1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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Cirruculum vitae Stefan Jasinski Geburtstag: 02. Juli 1978 Geburtsort: Nürnberg Staatsangehörigkeit: deutsch Familienstand: ledig Schulische Ausbildung 09.1984-07.1988 Grund- und Volksschule Igensdorf 09.1988-06.1997 Ehrenbürg-Gymnasium Forchheim, Abitur 1997 Ersatzdienst 07.1997-07.1998 Zivildienst, HNO Klinik der Universitätklinik Erlangen Hochschulausbildung 11.1998-10.2003 Studium an der Friedrich-Alexander-Universität Erlangen-Nürnberg 202 Studiengang: Chemie (Diplom) seit 10.2001 Stipendiat der Studienstiftung des deutschen Volkes 11.2003-07.2004 Diplomarbeit am Institut für Organische Chemie der Friedrich- Alexander-Universität Erlangen-Nürnberg unter Anleitung von Prof. Dr. A. Hirsch (Dr. N. Jux) zum Thema “Synthese und Charakterisierung inhärent chiraler Tetraarylporphyrinsysteme mit exozyklischen Ringen” 08.2004-11.2008 Doktorarbeit am Institut für Organische Chemie der Friedrich- Alexander-Universität Erlangen-Nürnberg unter Anleitung von Priv.- Doz. Dr. N. Jux zum Thema “Semi-Natural and Synthetic Chiral Cycloketo-Porphyrin Systems – Approaching Novel Photosensitizers”
203 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 http://www.nature.com/jid/journal/v67/n1/abs/5617014a.html 53 http://aad2008.omnibooksonline.com/data/papers/FRM-553-B.pdf 54 55
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Semi-Natural and Synthetic Chiral C
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Die vorliegende Arbeit entstand in
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Table of Contents 1 Introduction 1
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n J j-coupling (constant) with n in
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1 Introduction characteristics. For
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1 Introduction 1.1 Porphyrins - A G
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1 Introduction Especially interesti
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1 Introduction 8 [H] 4 + 4 O H O H
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1 Introduction complexes are usuall
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1 Introduction transitions as it is
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1 Introduction 1.2 Photodynamic The
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1 Introduction Certainly, Photofrin
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1 Introduction intact membranes bei
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1 Introduction components, the limi
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2 State of The Art & Aims They were
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2 State of The Art & Aims 2.2 Aim o
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3 Discussion and Results encapsulat
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3 Discussion and Results diastereot
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3 Discussion and Results 30 E ½ Re
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3 Discussion and Results irradiatio
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3 Discussion and Results 34 R 1 O N
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3 Discussion and Results 3.2.2.1.2
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3 Discussion and Results Table 4. S
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3 Discussion and Results 3.2.2.2 FR
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3 Discussion and Results 3.2.2.3 Ac
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3 Discussion and Results 3.2.3.1 IR
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3 Discussion and Results 3.2.3.2 NM
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3 Discussion and Results 3.2.3.3 Va
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3 Discussion and Results Obviously,
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3 Discussion and Results Like Figur
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3 Discussion and Results utilizatio
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3 Discussion and Results has been d
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3 Discussion and Results other TPP
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3 Discussion and Results (being sup
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3 Discussion and Results other band
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3 Discussion and Results Table 10.
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3 Discussion and Results voltammogr
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3 Discussion and Results 3.2.5 Inhe
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3 Discussion and Results effects 12
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3 Discussion and Results 74 Δθ [m
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3 Discussion and Results 3.2.6.2 10
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3 Discussion and Results vibration
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3 Discussion and Results 3.2.6.4 Sy
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3 Discussion and Results cyanomethy
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3 Discussion and Results 3.2.6.5 Co
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3 Discussion and Results phenyl sub
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3 Discussion and Results 90 5 μA -
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3 Discussion and Results 3.2.7 Appr
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3 Discussion and Results (75 eq.) w
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3 Discussion and Results 3.2.7.2 Sy
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3 Discussion and Results of rotatio
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3 Discussion and Results Thus, the
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3 Discussion and Results Time-resol
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3 Discussion and Results first redu
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3 Discussion and Results correspond
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3 Discussion and Results The remain
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3 Discussion and Results 3.2.8.1 Us
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3 Discussion and Results With all t
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3 Discussion and Results The interm
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3 Discussion and Results 116 HO 2 C
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3 Discussion and Results nitro comp
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3 Discussion and Results The effect
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3 Discussion and Results 3.2.9 Pote
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3 Discussion and Results peak at m/
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3 Discussion and Results Table 25.
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3 Discussion and Results 130
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4 Summary As the characterization d
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5 Zusammenfassung 5 Zusammenfassung
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5 Zusammenfassung Da in guten Ausbe
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6 Experimental Section UV/Vis spect
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6 Experimental Section 6.2 Studied
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6 Experimental Section 13 C NMR (10
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6 Experimental Section (cyanomethyl
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6 Experimental Section 6.2.4 AB3-Ty
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6 Experimental Section 6.2.4.3 5 4
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6 Experimental Section 6.2.4.5 5 4
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Page 166 and 167: 6 Experimental Section EA: C57H56N4
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Page 170 and 171: 6 Experimental Section 6.2.5 A2B2-T
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Page 176 and 177: 6 Experimental Section 6.2.5.7 αβ
Page 178 and 179: 6 Experimental Section 6.2.5.9 αα
Page 180 and 181: 6 Experimental Section 6.2.5.11 α
Page 182 and 183: 6 Experimental Section 6.2.5.13 α
Page 186 and 187: 6 Experimental Section 6.2.6 AB2C-T
Page 190 and 191: 6 Experimental Section UV/Vis (CH2C
Page 194 and 195: 6 Experimental Section UV/Vis (CH2C
Page 196 and 197: 6 Experimental Section broad signal
Page 198 and 199: 7 References 16 H. Fischer, K. Zeil
Page 200 and 201: 7 References 57 S. Schwartz, K. Abs
Page 202 and 203: 7 References 89 (a) R. C. Fuson, J.
Page 204 and 205: 7 References 131 (a) J. Perdew, Phy
Page 206 and 207: S. Jasinski, N. Jux, “Investigati
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1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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