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Coherent Backscattering from Multiple Scattering Systems - KOPS ...

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4 Samples<br />

3 0<br />

2 5<br />

n u m b e r o f p a rtic le s<br />

2 0<br />

1 5<br />

1 0<br />

5<br />

0<br />

1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0 4 5 0<br />

p a rtic le d ia m e te r [n m ]<br />

Figure 4.1: Particle size and polydispersity. From the electron microscope image<br />

(left) the distribution of the particle sizes of R700 (right) was obtained by measuring the<br />

diameters of approximately 150 particles [47].<br />

and can quite easily be calculated by measuring the weight m and the spatial dimensions r<br />

and h of the sample, while the mass density ρ of the scattering material can be obtained <strong>from</strong><br />

numerous literature sources.<br />

For strong scattering and low mean free paths, the sample should be as dense as possible. If<br />

however the filling fraction is larger than a certain value (which depends on the mismatch of<br />

the refractive indices of scatterers and surrounding medium) [20], scattering takes place at the<br />

holes rather than the particles, so that there is no use increasing the volume fraction beyond<br />

this value.<br />

4.1.3 Effective refractive index<br />

The refractive index mismatch between the particles and the surrounding medium determines<br />

the effectiveness of the scattering. In contrast, the effective refractive index, which is an average<br />

over the indices of the scatterers, n scat , and the medium in between, n surr , describes<br />

the sample as a whole and is for example needed to calculate the reflectivity of the sample<br />

surface.<br />

Linear approach<br />

The most simple and straightforward approach to calculate the effective refractive index n eff<br />

of a sample is to establish an average medium with an averaged refractive index<br />

36<br />

n eff = f · n scat + (1− f ) · n surr

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