1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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Als Dissertation genehmigt von der naturwissenschaftlichen Fakultät der Universität Erlangen-Nürnberg. Tag der mündlichen Prüfung: 17. April 2009 Vorsitzender der Promotionskommision: Prof. Dr. Eberhard Bänsch Erstberichterstatter: Priv.-Doz. Dr. Norbert Jux Zweitberichterstatter: Prof. Dr. Andreas Hirsch Drittberichterstatterin: Prof. Dr. Beate Röder
Die vorliegende Arbeit entstand in der Zeit von August 2004 bis Dezember 2008 am Institut für Organische Chemie der Friedrich-Alexander-Universität Erlangen-Nürnberg. Mein besonderer Dank gilt hierbei meinen Doktorvätern Prof. Dr. Andreas Hirsch und P. D. Dr. Norbert Jux für die gewährte Unterstützung und das rege Interesse am Fortgang der Arbeiten. In diesem Zusammenhang danke ich auch herzlich meinen Kooperationspartnern Prof. Dr. Gerhard Bringmann (Julius-Maximilians-Universität Würzburg), Prof. Dr. Klaus Schomäcker (Universität zu Köln) und vor allem Prof. Dr. Beate Röder (Humboldt-Universität zu Berlin) und Dr. Eugeny Ermilov (Berlin) für die hervorragende Zusammenarbeit. Phantasie ist wichtiger als Wissen, denn Wissen ist begrenzt. ALBERT EINSTEIN
Page 1: Semi-Natural and Synthetic Chiral C
Page 5 and 6: Table of Contents 1 Introduction 1
Page 7: n J j-coupling (constant) with n in
Page 10 and 11: 1 Introduction characteristics. For
Page 12 and 13: 1 Introduction 1.1 Porphyrins - A G
Page 14 and 15: 1 Introduction Especially interesti
Page 16 and 17: 1 Introduction 8 [H] 4 + 4 O H O H
Page 18 and 19: 1 Introduction complexes are usuall
Page 20 and 21: 1 Introduction transitions as it is
Page 22 and 23: 1 Introduction 1.2 Photodynamic The
Page 24 and 25: 1 Introduction Certainly, Photofrin
Page 26 and 27: 1 Introduction intact membranes bei
Page 28 and 29: 1 Introduction components, the limi
Page 30 and 31: 2 State of The Art & Aims They were
Page 32 and 33: 2 State of The Art & Aims 2.2 Aim o
Page 34 and 35: 3 Discussion and Results encapsulat
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Page 38 and 39: 3 Discussion and Results 30 E ½ Re
Page 40 and 41: 3 Discussion and Results irradiatio
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Page 44 and 45: 3 Discussion and Results 3.2.2.1.2
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3 Discussion and Results 3.2.3.1 IR
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3 Discussion and Results 3.2.3.2 NM
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3 Discussion and Results 3.2.3.3 Va
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3 Discussion and Results 3.2.3.3.2
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3 Discussion and Results Obviously,
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3 Discussion and Results Like Figur
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3 Discussion and Results utilizatio
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3 Discussion and Results has been d
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3 Discussion and Results other TPP
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3 Discussion and Results (being sup
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3 Discussion and Results other band
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3 Discussion and Results Table 10.
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3 Discussion and Results voltammogr
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3 Discussion and Results 3.2.5 Inhe
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3 Discussion and Results effects 12
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3 Discussion and Results 74 Δθ [m
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3 Discussion and Results 3.2.6.2 10
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3 Discussion and Results vibration
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3 Discussion and Results 3.2.6.4 Sy
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3 Discussion and Results cyanomethy
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3 Discussion and Results 3.2.6.5 Co
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3 Discussion and Results phenyl sub
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3 Discussion and Results 90 5 μA -
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3 Discussion and Results 3.2.7 Appr
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3 Discussion and Results (75 eq.) w
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3 Discussion and Results 3.2.7.2 Sy
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3 Discussion and Results of rotatio
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3 Discussion and Results Thus, the
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3 Discussion and Results Time-resol
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3 Discussion and Results first redu
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3 Discussion and Results correspond
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3 Discussion and Results The remain
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3 Discussion and Results 3.2.8.1 Us
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3 Discussion and Results With all t
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3 Discussion and Results The interm
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3 Discussion and Results 116 HO 2 C
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3 Discussion and Results nitro comp
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3 Discussion and Results The effect
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3 Discussion and Results 3.2.9 Pote
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3 Discussion and Results peak at m/
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3 Discussion and Results Table 25.
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3 Discussion and Results 130
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4 Summary As the characterization d
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5 Zusammenfassung 5 Zusammenfassung
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5 Zusammenfassung Da in guten Ausbe
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6 Experimental Section UV/Vis spect
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6 Experimental Section 6.2 Studied
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6 Experimental Section 13 C NMR (10
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6 Experimental Section (cyanomethyl
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6 Experimental Section 6.2.4 AB3-Ty
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6 Experimental Section 6.2.4.3 5 4
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6 Experimental Section 6.2.4.11 10
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6 Experimental Section EA: C57H56N4
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6 Experimental Section 6.2.4.15 10
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6 Experimental Section 6.2.5 A2B2-T
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6 Experimental Section 6.2.5.5 αβ
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6 Experimental Section 6.2.5.7 αβ
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6 Experimental Section 6.2.5.9 αα
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6 Experimental Section 6.2.5.11 α
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6 Experimental Section 6.2.5.13 α
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6 Experimental Section 6.2.6 AB2C-T
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6 Experimental Section UV/Vis (CH2C
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6 Experimental Section UV/Vis (CH2C
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6 Experimental Section broad signal
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7 References 16 H. Fischer, K. Zeil
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7 References 57 S. Schwartz, K. Abs
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7 References 89 (a) R. C. Fuson, J.
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7 References 131 (a) J. Perdew, Phy
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S. Jasinski, N. Jux, “Investigati
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Ein großer Dank gilt auch den Ange
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Cirruculum vitae Stefan Jasinski Ge
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1.1 Porphyrins - Friedrich-Alexander-Universität Erlangen-Nürnberg

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