1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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6 Experimental Section broad signals), 136.0, 136.4, 137.0, 137.4, 137.7, 137.9 (two signals), 138.4, 141.9, 142.1, 145.3, 149.0, 150.7 (two signals), 151.2, 152.3, 155.5, 160.1, 171.5, 192.2, 196.7. MS (MALDI-TOF, DCTB): m/z (%) = 1369 (100) [M] + . IR (ATR): 𝜈� [cm -1 ] = 3318, 3304, 3032, 2964, 2931, 2869, 1777, 1682, 1617, 1553, 1502, 1476, 1399, 1363, 1348, 1307, 1222, 1159, 1110, 1058, 1026, 984, 850, 800, 729, 676. UV/Vis (CH2Cl2): λ [nm] (ε [M -1 ·cm -1 ]) = 419 (100900), 444 (155100), 541 (13500), 603 (10200), 669 (30600), 733 (12700). EA: C92H89N9O3·EtOAc·0.5 H2O. Calc.: C 78.66, H 6.74, N 8.60; found: C 79.06, H 7.14, N 8.41. 188
7 References References 7 1 (a) World Health Organization (WHO), The World Health Report 2007, WHO Press, Geneva, 2007. (b) World Health Organization (WHO), The World Health Report 2008, WHO Press, Geneva, 2008. 2 Shell International BV, Shell Energy Scenarios To 2050, The Hague, 2008. 3 R. Bonnett, Chemical Aspects of Photodynamic Therapy (Advanced Chemistry Texts), Gordon and Breach Science Publishers, Amsterdam, 2000. 4 M. R. Hamblin, P. Mroz (Eds.), Advances in Photodynamic Therapy: Basic, Translational and Clinical (Engineering in Medicine & Biology), Artech House Inc., Boston/London, 2008. 5 B. C. Wilson, M. S. Patterson, Phys. Med. Biol. 2008, 53, R61-R109. 6 A. Juarranz, P. Jaen, F. Sanz-Rodriguez, J. Cuevas, S. Gonzalez, Clin. Transl. Oncol. 2008, 10, 148-154. 7 see e.g.: (a) T. S. Marks, A. Maule, Appl. Microbiol. Biotechnol. 1992, 38, 413-416. (b) T. S. Marks, J. D. Allpress, A. Maule, Appl. Environ. Microbiol. 1989, 55, 1258-1261. 8 see e.g.: (a) V. Balzani, A. Credi, M. Venturi, Molecular Devices and Machines – A Journey into the Nano-World, Wiley-VCH, Weinheim, 2003. (b) J. A. Hutchison, T. D. M. Bell, T. Ganguly, K. P. Ghiggino, S. J. Langford, N. R. Lokan, M. N. Paddon-Rowb, J. Photochem. Photobiol. A 2008, 197, 220-225. 9 A. F. Collings, C. Critchley (Eds.), Artificial Photosynthesis – From Basic Biology to Industrial Application, Wiley-VCH, Weinheim, 2005. 10 (a) Govindjee, H. Gest, Photosynth. Res. 2002, 73, 11-20. (b) Govindjee, J. T. Beatty, H. Gest, Photosynth. Res. 2003, 76, 303-318. (c) Govindjee, J. F. Allen, J. T. Beatty, Photosynth. Res. 2004, 80, 1-13. 11 see e.g.: (a) A. Amunts, O. Drory, N. Nelson, Nature 2007, 447, 58-63. (b) B. Loll, J. Kern, W. Saenger, A. Zouni, J. Biesiadka, Nature 2005, 438, 1040-1044. (c) K. N. Ferreira, T. M. Iverson, K. Maghlaoui, J. Barber, S. Iwata, Science 2004, 303, 1831- 1838. 12 see e.g.: (a) F. Vacha, L. Bumba, D. Kaftan, M. Vacha, Micron 2005, 36, 483-502. (b) A. Telfer, Photochem. Photobiol. Sci. 2005, 4, 950-956. (c) C. Putnam-Evans, B. A. Barry, Photosynth. Res. 2007, 92, 273-274. (d) K. Sauer, J. Yano, V. K. Yachandra, Coord. Chem. Rev. 2008, 252, 318-335. (e) P. Fromme, I. Grotjohann, Structure of Photosystems I and II in Results and Problems In Cell Differentiation, Vol. 45, Springer- Verlag GmbH, Heidelberg/Berlin, 2008. 13 C. Neveu, bsd. on pdb files 2axt and 1s5l, 2008. 14 L. R. Milgrom, The Colours of Life – An Introduction tot he Chemistry of <strong>Porphyrins</strong> and Related Compounds, Oxford University Press – Oxford, 1997. 15 W. Z. Küster, Z. Physiol. Chem., 1913, 82, 463-483. 189
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Semi-Natural and Synthetic Chiral C
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Die vorliegende Arbeit entstand in
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Table of Contents 1 Introduction 1
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n J j-coupling (constant) with n in
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1 Introduction characteristics. For
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1 Introduction 1.1 Porphyrins - A G
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1 Introduction Especially interesti
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1 Introduction 8 [H] 4 + 4 O H O H
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1 Introduction complexes are usuall
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1 Introduction transitions as it is
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1 Introduction 1.2 Photodynamic The
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1 Introduction Certainly, Photofrin
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1 Introduction intact membranes bei
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1 Introduction components, the limi
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2 State of The Art & Aims They were
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2 State of The Art & Aims 2.2 Aim o
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3 Discussion and Results encapsulat
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3 Discussion and Results diastereot
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3 Discussion and Results 30 E ½ Re
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3 Discussion and Results irradiatio
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3 Discussion and Results 34 R 1 O N
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3 Discussion and Results 3.2.2.1.2
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3 Discussion and Results Table 4. S
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3 Discussion and Results 3.2.2.2 FR
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3 Discussion and Results 3.2.2.3 Ac
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3 Discussion and Results 3.2.3.1 IR
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3 Discussion and Results 3.2.3.2 NM
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3 Discussion and Results 3.2.3.3 Va
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3 Discussion and Results Obviously,
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3 Discussion and Results Like Figur
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3 Discussion and Results utilizatio
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3 Discussion and Results has been d
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3 Discussion and Results other TPP
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3 Discussion and Results (being sup
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3 Discussion and Results other band
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3 Discussion and Results Table 10.
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3 Discussion and Results voltammogr
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3 Discussion and Results 3.2.5 Inhe
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3 Discussion and Results effects 12
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3 Discussion and Results 74 Δθ [m
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3 Discussion and Results 3.2.6.2 10
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3 Discussion and Results vibration
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3 Discussion and Results 3.2.6.4 Sy
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3 Discussion and Results cyanomethy
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3 Discussion and Results 3.2.6.5 Co
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3 Discussion and Results phenyl sub
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3 Discussion and Results 90 5 μA -
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3 Discussion and Results 3.2.7 Appr
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3 Discussion and Results (75 eq.) w
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3 Discussion and Results 3.2.7.2 Sy
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3 Discussion and Results of rotatio
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3 Discussion and Results Thus, the
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3 Discussion and Results Time-resol
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3 Discussion and Results first redu
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3 Discussion and Results correspond
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3 Discussion and Results The remain
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3 Discussion and Results 3.2.8.1 Us
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3 Discussion and Results With all t
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3 Discussion and Results The interm
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3 Discussion and Results 116 HO 2 C
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3 Discussion and Results nitro comp
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3 Discussion and Results The effect
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3 Discussion and Results 3.2.9 Pote
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3 Discussion and Results peak at m/
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3 Discussion and Results Table 25.
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3 Discussion and Results 130
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4 Summary As the characterization d
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5 Zusammenfassung 5 Zusammenfassung
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5 Zusammenfassung Da in guten Ausbe
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1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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