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Catalogue of Research Groups from Moldova - WBC-INCO Net

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SEVENTH FRAMEWORK<br />

PROGRAMME<br />

THE LABORATORY OF COORDINATION CHEMISTRY<br />

Organization activity type : RES<br />

FP7 theme : nmp<br />

Contact person : Dr. Ion Bulhac<br />

Address : The Institute <strong>of</strong> Chemistry <strong>of</strong> The Academy <strong>of</strong> Sciences<br />

3, Academiei street<br />

MD2028 Chisinau<br />

Republic <strong>of</strong> <strong>Moldova</strong><br />

E-mail : ionbulhac@yahoo.com<br />

webpage : www.chem.md<br />

8<br />

THE INSTITUTE OF CHEMISTRY, THE ACADEMY OF SCIENCES<br />

BRIEf dESCRIpTIon <strong>of</strong> ThE oRganIzaTIon<br />

The Laboratory <strong>of</strong> Coordination Compounds was founded by the academician Antonie Ablov in 1959 as<br />

part <strong>of</strong> the Institute <strong>of</strong> Chemistry <strong>of</strong> the Academy <strong>of</strong> Sciences <strong>of</strong> <strong>Moldova</strong>.<br />

Polynuclear dioximates and carboxylates <strong>of</strong> transition metals were obtained on the basis <strong>of</strong> fundamental<br />

concepts and laws. Based on this research several elaborations were <strong>of</strong>fered and over 40 <strong>of</strong> them patented<br />

: patents on the themes <strong>of</strong> catalysts, colorants, stimulators <strong>of</strong> biological processes, new coordination<br />

compounds for obtaining extra-pure metals, ion-selective electrodes and anticorrosion coating agents.<br />

KEywoRdS on CoRE CompETEnCIES<br />

template synthesis; polynuclear compounds; magnetic properties; biological activity; transition metals<br />

ExpERTISE / CompETEnCIES / TEChnologIES / RTd Know-how<br />

Synthetic methods (including template synthesis) <strong>of</strong> the mononuclear, polynuclear, supramolecular<br />

compounds and coordination polymers <strong>of</strong> the transition metals with organic polyfunctional ligands,<br />

based on Schiff bases and metal carboxylates;<br />

Basic research in elucidating physical, chemical, magnetic, catalytic and structural properties <strong>of</strong> the<br />

synthesized compounds;<br />

Applied research <strong>of</strong> the coordination compounds as stimulators <strong>of</strong> the vital activity <strong>of</strong> some<br />

microorganisms in the biosynthesis <strong>of</strong> enzymes, as well as stimulators to raise the productivity and<br />

drought resistance <strong>of</strong> cultivated plants.<br />

InTERnaTIonal CoopERaTIon ExpERIEnCE<br />

2009-2012 SCOPES “Magnetic coordination polymers <strong>of</strong> the nanosized clusters”;<br />

2006-2008 SCOPES “New Approaches for Building Potential Magnetic Materials : From Isolated<br />

Metals Clusters to Molecule-Based Magnets”;<br />

2005-2007 MRDA/CRDF “Synthesis and Investigation <strong>of</strong> Homo-, Hetero- and Mixed Valence Iron<br />

Complexes with Carboxylate and Hydrazine Derivatives Ligands as New Catalysts for Oxygenation <strong>of</strong><br />

Hydrocarbons”;<br />

2004-2006 INTAS “Polymetallic Complexes as Molecular Nanomagnets and Novel Homogeneous<br />

Catalysts”.

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