102of the crystallization phenomenon.Figure 4. Heat flow rate released during ethanol fermentation˙Q f , heat flow rate of the fermentation heat exchanger˙Q fhx and fermentation temperature T 21.Figure 7. Variation of the lithi<strong>um</strong> bromi<strong>de</strong> mass fractionduring the fermentation process.Figure 5.flows.Pressure profile of absorption <strong>chiller</strong> internalHeat flows variation during the fermentation pro-Figure 8.cess.Similarly, the profile of the heat flow input in the absorption<strong>chiller</strong> was obtained during the fermentationprocess and is shown in Figure 8. The cooling capacity˙Q e <strong>de</strong>creases by around 4% during the process. Thus,itcanaffectthefermentationtemperatureandreducethe fermentation efficiency. There are some alternativesavailable to increase the cooling capacity of the machinewhich inclu<strong>de</strong>: increasing the water loop inlet temperaturegenerator T 11 or <strong>de</strong>creasing the temperature of thewater from the cooling tower T 23 that enters in the con<strong>de</strong>nserT 15 and evaporator T 17.During the fermentation, the water loop outlet evaporatorFigure 6. Temperature profile of absorption <strong>chiller</strong> internaltemperature T 18 increases by around 3 ◦ C,becauseflows.of the temperature variation of the water from the coolingtower. The water loop outlet generator temperatureence Δξ between the strong and the weak solution <strong>de</strong>creaseduring the ethanol fermentation. Thus the massflow rate of the superheated steam (point 7) <strong>de</strong>creases,and the cooling capacity ˙Q e of the absorption <strong>chiller</strong>also <strong>de</strong>creases, as seen in Figure 8. The crystallizationline ξ cryst presented in Figure 7 shows the value of thelithi<strong>um</strong> bromi<strong>de</strong> mass fraction at point 6 from which thecrystallization process occurs. The difference betweenthe lithi<strong>um</strong> bromi<strong>de</strong> mass fraction of the strong solutionξ 4 and the mass fraction of the crystallization point ξ crystis around 10 %, showing that the operational conditionsof the absorption <strong>chiller</strong> differ consi<strong>de</strong>rably from thoseT 12 is around 88 ◦ C. This stream can still be used inanother process to improve the energy efficiency of theplant, either in a cooling capacity or to improve otherprocesses such as air conditioning systems, sugar dryers,recovery of alcoholic gas in the distillery and cooling ofmust or wine.The temperature of the water from the cooling towerT 23 is an important parameter as it affects the performanceand the cooling capacity of the absorption <strong>chiller</strong>.As seen in Figure 9, on increasing the water temperature,the heat flow input in the absorption <strong>chiller</strong> <strong>de</strong>creases.The cooling capacity ˙Q e is affected by the cool-116 / Vol. 13 (No. 3) Int. Centre for Applied Thermodynamics (ICAT)
103ing tower and it is essential to keep the water temperatureas low as possible. For each 1 ◦ C increase in thetemperature of the water from the cooling tower, thecooling capacity of the absorption <strong>chiller</strong> <strong>de</strong>creases byaround 35 kW, which is the cause of the reduction inthe cooling capacity shown in Figure 8.Figure 9. Heat flow input to the absorption <strong>chiller</strong> with thevariation in the temperature of the water from the coolingtower.process4 ConclusionsThe introduction of an absorption <strong>chiller</strong> in theethanol fermentation cooling system has been investigatedin this paper. A dynamic mo<strong>de</strong>l for the fed-batchfermentation process coupled with a quasi-steady statemo<strong>de</strong>l for the absorption system was <strong>de</strong>veloped un<strong>de</strong>rindustrial conditions.The simulation with the new configuration of the refrigerationsystem (absorption <strong>chiller</strong> and cooling tower)showed that it is possible to reduce the fermentationtemperature by around 1 ◦ C and increase the fermentationefficiency by around 0.8%, representing an annualethanol increase of around 240 m 3 per fermentation vat.These results can be improved by <strong>de</strong>creasing the temperatureto an i<strong>de</strong>al value in terms of both fermentationkinetics and cell viability. To improve these results,a refrigeration machine with a higher cooling capacityshould be used, un<strong>de</strong>r controlled operating conditions.An increase in the ethanol concentration of the winecan reduce significantly the energy cons<strong>um</strong>ption in thedownstream processes, such as distillation and vinasseconcentration. The industrial losses, especially those relatedto contamination of the fermentation medi<strong>um</strong>, canbe minimized through a temperature control.The results of this study <strong>de</strong>monstrate the potentialapplication of the absorption <strong>chiller</strong> in the fermentationprocess. An absorption <strong>chiller</strong> powered by industrialwaste heat is an excellent energy saving option in a cogenerationsystem in a sugar and ethanol plant. Thismay also promote an increase in the energy balance ofthe ethanol production process, the value for which iscurrently around 8.5. All of these advantages contributealso to the competitiveness and sustainability of ethanolindustry.AcknowledgementsThe authors would like to acknowledge Usina CerradinhoAçúcar e Álcool S/A for making available thedata and the FINEP for the financial support ofthis study.NomenclatureCOP coefficient of performanceCp specific heat capacity, kJ kg −1 K −1E ethanol concentration, kg m −3h enthalpy, kJ kg −1K i substrate inhibition coefficient, m 3 kg −1K S substrate saturation constant, kg m −3M molecular mass, kg kmol −1ṁ mass flow rate, kg h −1m E ethanol production associated with growth,kg kg −1 h −1m X maintenance coefficient, kg kg −1 h −1n product inhibition powerP pressure, kPa˙Q heat flow, kWS substrate concentration, kg m −3t time, hT temperature, ◦ CUA overall thermal conductance, kW K −1V working vol<strong>um</strong>e, m 3˙V vol<strong>um</strong>e flow rate, m 3 h −1X cell concentration, kg m −3y mole fractionY yield factor, kg kg −1Ẇ power, kWGreek symbolsΔH S fermentation heat released, kJ kg −1Δt time difference, hη efficiency, %μ specific growth rate, h −1φ productivity, kg m −3 h −1ρ <strong>de</strong>nsity, kg m −3ξ lithi<strong>um</strong> bromi<strong>de</strong> mass fraction, %References:Albers, E., Larsson, C., Lidén, G., Niklasson, C., andGustafsson, L. (2002). Continuous estimation of productconcentration with calorimetry and gas analysisduring anaerobic fermentations of Saccharomyces cerevisiae.Thermochimica acta, 394:185–190.Aldiguier, A. S., Alfenore, S., Cameleyre, X., Goma, G.,Uribelarrea, J. L., Guillouet, S. E., and Molina-Jouve,C. (2004). Synergistic temperature and ethanol effect onSaccharomyces cerevisiae dynamic behaviour in ethanolbio-fuel production. Bioprocess and Biosytems Engineering,26(4):217–222.ASHRAE (2001). HVAC Fundamentals Handbook.American Society of Heating, Refrigerating and Air-Conditioning Engineers.Atala, D. I. P., Costa, A. C., Maciel, R., and Maugeri,F. (2001). Kinetics of ethanol fermentation with highbiomass concentration consi<strong>de</strong>ring the effect of temperature.Applied Biochemistry and Biotechnology, 91-93(1-9):353–365.Bejan, A. and Kraus, A. D. (2003). Heat Transfer Handbook.John Wiley and Sons, Inc.Int. J. of Thermodynamics (IJoT) Vol. 13 (No. 3) / 117
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UNIVERSIDADE FEDERAL DE SANTA CATAR
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Catalogação na fonte pela Bibliot
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A toda minha família e amigos. . .
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Quem, de três milênios,Não é ca
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ABSTRACTEthanol fermentation is an
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Figura 20 Sistema de resfriamento d
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Figura 59 Diagrama de Dühring do r
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LISTA DE SÍMBOLOSSímbolos GeraisA
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SsttrvXwwbwkSubstratoForteTorre de
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4.3.7 Bomba de Solução . . . . .
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2A relação entre a energia renov
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4energia disponíveis no setor sucr
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6Cana de AçúcarRecepçãoCana de
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8A levedura é um microorganismo te
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10(a) Variação diária da tempera
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12efeitos, obtendo-se então os vap
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142.2 REFRIGERAÇÃO POR ABSORÇÃO
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16sorção intermitente, onde exist
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18Tabela 1 - Volume específico dos
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20segue,COP ca =COP =˙Q e˙Q g(2.4
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22Figura 14 - Diagrama de Dühring
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242.2.4 RESFRIADORES DE ABSORÇÃO
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26Figura 17 - Resfriador de absorç
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28em etanol foram encontrados para
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303.4 RESFRIADOR DE ABSORÇÃOSiste
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32ses como Japão, China e Coréia
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354 MODELAGEM MATEMÁTICA4.1 FERMEN
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37Tabela 5 - Dados fermentativos co
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39onde t é o tempo final do proces
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41onde a relação ω é expressa p
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43Tabela 8 - Dados de entrada da si
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45como segue,Cp g M gdT gdt= ∑ i(
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47O balanço de massa é expresso p
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49ção,(T 14 = T 13 + (T a − T 1
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- Page 108 and 109: 80Tabela 12 - Resultados do process
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- Page 113 and 114: 85REFERÊNCIAS BIBLIOGRÁFICASALBER
- Page 115 and 116: 87DIAS, M. O. S.; FILHO, R. M.; ROS
- Page 117: 89SÁNCHEZ, S.; BRAVO, V.; MOYA, A.
- Page 120 and 121: 922001). Os parâmetros da Equaçã
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- Page 124 and 125: 96Figura 63 - Calor específico da
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- Page 128 and 129: 100inhibition coefficient, E max is
- Page 132: 104Camargo, C. A., Ushima, A. H., R