limestone) Travertine is a special kind of limestone composed

of calcite (CaCO 3

) formed by chemical precipitation from groundwater that

has seeped out of the ground either in hot- or cold-water springs or from the walls

of caves.

■ Dolostone like limestone, is a carbonate rock, but it differs from limestone

in that it contains a significant amount of dolomite, a mineral with equal amounts

of calcium and magnesium [CaMg(CO 3

) 2

]. Unlike calcite in oolitic limestone or

travertine, the dolomite doesn’t precipitate directly from seawater. Instead, it forms

from limestone during diagenesis when magnesium in groundwater interacts with

calcite.

■ Chert composed of very fine-grained silica. One kind of chert, called replacement

chert, is formed by diagenesis when cryptocrystalline quartz replaces calcite in

limestone. Another kind (biochemical chert) is formed from microscopic plankton

shells, as we will see shortly. Note: The chemical and biochemical forms of chert cannot

be distinguished in hand samples.

6.3 THE BASIC CLASSES OF SEDIMENTARY ROCKS

151

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